A 35CL NQR Spin-Lattice Relaxation Study on the Motion of D4h Anions in [C(NH2)3]2PdCl4, [C(NH2)3]2PtCl4, and [C(NH2)3]AuCl4

1986 ◽  
Vol 41 (1-2) ◽  
pp. 416-420
Author(s):  
Yoshihiro Furukawa ◽  
Daiyu Nakamura
Keyword(s):  
Relaxation Times ◽  
Sharp Decrease ◽  
Lattice Relaxation ◽  
Spin Lattice Relaxation ◽  
Temperature Dependent ◽  
Spin Lattice ◽  
35Cl Nqr ◽  
The One ◽  
Increasing Temperature ◽  
Complex Anions

The temperature dependence of 35Cl NQR spin-lattice relaxation times T1ClQ was observed for the crystal of the title complexes. For the Pd(II) and Pt(II) complexes, the log T1ClQ vs. 103 T-1 curves having gentle positive gradients at lower temperatures decreased sharply with increasing temperature from ca. 150 and ca. 130 K, respectively. This sharp decrease of T1ClQ can be explained by the C4 reorientation of the D4h complex anions with the activation energy Ea of 34 kJ mol-1 for the former and 29 kJ mol-1 for the latter complex. These values agree well with those estimated from 1H T1 showing temperature dependent dipolar-quadrupolar cross relaxation. For the Au(III) salt, two of four 35Cl NQR lines showed a sharp decrease in T1ClQ from ca. 270 K, suggesting the onset of the C4 reorientation of the one kind crystallographically equivalent anions with Ea of 67 kJ mol-1.

35Cl NQR in Solid Trichloroacetyl Halides

1996 ◽  
Vol 51 (5-6) ◽  
pp. 751-754 ◽  
Author(s):  
A. D. Gordeev ◽  
A. N. Osipenko ◽  
G. B. Soifer
Keyword(s):  
Crystal Lattice ◽  
Linear Correlation ◽  
Relaxation Times ◽  
Lattice Relaxation ◽  
Spin Lattice Relaxation ◽  
Temperature Dependent ◽  
Spin Lattice ◽  
Resonance Frequencies ◽  
35Cl Nqr ◽  
Temperature Dependences

Abstract By 35Cl NQR the temperature dependences of the resonance frequencies and spin-lattice relaxation times for the 35Cl nuclei have been studied in solid CCl3COHal (Hal = F, CI, Br, I). A linear correlation between the average 35Cl NQR frequencies of the CCl3 groups and the electronegativities of the halogen atoms in the COHal groups has been discovered. The temperature-dependent NQR data reveal thermoactivated reorientations of the CCl3COHal molecules as a whole in the crystal lattice. The activation energies of this motion are found to lie in the range 31 - 37 kJ mol - 1

scholarly journals The Motion of the OH Group in p-Chlorophenol and its Influence on the 35Cl NQR Parameters

1986 ◽  
Vol 41 (1-2) ◽  
pp. 408-411 ◽  
Author(s):  
Mariano J. Zuriaga ◽  
Carlos A. Martin
Keyword(s):  
Activation Energy ◽  
Relaxation Times ◽  
Lattice Relaxation ◽  
Frequency Difference ◽  
Spin Lattice Relaxation ◽  
Normal Behaviour ◽  
Spin Lattice ◽  
35Cl Nqr ◽  
Two Temperature ◽  
Nqr Parameters

The 35Cl NQR transition frequencies and the spin-lattice relaxation times, T1, for both lines in p-chlorophenol have been measured in the temperature range 90 - 310 K. The frequency difference and the temperature derivatives for both lines clearly show the existence of two temperature intervals with distinct lattice contributions to the EFG. Similarly, T1, data show a normal behaviour due to spin-phonon interactions up to 240 K. Above this temperature T1 begins to shorten in an exponential manner. The hindered motions of the OH group are proposed as responsibles of these effects, and an activation energy of 26 kJ mol-1 is determined.

Hydrogen Isotope Effect on the Temperature Dependence of the 35Cl-NQR Frequency in (NH4)2IrCl6

2002 ◽  
Vol 57 (6-7) ◽  
pp. 504-508 ◽  
Author(s):  
Yoshio Kume ◽  
Tetsuo Asaji
Keyword(s):  
Relaxation Times ◽  
Lattice Relaxation ◽  
Spin Lattice Relaxation ◽  
Ammonium Ion ◽  
Energy Separation ◽  
Rotational States ◽  
Spin Lattice ◽  
35Cl Nqr ◽  
Deuterated Analogue ◽  
Hydrogen Isotope Effect

The 35Cl-NQRfrequencies and spin-lattice relaxation times of (NH4)2IrCl6 and (ND4)2IrCl6 were measured in the temperature range 4.2 - 300 K. It was confirmed that no phase transition takes place down to 4.2 K. The observed frequency at 4.2 K in (ND4)2IrCl6 was higher by 18 kHz than that in the non-deuterated analogue. This discrepancy was attributed to a difference between the lowest rotational states of the ammonium ions in these compounds. The energy separation between the ground state and excited state of rotational motion, in which N-H of the ammonium ion rotates among the three directions slightly apart from the triad axis, was estimated by fitting analysis to be 31 cm-1 and 93 cm-1 for (ND4)2IrCl6 and (NH4)2IrCl6, respectively. The activation energy of the reorientation of the ammonium ion among the four directions of the triad axis was estimated to be 6.9 and 7.6 kJ mol-1, respectively

Conformation of ring A in triterpenoid ketones. Carbon-13 chemical shifts and spin-lattice relaxation times of lupane and 18α-oleanane derivatives

1989 ◽  
Vol 54 (7) ◽  
pp. 1928-1939 ◽  
Author(s):  
Miloš Buděšínský ◽  
Jiří Klinot
Keyword(s):  
Chemical Shifts ◽  
Relaxation Times ◽  
Lattice Relaxation ◽  
Chair Conformation ◽  
Spin Lattice Relaxation ◽  
Spin Lattice ◽  
Structural Assignment ◽  
Boat Form ◽  
The One ◽  
C Nmr

13C NMR spectra of sixteen lupane and 19β,28-epoxy-18α-oleanane triterpenoids I-XVI were measured and a complete structural assignment of chemical shifts was made. For most compounds also the carbon spin-lattice relaxation times T1 were obtained. Characteristic differences in chemical shifts of some carbon atom signals were found between 2α-methyl-3-oxo and 2α-methyl-1-oxo derivatives II, V and VIII with chair conformation of the ring A on the one hand and their 2β-isomers III, VI and IX (boat form) on the other. Using these 2-methyl ketones as models, the chair-boat population in allobetulone (I), 3-oxo-28-lupanenitrile (IV) and 1-oxo derivative VII was determined. The results agree well with the data obtained by other physical methods.

NQR and Phase Transitions of Tetramethylammonium Tetrahalogenomercurates (II)

1996 ◽  
Vol 51 (5-6) ◽  
pp. 755-760 ◽  
Author(s):  
Hiromitsu Terao ◽  
Tsutomu Okuda ◽  
Koji Yamada ◽  
Hideta Ishihara ◽  
Alarich Weiss
Keyword(s):  
Phase Transitions ◽  
Room Temperature ◽  
Relaxation Times ◽  
Lattice Relaxation ◽  
Spin Lattice Relaxation ◽  
Temperature Phase ◽  
Reorientational Motion ◽  
Spin Lattice ◽  
Increasing Temperature

NQR and DTA revealed phase transitions in [(CH3)4N] 2HgBr4 and [(CH3)4N] 2HgI4 at 272 K and 264 K, respectively. The NQR resonance lines faded out with increasing temperature. From preliminary measurements of 81Br NQR spin-lattice relaxation times and 199Hg NMR a reorientational motion of HgBr4 ions around one of their pseudo C3 axes in the room temperature phase of [(CH3)4N] 2HgBr4 is suggested.

A 35Cl NQR Study on Exchange Interactions between Paramagnetic [IrCl6]2– Ions

2002 ◽  
Vol 57 (6-7) ◽  
pp. 431-434 ◽  
Author(s):  
Hiroshi Miyoshi ◽  
Keizo Horiuchi ◽  
Ryuichi Ikeda
Keyword(s):  
Relaxation Times ◽  
Exchange Interactions ◽  
Lattice Relaxation ◽  
Spin Lattice Relaxation ◽  
Spin Lattice ◽  
35Cl Nqr ◽  
Temperature Dependences ◽  
Field Fluctuations ◽  
Paramagnetic Ions ◽  
Exchange Parameters

The 35Cl and 37Cl NQR frequencies and spin-lattice relaxation times T1Q in paramagnetic M2IrCl6 (M = NH4, Cs) were measured at 4 - 350 K. The observed temperature dependences were attributed to EFG fluctuations caused by lattice vibrations and magnetic field fluctuations caused by paramagnetic ions. The exchange parameters in the NH4 and Cs salts were calculated from 35Cl NQR T1Q to be 8.6 K and 1.8 K respectively. 37Cl data yielded 9.1 K and 2.1 K respectively. The obtained lattice constant dependence of J values was explained by considering Ir-Cl Cl-Ir superexchange interaction

Solitons, polarons and their dynamics in mixed-valence halogen-bridged MX-chains

2007 ◽  
Vol 366 (1862) ◽  
pp. 93-100 ◽  
Author(s):  
Shinya Takaishi ◽  
Masahiro Yamashita
Keyword(s):  
Mixed Valence ◽  
Relaxation Times ◽  
Lattice Relaxation ◽  
Spin Lattice Relaxation ◽  
Relaxation Processes ◽  
Spin Lattice ◽  
H Nmr ◽  
Spin Resonance ◽  
1D Chain ◽  
The One

This article describes the photo-generation processes of elementary excitations such as solitons and polarons, and their dynamics in the one-dimensional (1D) halogen-bridged Pt compound [Pt(en) 2 Br](ClO 4 ) 2 . Spin-solitons were photo-generated via relaxation processes of CT excitons and self-trapped excitons, made evident by photo-induced absorption and photo-induced electron spin resonance spectra. Polarons were not generated from CT excitons. Diffusion of spin-solitons on the 1D chain was studied quantitatively by analysing 1 H NMR spin-lattice relaxation times ( T 1 ).

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