Lignin modification in the initial phase of softwood kraft pulp delignification with polyoxometalates (POMs)

Holzforschung ◽  
2007 ◽  
Vol 61 (5) ◽  
pp. 492-498 ◽  
Author(s):  
Biljana Bujanovic ◽  
Sally A. Ralph ◽  
Richard S. Reiner ◽  
Rajai H. Atalla
Keyword(s):  
Kraft Pulp ◽  
Lignin Content ◽  
Kappa Number ◽  
Ring Cleavage ◽  
Residual Lignin ◽  
Glucose Content ◽  
Lower Glucose ◽  
Softwood Kraft Pulp ◽  
Alkaline Conditions ◽  
Extraneous Material

Abstract Commercial softwood kraft pulp with kappa number 30.5 (KP30.5) was delignified with polyoxometalates (POM, Na5(+2)[SiV1(-0.1)MoW10(+0.1)O40]), and POM-treated kraft pulp of kappa number 23.6 was obtained (KPPOM,23.6). Residual lignin from pulps was isolated by mild acid hydrolysis and characterized by analytical and spectral methods to gain insight into lignin reactions taking place during the initial delignification phase. Lignin from POM-delignified pulp was isolated in lower yield. Comparative analysis of residual lignins (RL-KP30.5, RL-KPPOM,23.6) showed that POM leads to products enriched in carbonyl/carboxyl groups and carbohydrates. POM lignins have a lower molecular mass and a lower content of phenolic hydroxyl and methoxyl groups. Based on these results and FTIR spectra, we suggest that aromatic ring cleavage and quinone formation occur during POM delignification. The degree of lignin-cellulose association increases after POM delignification. Lignin-cellulose association was found to be partially unstable under mild alkaline conditions, as residual lignin isolated after alkaline extraction of KPPOM,23.6 pulp (RL-KPPOM/NaOH) exhibited lower glucose content, higher Klason lignin content, and less extraneous material.

Changes in the lignin-carbohydrate complex in softwood kraft pulp during kraft and oxygen delignification

Holzforschung ◽  
2004 ◽  
Vol 58 (6) ◽  
pp. 603-610 ◽  
Author(s):  
Martin Lawoko ◽  
Rickard Berggren ◽  
Fredrik Berthold ◽  
Gunnar Henriksson ◽  
Göran Gellerstedt
Keyword(s):  
Kraft Pulp ◽  
Kappa Number ◽  
Kraft Pulps ◽  
Residual Lignin ◽  
Oxygen Delignification ◽  
Number Range ◽  
Morphological Aspects ◽  
Carbohydrate Complex ◽  
Softwood Kraft Pulp ◽  
Hydrolysis Of

Abstract Three kraft pulps in the kappa number range between 50 and 20 and the same pulps oxygen-delignified to similar lignin contents (kappa approximately 6) were analyzed for lignin-carbohydrate complexes (LCC) by a method based on selective enzymatic hydrolysis of the cellulose, and quantitative fractionation of the LCC. Between 85 and 90% of residual lignin in the unbleached kraft pulp and all residual lignin in the oxygen-delignified pulps were isolated as LCC. Three types of complexes were found; viz., xylan-lignin, glucomannan-lignin-xylan and glucanlignin complexes. After pulping to a high kappa number, most of the residual lignin was linked to xylan. Different delignification rates were observed so that most of the residual lignin was linked to glucomannan when the pulping was extended to a low kappa number. With increasing degree of oxygen delignification, a similar trend in the delignification rates of LCC was observed so that the residual lignin was increasingly linked to glucomannan. Complex LCC network structures seemed to be degraded into simpler structures during delignification. The differences in delignification rates are discussed with reference to the solubility properties and structural differences of LCC, and to morphological aspects of the pulp.

scholarly journals Effects of Manganese Peroxidase on Residual Lignin of Softwood Kraft Pulp

1998 ◽  
Vol 64 (6) ◽  
pp. 2273-2274 ◽  
Author(s):  
Ian D. Reid ◽  
Michael G. Paice
Keyword(s):  
Manganese Peroxidase ◽  
Kraft Pulp ◽  
Kappa Number ◽  
Residual Lignin ◽  
Softwood Kraft Pulp

ABSTRACT Manganese peroxidase treatment lowered the kappa number of kraft pulp and increased the alkali extractability of the residual lignin but did not directly solubilize it. This indicates that MnP partially oxidizes the lignin in the pulp but does not degrade it to soluble fragments.

Sodium sulphite pulping of Scots pine under neutral and mildly alkaline conditions (NS pulping)

Holzforschung ◽  
2016 ◽  
Vol 70 (7) ◽  
pp. 603-609 ◽  
Author(s):  
Saara Hanhikoski ◽  
Elina Warsta ◽  
Antero Varhimo ◽  
Klaus Niemelä ◽  
Tapani Vuorinen
Keyword(s):  
Scots Pine ◽  
Lignin Content ◽  
Kappa Number ◽  
Sulphonic Acid ◽  
Sodium Sulphite ◽  
Residual Lignin ◽  
Initial Ph ◽  
Alkaline Conditions ◽  
Ph Range

Abstract Sodium sulphite pulping of Scots pine chips in the initial pH range of 7.5–9 was investigated at 180°C and 165°C (for 120–240 min), using chemical charges between 25 and 50% and anthraquinone (AQ) charges 0–0.2%. As a result, pulps with yields of 52–73% and kappa numbers of 35–106 were produced. Delignification was accelerated by higher Na2SO3 charges and temperatures, and by AQ addition, whereas the effect of initial pH was negligible. The high pulp yields at a given kappa number were attributable to high retention of hemicelluloses, especially that of galactoglucomannan. The relatively low viscosities of pulps were apparently caused by depolymerisation of cellulose by sulphite. The sulphonic acid groups in the pulps correlated well with the residual lignin content, although some sulphonation of polysaccharides may also be possible. The results indicate that pulping of softwood in buffer-free (without Na2CO3 and/or NaOH) sodium sulphite liquor may result in pulps with tailored characteristics.

scholarly journals Assessment of Q(OP)D(PO) bleachability of softwood kraft pulp

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Sara Starrsjö ◽  
Maria Boman ◽  
Olena Sevastyanova ◽  
Mikael E. Lindström ◽  
Juha Fiskari
Keyword(s):  
Kraft Pulp ◽  
Kappa Number ◽  
Carbohydrate Content ◽  
Residual Lignin ◽  
Three Samples ◽  
Softwood Kraft Pulp ◽  
Pulp Sample ◽  
Yield Gain ◽  
Hexenuronic Acid

Abstract Bleachability is evaluated as how easily a pulp sample is bleached and it depends on the structure of residual lignin and carbohydrates. Also, the bleachability varies depending on the bleaching sequence. ECF light sequences have been improved significantly in the recent years. However, we still don’t fully understand how ECF light bleach plants are optimally run. This work studies the bleachability of softwood kraft pulp in an ECF light bleaching sequence, (OO)Q(OP)D(PO). Three pulp samples with brown stock kappa number 27, 32 and 35 were bleached and studied for residual lignin, hexenuronic acid and carbohydrate content. It was found that in the bleaching stages that are highly delignifying, it is beneficial with a higher kappa number for the delignifying bleachability. However, in the bleaching stages where the objective is brightness increase, the brightness gain bleachability is improved by a lower kappa number. We also intended to determine which of the three samples had the best suited kappa number for this particular bleaching sequence. According to our results, the bleaching was most effective with kappa number around 32. Although an even higher kappa number resulted in higher yield after cooking, it seemed that this bleaching sequence cannot preserve the yield gain.

Elucidating carboxylic acid profiles for extended oxygen delignification of high-kappa softwood kraft pulps

Holzforschung ◽  
2006 ◽  
Vol 60 (2) ◽  
pp. 123-129 ◽  
Author(s):  
Dongcheng Zhang ◽  
Yunqiao Pu ◽  
Xing-Sheng Chai ◽  
Ved Naithani ◽  
Hasan Jameel ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Acid Content ◽  
Kraft Pulp ◽  
Lignin Content ◽  
Acid Group ◽  
Kraft Pulps ◽  
Residual Lignin ◽  
Oxygen Delignification ◽  
Acid Ratio ◽  
Softwood Kraft Pulp

Abstract Two laboratory high-lignin-content softwood (SW) kraft pulps with kappa values of 48.0 and 49.5, prepared by cooking at high and low active alkali (AA), were used for the study of fiber charge development during two-stage oxygen delignification with inter-stage washing (OwO). It was established that the first oxygen delignification (O) stage increased total fiber charge by 2–4%, and further O-delignification via a second O-stage led to a 3–18% decrease in total fiber charge. Carboxylic acid content in pulp holocelluloses decreased by 12–26% with respect to a 35–70% kappa number reduction due to an O and OwO stage of delignification for high and low AA cooked SW kraft pulps. After an OwO-stage delignification, the residual lignin was found to exhibit a 50–100% increase in carboxylic acid content. 13C NMR spectral data for the residual lignin samples indicated that the unconjugated/conjugated acid ratio was approximately (3–4):1. Generally, the carboxylic acid content in low AA cooked softwood kraft pulp and the corresponding oxygen-delignified pulps was systematically higher (13–23%) than that in high AA cooked SW kraft pulp and the corresponding oxygen-delignified pulps. The experimental results also demonstrated that maximum acid-group content in total fiber occurred after 45–50% oxygen delignification of the SW kraft pulps studied.

Isolation of residual lignin from softwood kraft pulp. Advantages of the acetic acid acidolysis method

2004 ◽  
Vol 327 (9-10) ◽  
pp. 911-916 ◽  
Author(s):  
Dominique Lachenal ◽  
Gérard Mortha ◽  
Rose-Marie Sevillano ◽  
Michail Zaroubine
Keyword(s):  
Acetic Acid ◽  
Kraft Pulp ◽  
Residual Lignin ◽  
Softwood Kraft Pulp

Effect of lignin content and magnesium-to-manganese ratio on the selectivity of oxygen delignification in softwood kraft pulp

2001 ◽  
Vol 73 (12) ◽  
pp. 2059-2065
Author(s):  
Lucian A. Lucia ◽  
Rachel S. Smereck
Keyword(s):  
Chemical Process ◽  
Kraft Pulp ◽  
Lignin Content ◽  
Dry Mass ◽  
The Other ◽  
Kraft Pulps ◽  
Oxygen Delignification ◽  
Pulp Viscosity ◽  
Softwood Kraft Pulp ◽  
Temperature Time

A series of oxygen delignification experiments were performed on two softwood kraft pulps that had differing starting lignin contents. One had an initial kappa of 40 and the other 25, corresponding to lignin contents of 6% and 3.75% by dry mass, respectively. Several chemical process modifications were examined to determine their influence over the delignification selectivity and final pulp viscosity. A 2k factorial format was used to assess the significance of varying the temperature, time, and Mg/Mn ratio during the oxygen delignification of the pulps. It was found that the lower lignin content pulp displayed greater delignification selectivity than the higher lignin content pulp. Kappa numbers, viscosity values, and ICP metals contents were determined and are the basis of discussion for the results obtained.

Kraft pulp yields and wood properties of fertilized red spruce

1980 ◽  
Vol 10 (2) ◽  
pp. 183-189
Author(s):  
Robert K. Shepard Jr. ◽  
James E. Shottafer ◽  
Joseph M. Genco
Keyword(s):  
Kraft Pulp ◽  
Lignin Content ◽  
Volume Growth ◽  
Wood Properties ◽  
Kappa Number ◽  
Red Spruce ◽  
Unit Weight ◽  
Pulp Yield ◽  
Average Yield ◽  
Posttreatment Period

Red spruce (Picearubens Sarg.) near Princeton, Maine, U.S.A. fertilized with 168 kg N/h in 1970 increased in volume growth by nearly 50% over pretreatment rates during the 8-year posttreatment period; specific gravity was not affected. Average pulp yield per unit weight of posttreatment wood from fertilized trees was 1.9% greater than average yield from pretreatment wood, but rejects increased by 2.2% and kappa number by 17.7 mL. Average pulp yield per unit weight of posttreatment wood from unfertilized trees was 1.2% less than from pretreatment wood; rejects were 0.4% less and kappa number 2.6 mL higher. Fertilization increased the lignin content of posttreatment wood by about 3% and the resin content by 2%. Ash content also increased after fertilization.

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