Effect of TiB2 addition on the microstructural, electrical, and mechanical behavior of Cu–TiB2 composites processed via spark plasma sintering

Author(s):  
C Ayyappadas ◽  
Ravi Teja ◽  
A. Raja Annamalai ◽  
Dinesh K Agrawal ◽  
Shaik Dilkush ◽  
...  

Abstract In this investigation, copper–TiB2 metal matrix composites were fabricated by spark plasma sintering. The effect of TiB2 (2.5, 5, 7.5, and 10 wt.%) additions on the microstructural, electrical, and mechanical properties of the composites was investigated. There was a remarkable reduction in processing time and temperature by this process as compared to conventional sintering. Scanning electron microscopy with energy dispersive X-ray spectroscopy elemental maps revealed a homogeneous distribution of TiB2 in the copper matrix. The hardness of the composites exhibited no consistent trend with the addition of TiB2. An improvement in tensile strength was observed at the expense of ductility. Electrical conductivity showed a decreasing trend. Morphology of the fracture surfaces was analyzed to predict the nature of failure under tensile load.

Materials ◽  
2020 ◽  
Vol 13 (11) ◽  
pp. 2602 ◽  
Author(s):  
Massimo Pellizzari ◽  
Giulia Cipolloni

The aim of this study is to fabricate a Cu-0.5wt%TiB2 composite by mechanical alloying (MA) and spark plasma sintering (SPS). Increasing the milling time, the powders are subjected firstly to a severe flattening process and then to intense welding, which promotes the refinement of TiB2 particles, their uniform dispersion in the metal matrix, and the adhesion between the two constituents. Sintered metal matrix composites (MMC) exhibit density values between 99 and 96%, which are generally decreased by increasing milling time in view of the stronger strain hardening. On the other side, the hardness increases with milling time due to the refinement of TiB2 particles and their improved distribution. The hardness of MMC is three times higher (225 HV0.05) than the starting hardness of atomized copper (90 HV0.05). Tensile tests show a loss of ductility, but ultimate tensile strength has been increased from 276 MPa of atomized copper to 489 MPa of MMC milled for 240 min. The thermal conductivity of MMC is comparable to that of atomized copper (300 W/mK), i.e., much higher than that of the commercial Cu-Be alloy (Uddeholm Moldmax HH, 106 W/mK) typically used for tooling applications.


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