Effect of the particulate morphology of resin on the gelation process of PVC plastisols

2017 ◽  
Vol 37 (8) ◽  
pp. 757-764 ◽  
Author(s):  
Yubi Ji ◽  
Zhao Yang ◽  
Min Shi ◽  
Hong Tan

Abstract The gelation process of poly(vinyl chloride) (PVC) plastisol is very important to ensure the quality of the product and is affected by the type of resins, plasticizers, and other additives. In this study, the gelation process of the as-prepared PVC plastisol was characterized by measuring the evolution of vibrational viscosity with temperature or time using a vibrational viscometer. Furthermore, the effect of some commercial resins with different particulate morphologies on the gelation process was investigated by synchronously combining scanning election microscopy and laser particle size analyses. The results of this study proved that the particle size distribution and the aggregation degree of the secondary particles of a resin are the key factors affecting the gelation process. For the resin with bimodal particle size distribution, the closer the aggregation of the secondary particles, the slower the gel speed; however, an opposite behavior was observed for the resins with unimodal particle size distribution.

Author(s):  
T.V. Karlova ◽  
◽  
D.O. Sv ◽  

The article is devoted to the analysis of parameters of medical technological equipment that take into account factors affecting the quality of manufacture of drugs. Factors such as particle size, particle size distribution, particle shape, particle surface properties, particle strength, which, based on the «Web» method, are used to analyze the «vibrosieve» technological equipment, are considered.


Author(s):  
I. L. Whyte

AbstractThe origins and development of the U100 (U4) thick-walled open-drive sampler are reviewed. The requirements of CP 2001 and BS 5930 are examined in relation to sample quality, and these are shown to be too favourable. Causes of sample disturbance are considered, particularly those due to volume changes, and shown to depend on moisture content, plasticity and particle size distribution. Quality classes possible with conventional U100 samples are suggested, and Classes 3 or 4 are to be generally expected. Class 1 samples are improbable. It is recommended that a general purpose sampler such as the U100 should have a maximum inside clearance of 1% and not ‘about 1%’ as recommended in BS 5930.


2020 ◽  
Vol 586 ◽  
pp. 119495 ◽  
Author(s):  
Anh Vo ◽  
Xin Feng ◽  
Deval Patel ◽  
Adil Mohammad ◽  
Darby Kozak ◽  
...  

1990 ◽  
Vol 55 (9) ◽  
pp. 2244-2251 ◽  
Author(s):  
Christina Apostolidou ◽  
Michael Stamatoudis

Experiments were conducted on some of factors affecting the polymerized particle size distribution in suspension polymerization of styrene. Polymerization experiments with styrene at 80 °C showed that the final polystyrene product size distribution is strongly affected by the stabilizer concentration, the type and the speed of impeller, and the hold-up fraction.


2015 ◽  
Vol 70 (3) ◽  
pp. 193-198 ◽  
Author(s):  
S. Müller ◽  
D. Schaub

Abstract. An important factor in the release of phosphorus by soil erosion, with corresponding consequences on the quality of surface waters, is the formation of aggregates and their stability. Around the eutrophic Lake Hallwil six arable lands were examined in five repetitions regarding aggregate and particle size distribution, P-contents of the different fractions and aggregate stability. Central to this was the use of the setting column for fractionation of soil samples. In the case of Lake Hallwil the risk of phosphorus discharges by soil erosion seems low since the phosphorus is mainly bound in aggregates which are transported over short distances only. Thus other pathways (runoff from grassland, leaching via drains) may be more important.


2020 ◽  
pp. 11-20
Author(s):  
A.E. Knyazev ◽  
◽  
A.V. Vostrikov ◽  

Considers the features of powders obtained by various methods, their technological properties in relation to additive and granular manufacturing. The sequence of operations upon receipt of metal powder compositions is presented. The factors affecting the process of vibration sieving of metal powders and granules are described. The features and advantages of vibratory sieving on horizontally arranged circular sieves using ultrasonic cleaning to obtain specified trajectories of motion are shown. Criteria for evaluating the sieving efficiency are given and explanations are given for determining the particle size distribution of powders and granules.


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