Performance of a UASB reactor for the treatment of anionic surfactant wastewater

Author(s):  
Lorena Oliveira Pires ◽  
Renata Piacentini Rodriguez ◽  
Juliana Braga ◽  
Matheus Marques Pizzo ◽  
Giselle Patrícia Sancinetti
2014 ◽  
Vol 4 (02) ◽  
Author(s):  
Rina S. Soetopo ◽  
Sri Purwati ◽  
Henggar Hardiani ◽  
Mukharomah Nur Aini ◽  
Krisna Adhitya Wardhana

A continuous pilot scale study has been conducted to investigate the effectiveness of anaerobic digestion of biological sludge. The sludge has a total solid content of 0.53% - 1.1%, pH of 7.20 to 7.32. Its organic content is about 97 %, The research were conducted in two stages, which are acidification (performed in 3 m3 the Continously Stirred Tank Reactor/CSTR at pH of 5.5 to 6.0) and methanation (performed in 5 m3 the Up Flow Anaerobic Sludge Blanket/UASB reactor at pH 6.5 to 7.0). The retention time (RT) was gradually shortened from 6 days to 1 day for acidification and from 8 days to 2 days for methanation. The results showed that operating the CSTR at the RT of 1 day and the organic loading of 8.23 g Volatile Solid (VS)/m3.day could produce Volatile Fatty Acid (VFA) at an average value of 17.3 g/kg VS.day. Operating the UASB reactor at the RT of 2 days and the organic loading (Chemical Oxygen Demand/COD) of 2.4 kg COD/m3.day could produce biogas at an average value of 66.3 L/day, with an average methane content of 69.9%, methane rate of 0.17 L CH4/g COD reduction or 19.06 L CH4/kg VS. Furthermore, methanation could reduce COD at an average value of 51.2 %, resulting in the effluent average value of COD filtrate and COD total of 210.1 mg/L and 375.2 mg /L, respectively.Keywords: acidification, methanation, CSTR, UASB, biogas ABSTRAKPercobaan digestasi anaerobik lumpur IPAL biologi industri kertas secara kontinyu skala pilot telah dilakukan di industri kertas dengan tujuan mengkaji efektivitas proses digestasi anaerobik dalam mengolah lumpur tersebut. Lumpur yang digunakan memiliki total solids sekitar 0,53% – 1,1%, pH netral (7,20 – 7,32) dengan komponen utama senyawa organik sekitar 97%. Percobaan dilakukan dalam dua tahap yaitu asidifikasi dalam reaktor CSTR berkapasitas 3 m3 pada pH 5,5 – 6,0 dan metanasi dalam reaktor UASB berkapasitas 5 m3 pada pH 6,5 – 7,0. Percobaan dilakukan dengan waktu retensi yang dipersingkat secara bertahap dari 6 hari ke 1 hari untuk proses asidifikasi dan dari 8 hari ke 2 hari untuk proses metanasi. Hasil percobaan menunjukkan bahwa pengoperasian reaktor CSTR dengan waktu retensi 1 hari dan beban organik 8,3 g VS/m3.hari dapat menghasilkan VFA rata-rata 17,3 g/kg VS.hari dengan kisaran 8,36 – 30,59 g/kg VS.hari, sedangkan pengoperasian reaktor UASB pada waktu retensi 2 hari dan beban organik 2,4 kg COD/m3.hari dapat menghasilkan biogas rata-rata 66,3 L/hari dengan kadar metana rata-rata 69,9% atau 0,17 L CH4/g COD reduksi atau 19,06 L CH4/kg VS. Selain itu proses metanasi dapat menurunkan COD terlarut rata-rata 51,2%, dengan konsentrasi efluen COD terlarut  rata-rata 210,1 mg/L dan COD total rata-rata 375,2 mg/L.Kata kunci: asidifikasi, metanasi, CSTR, UASB, biogas


2017 ◽  
Vol 16 (1) ◽  
pp. 121-130 ◽  
Author(s):  
Seyyed Mohammad Mousavi ◽  
Seyed Omid Rastegar ◽  
Seyed Abbas Shojaosadati ◽  
Soheila Sheibani

1997 ◽  
Vol 35 (8) ◽  
pp. 247-253 ◽  
Author(s):  
Herbert H. P. Fang ◽  
Ivan W. C. Lau ◽  
Denis W. C. Chung

The effects of nine common aromatic pollutants from chemical industry on the bioactivity of anaerobic granules were examined. The granules were obtained from an upflow anaerobic sludge blanket (UASB) reactor treating wastewater containing colloidal starch. The specific methanogenic activities (SMA) of granules were measured at 37°C in serum vials using 3000 mg/l of colloidal starch as substrate, plus individual pollutants at various concentrations. The toxicity was expressed by the IR50 and IC50 values, i.e. the toxicant/biomass ratio and concentration at which levels the granules exhibited only 50% of their original bioactivities. Results showed that in general the granules exhibited mild resistance to toxicity of aromatic pollutants, probably due to the granules' layered microstructure. The toxicities, which were dependent on the nature of chemical functional group, of the aromatic pollutants were in the following descending order: cresols > phenol > hydroxyphenols/phthalate > benzoate. There was only marginal difference between the toxicity of the steric isomers. For the seven phenolic pollutants, the more hydrophobic the functional group the higher the toxicity. The granules' resistance to toxicity suggested the plausibility of anaerobic treatment of wastewater from the chemical industry.


1999 ◽  
Vol 40 (8) ◽  
pp. 145-151 ◽  
Author(s):  
Liliana Borzacconi ◽  
Gisela Ottonello ◽  
Elena Castelló ◽  
Heber Pelaez ◽  
Augusto Gazzola ◽  
...  

The performance of a bench scale upflow sludge bed (USB) denitrifying reactor was evaluated in order to integrate it into a C and N removal system for Sanitary Landfill Leachate. The raw leachate used presented COD and NH4-N average values of 30000 mg/l and 1000 mg/l, respectively. The complete system comprises in addition an UASB reactor and a nitrifying RBC. A portion of the aerobic reactor effluent was recycled into the denitrification stage and some raw leachate was also added as an additional C source. In order to obtain operating parameters the denitrifying reactor was operated alone. Sludge from an aerobic reactor (RBC) treating raw leachate was used as inoculum. Shortly after the start up, good granulation of the sludge bed was observed. Using raw leachate and UASB outlet as carbon sources with COD/NO3-N ratios of 4 and 12, respectively, denitrification efficiencies of about 90% were reached. A sludge yield of 0.16 gVSS/gCODremoved was obtained operating with raw leachate. For the anoxic reactor operating in the complete system, denitrification efficiencies of 90% were also achieved. A nitrogen gas recycle was a successful way to avoid frequently observed sludge bed rising problems.


1997 ◽  
Vol 36 (6-7) ◽  
pp. 133-140 ◽  
Author(s):  
Zhu Jianrong ◽  
Hu Jicui ◽  
Gu Xiasheng

The bacterial numeration and microbial observation were made on granular sludge from laboratory single and two-phase UASB reactors. It was shown that the fermentative bacteria (group I), H2-producing acetogenic bacteria (group II) and methanogenic bacteria (group III) of granular sludge in single UASB reactor were 9.3 × 108−4.3 × 109, 4.3 × 107−4.3 × 108, 2.0−4.3 × 108, respectively, during the granulation process. The sludge of methanogenic reactor exhibited the similar results. That indicates there is no big difference between suspended and granular sludge, and bacterial population for three groups of anaerobic bacteria are similar. The formation of granular sludge depends mainly on the organization and arrangement of bacteria. An observation of granular sludge using electron microscope revealed that the fermentative bacteria and hydrogenotrophic methanogens existed on outer surface of granules, and aceticlastic methanogens and H2-producing acetogenic bacteria occupied the inner layer. A new syntrophic association between Methanosaeta sp. and Syntrophomonas sp. (even plus Methanobrevibacter sp.) was observed. Because Methanosaeta can effectively convert the acetate (the end product of propionate and butyrate) to methane, such a new syntrophic association is supposed to support the degradation of short fatty acids and high methanogenic activity of granular sludge. Based on structural pattern, a hypothesis on mechanism of granulation called “crystallized nuclei formation” is proposed.


Author(s):  
Zilong Liu ◽  
Hayati Onay ◽  
Fengzhi Guo ◽  
Junqing Chen ◽  
Lukasz Poltorak ◽  
...  

Author(s):  
E. Fernández-Palacios ◽  
Xudong Zhou ◽  
Mabel Mora ◽  
David Gabriel

In this study, the long-term performance and microbial dynamics of an Upflow Anaerobic Sludge Blanket (UASB) reactor targeting sulfate reduction in a SOx emissions treatment system were assessed using crude glycerol as organic carbon source and electron donor under constant S and C loading rates. The reactor was inoculated with granular sludge obtained from a pulp and paper industry and fed at a constant inlet sulfate concentration of 250 mg S-SO42−L−1 and a constant C/S ratio of 1.5 ± 0.3 g Cg−1 S for over 500 days. Apart from the regular analysis of chemical species, Illumina analyses of the 16S rRNA gene were used to study the dynamics of the bacterial community along with the whole operation. The reactor was sampled along the operation to monitor its diversity and the changes in targeted species to gain insight into the performance of the sulfidogenic UASB. Moreover, studies on the stratification of the sludge bed were performed by sampling at different reactor heights. Shifts in the UASB performance correlated well with the main shifts in microbial communities of interest. A progressive loss of the methanogenic capacity towards a fully sulfidogenic UASB was explained by a progressive wash-out of methanogenic Archaea, which were outcompeted by sulfate-reducing bacteria. Desulfovibrio was found as the main sulfate-reducing genus in the reactor along time. A progressive reduction in the sulfidogenic capacity of the UASB was found in the long run due to the accumulation of a slime-like substance in the UASB.


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