Pressure and Temperature Dependence of Self-Diffusion in Liquid Linear Hydrocarbons
1986 ◽
Vol 41
(7)
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pp. 963-970
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Keyword(s):
The Self
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The pressure and temperature dependence o f the self-diffusion coefficients D of n-butane, n-pentane, n-hexane, n-decane, trans-2-butene, cis-2-butene and 2-butyne were determined in the liquid state by NM R-techniques at pressure up to 200 MPa and temperatures up to 450 K. The results are taken as tests for the various dynamical models and compared to results obtained by M D calculations. The activation parameters for translational transport and the parameters for the RHS-m odel are derived and discussed.
2009 ◽
Vol 283-286
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pp. 155-160