Sustainable Electrochemical NO Capture and Storage System Based on the Reversible Fe2+/Fe3+-EDTA Redox Reaction

The removal of nitric oxide (NO), which is an aggregation agent for fine dust that causes air pollution, from exhaust gas has been considered an important treatment in the context of environmental conservation. Herein, we propose a sustainable electrochemical NO removal system based on the reversible Fe2+/Fe3+-ethylenediamine tetraacetic acid (EDTA) redox reaction, which enables continuous NO capture and storage at ambient temperature without the addition of any sacrificial agents. We have designed a flow-type reaction system in which the NO absorption and emission can be separately conducted in the individual reservoirs of the catholyte and anolyte with the continuous regeneration of Fe2+-EDTA by the electrochemical reduction in Fe3+-EDTA. A continuous flow reaction using a silver cathode and glassy carbon anode showed that the concentrations of Fe2+ and Fe3+-EDTA in the electrolyte were successfully maintained at a 1:1 ratio, which demonstrates that the proposed system can be applied for continuous NO capture and storage.

Kajian Performa Passive Residual Heat Removal System (PRHRS) pada System-Integrated Advanced Modular Reactor (SMART)

SMART (System-Integrated Advanced Modular Reactor) merupakan desain reaktor multifungsi Generasi III+ tipe SMR (Small Modular Reactor) yang dikembangkan oleh KAERI (Korean Atomic Energy Research Institute) dengan kapabilitas produksi listrik 107 MWe dan energi termal 365 MWt. Sistem SMART meliputi berbagai fitur keselamatan untuk mengatasi LOCA (Loss of Coolant Accident) dan skenario kecelakaan lainnya. Salah satu dari fitur tersebut adalah Passive Residual Heat Removal System (PRHRS) atau sistem pembuang sisa panas pasif yang bekerja tanpa membutuhkan sumber daya elektrik. Sistem ini bekerja sesuai dengan prinsip sirkulasi alam sehingga bergantung pada aspek termal, tekanan, dan pengaruhnya terhadap aliran massa. Ketiga aspek tersebut dapat mempengaruhi kapabilitas pembuangan panas pada sistem. Data performa PRHRS reaktor SMART pada beberapa kondisi kecelakaan yang diperoleh melalui studi eksperimental maupun simulasi termohidrolika dianalisis pada kajian ini. Hasil analisis menunjukkan unjuk kerja pembuangan sisa panas yang baik oleh PRHRS SMART dengan waktu aktuasi yang tepat dan pendinginan yang stabil. Dengan kapabilitas multifungsi dan kemampuan pendinginan yang baik pada berbagai skenario kecelakaan, SMART memiliki potensi tinggi untuk kelak diterapkan di Indonesia.

Infinite Water: Implementation of Nanofiltration for Optimization of Vessel Stimulation Operations in the Offshore Greater Ekofisk Area, North Sea

The incorporation of a sulfate removal system onto a stimulation vessel has been shown to positively affect vessel utilization, increase efficiency in field development, and reduce freshwater consumption. Stimulation vessels have fixed storage and transportation volumes as well as a fixed total mass that can be loaded. Fresh water occupies the highest proportion of space and mass in most stimulation treatments, which imposes limitations on all other products that can be loaded out. Particularly for acid stimulation treatments, a compromise between the volumes of raw acid and fresh water must be made in order to achieve the best operational efficiency possible. Any method that can reduce, eliminate, or replace fresh water as a component in stimulation fluids will have a significant impact on vessel efficiency. One option is the use of seawater as the base fluid. However, seawater can cause problems for well production due to the high sulfate content in the water leading to the formation of mineral scale. The solution to this problem has been the installation of a sulfate removal system on the stimulation vessel. Driven by membrane nanofiltration, this system can produce up to 100 m3/hr of low sulfate water from seawater for well stimulation operations. By removing the scaling risk from seawater, this system enables the stimulation vessel to maximize the products it loads with the ability to produce low sulfate water as and when it is needed. The sulfate removal system can reduce SO4 content to 4.3 mg/l and reduce other ions present in seawater. With an output of 100 m3/hr and being installed independently from stimulation systems, the unit is able to produce water regardless of ongoing activities. In stimulation jobs, multistage ball drop operations are the most time-critical operations. In the analysis of hundreds of stages stimulated with water from the new nanofiltration system, the average stage completion time was 6 hours, which included ball loading, dropping, and displacement; diagnostic injection testing; and the main treatment. With an average water requirement of 600 m3, the vessel can keep up with water demand and remove water capacity from the utilization equation. The use of a compact nanofiltration system for SO4 removal has improved stimulation vessel operations where scale production is a key concern for operators. In addition to increasing vessel utilization and intervention efficiency, the system will lead to the elimination of approximately 68,000 m3 of fresh water being pumped every year for stimulation operations in the North Sea.