scholarly journals Landau theoretical analyses of phase transitions and ferroelec-tricity in antiferroelectric ferroics

2017 ◽  
Vol 6 (3) ◽  
pp. 51
Author(s):  
Egidius Rutatizibwa Rwenyagila

This paper presents Landau theoretical interpretation of phase transitions in Antiferroelectrics (AFEs) materials. The results show that the phase transitions occurring in AFEs have prominently first and second order properties. Landau theories of first and second order phase transition have been appropriately analyzed in order to explain some of desirable phenomenological behaviors occurring in AFE materials. The spatial order parameter profile of AFE domain wall was derived and tested for possibilities of having ferroelectricity (FE) in accordance with Landau type energy functional. It was found that FE may appear but with additional system instability because of additional energy as a result of polarization gradient.

2017 ◽  
Vol 2017 ◽  
pp. 1-5 ◽  
Author(s):  
Jakub Mielczarek

This article addresses the issue of possible gravitational phase transitions in the early universe. We suggest that a second-order phase transition observed in the Causal Dynamical Triangulations approach to quantum gravity may have a cosmological relevance. The phase transition interpolates between a nongeometric crumpled phase of gravity and an extended phase with classical properties. Transition of this kind has been postulated earlier in the context of geometrogenesis in the Quantum Graphity approach to quantum gravity. We show that critical behavior may also be associated with a signature change in Loop Quantum Cosmology, which occurs as a result of quantum deformation of the hypersurface deformation algebra. In the considered cases, classical space-time originates at the critical point associated with a second-order phase transition. Relation between the gravitational phase transitions and the corresponding change of symmetry is underlined.


2009 ◽  
Vol 65 (2) ◽  
pp. 147-159 ◽  
Author(s):  
Michael A. Carpenter ◽  
Christopher J. Howard

The structural evolution of selected perovskites containing Jahn–Teller cations has been investigated in the light of a formal analysis of symmetry hierarchies for phase transitions driven by octahedral tilting and Jahn–Teller cooperative distortions. General expressions derived from the strain/order-parameter coupling relationships allowed by symmetry are combined with observed changes in lattice parameters to reveal details of order-parameter evolution and coupling. LuVO3, YbVO3, YVO3 and CeVO3 are representative of systems which develop Jahn–Teller ordering schemes associated with irreducible representations M^+_2 and R^+_3 of the space group Pm\bar 3m. Tilting of their octahedra is associated with M^+_3 and R^+_4. The Pnma (M^+_3+R^+_4 tilting) ↔ P21/a (M^+_3+R^+_4 tilting, R^+_3 Jahn–Teller order) transition below room temperature is close to second order in character. Shear strains which depend primarily on tilt angles show little variation, implying that there is only weak coupling between the tilting and Jahn–Teller order parameters. The subsequent P21/a ↔ Pnma (M^+_3+R^+_4 tilting, M^+_2 Jahn–Teller order) is first order in character, and involves either a reduction in the R^+_4 tilt angle or a change in the strength of tilt/Jahn–Teller order-parameter coupling. In LaMnO3, the isosymmetric Pnma (M^+_3+R^+_4 tilting) ↔ Pnma (M^+_3+R^+_4 tilting, M^+_2 Jahn–Teller order) transition can be described in terms of a classical first-order transition conforming to a 246 Landau expansion with negative fourth-order coefficients. Strain evolution in Ba-doped samples suggests that the transition becomes second order in character and reveals a new strain relaxation mechanism in LaMnO3 which might be understood in terms of local strain heterogeneities due to the disordering of distorted MnO6 octahedra. Transitions in PrAlO3 and La0.5Ba0.5CoO3 illustrate the transformation behaviour of systems in which the Jahn–Teller ordering scheme is associated with the irreducible representation \Gamma^+_3. Overall, coupled tilting + Jahn–Teller phase transitions in perovskites conform to mean-field behaviour, consistent with the underlying role of strain in promoting long interaction lengths.


Author(s):  
Dmitrii Andrianov ◽  
◽  
Petr Simonov ◽  

A review of theoretical and applied results obtained in the framework of the scientific direction in econophysics at the Department of information systems and mathematical methods in economics is given. The first part gives the concept of a financial bubble and methods for finding them. At the beginning of the article, the development of econophysics is given. Therefore, using the research of physicists as a model, econophysics should begin its research not from the upper floors of an economic building (in the form of financial markets, distribution of returns on financial assets, etc.), but from its fundamental foundations or, in the words of physicists, from elementary economic objects and forms of their movement (labor, its productivity, etc.). Only in this way can econophysics find its subject of study and become a "new form of economic theory". Further, the main prerequisites of financial bubble models in the market are considered: the principle of the absence of arbitrage opportunities, the existence of rational agents, a risk-driven model, and a price-driven model. A well-known nonlinear LPPL model (log periodic power law model) was proposed. In the works of V.O. Arbuzov, it was proposed to use procedures for selecting models. Namely, basic selection, "stationarity" filtering, and spectral analysis were introduced. The results of the model were presented in the works of D. Sornette and his students. The second part gives the concept of percolation and its application in Economics. We will consider a mathematical model proposed by J.P. Bouchaud, D. Stauffer, and D. Sornette that recreates the behavior of an agent in the market and their interaction, geometrically describing a phase transition of the second kind. In this model, the price of an asset in a single time interval changes in proportion to the difference between supply and demand in this market. The results are published in the works of A.A. Byachkova, B.I. Myznikova and A.A. Simonov. There are two types of phase transition: the first and second kind. During the phase transition of the first kind, the most important, primary extensive parameters change abruptly: the specific volume, the amount of stored internal energy, the concentration of components, and other indicators. It should be noted that this refers to an abrupt change in these values with changes in temperature, pressure, and not a sudden change in time. The most common examples of phase transitions of the first kind are: melting and crystallization, evaporation and condensation. During the second kind of phase transition, the density and internal energy do not change. The jump is experienced by their temperature and pressure derivatives: heat capacity, coefficient of thermal expansion, or various susceptibilities. Phase transitions of the second kind occur when the symmetry of the structure of a substance changes: it can completely disappear or decrease. For quantitative characterization of symmetry in a second-order phase transition, an order parameter is introduced that runs through non-zero values in a phase with greater symmetry, and is identically equal to zero in an unordered phase. Thus, we can consider percolation as a phase transition of the second kind, by analogy with the transition of paramagnets to the state of ferromagnets. The percolation threshold or critical concentration separates two phases of the percolation grid: in one phase there are finite clusters, in the other phase there is one infinite cluster. The key situation to study is the moment of formation of an infinite cluster on the percolation grid, since this means the collapse of the market, when the overwhelming part of agents for this market has a similar opinion about their actions to buy or sell an asset. The main characteristics of the process are the threshold probability of market collapse, as well as the empirical distribution function of price changes in this market. Keywords: econophysics, behavior of agents in the market, market crash, second-order phase transition, percolation theory, model calibration, agent model calibration, percolation gratings, gradient percolation model, percolation threshold, clusters, fractal dimensions, phase transitions of the first and second kind.


1999 ◽  
Vol 13 (09n10) ◽  
pp. 275-283 ◽  
Author(s):  
KISOR MUKHOPADHYAY ◽  
PRABIR K. MUKHERJEE

We propose a Landau-de Gennes phenomenological model to describe the pressure induced smectic A-nematic phase transition. The influence of pressure on smectic A-nematic phase transitions are discussed for varying coupling between orientational and translational order parameter with pressure. Increasing the pressure, the first order nematic-smectic A transition becomes second order at a tricritical point which agrees fairly well with available experimental results.


Sign in / Sign up

Export Citation Format

Share Document