Influence of Hydrogen on the Structure of Amorphous Sputtered Fe-Co-Tb Films by Means of Wide- and Small Angle Neutron Scattering

1991 ◽  
Vol 46 (12) ◽  
pp. 1015-1020 ◽  
Author(s):  
M. Heckele ◽  
R. Bellissent ◽  
A. Brunseh ◽  
P. Lamparter ◽  
S. Steeb

Abstract Sputtered amorphous Fe-Co Tb-films with perpendicular and in-plane magnetic anisotropy were investigated by wide- and small angle neutron scattering. By combination with X-ray data the maxima in the pair correlation function could be attributed to the individual atomic pairs. Thus also partial coordination numbers and a short range order parameter could be determined. Wide angle diffraction revealed that the film with magnetic in-plane anisotropy contained 13 atomic percent hydrogen. The hydrogen incorporation causes substantial changes in the short range order, associated with enhanced formation of Tb-rich clusters, and the in-plane anisotropy. The clustering effect was confirmed by results from small angle scattering with polarized neutrons

1997 ◽  
Vol 12 (8) ◽  
pp. 2117-2126 ◽  
Author(s):  
Hyun M. Jang ◽  
Su-Chan Kim

The limitation of the long-range order parameter and the necessity of the short-range order parameter for the thermodynamic description of Pb()O3-type perovskites are discussed. Based on the discussion, a statistical thermodynamic model that takes into account the configuration of the neighboring B-site ions (B′ and B″ cations) was developed. A pair-correlation approximation was used in the calculation of the configurational entropy and the long-range coulombic interaction energy between the nearest B-site ions. The theoretical calculations using Pb(Sc1/2Ta1/2)O3 (PST) and Pb(Sc1/2Nb1/2)O3 (PSN) systems indicate that the short-range order parameter persists over a wide range of temperatures examined (0–1800 K) and that there possibly occur consecutive long-range order-disorder transitions in the configuration of B-site cations. The possibility of the existence of short-range ordering above the long-range order-disorder transition temperature was also examined using the annealed PSN specimen as a typical example of Pb()O3-type perovskites.


1981 ◽  
Vol 36 (8) ◽  
pp. 880-885 ◽  
Author(s):  
W. Hoyer ◽  
B. Kunsch ◽  
M. Suda ◽  
E. Wieser

Abstract Neutron scattering results on Se1-xTex melts (x = 0.3, 0.6, 0.8) obtained at 460 °C are combined with earlier X-ray diffraction data. The behaviour of the number and distance of nearest neighbours is discussed with respect to chemical short-range order and transition from twofold to three-fold coordination. For Se70Te30 the radial concentration correlation function 4πr2 ρcc(r) has been evaluated. It shows clearly the preferred formation of unlike pairs (Se-Te) within the chains.


1989 ◽  
Vol 156-157 ◽  
pp. 174-176 ◽  
Author(s):  
A. Menelle ◽  
R. Bellissent ◽  
A.M. Flank

2013 ◽  
Vol 46 (5) ◽  
pp. 1361-1371 ◽  
Author(s):  
B. Hammouda ◽  
D. F. R. Mildner ◽  
A. Brûlet ◽  
S. Desert

Neutron focusing leads to significant gains in flux-on-sample in small-angle neutron scattering and very small angle neutron scattering instruments. Understanding the out-of-focus condition is necessary for less than optimal conditions such as for short instruments and low neutron wavelengths. Neutron focusing is investigated using a three-pronged approach. The three methods are analytical calculations, resolution measurements and computer simulations. A source aperture containing a single small-size hole and a sample aperture containing multiple holes are used to produce multiple spots on the high-resolution neutron detector. Lens focusing elongates off-axis spots in the radial direction. The standard deviation for the size of each spot is estimated using these three approaches. Varying parameters include the neutron wavelength, the number of focusing lenses and the location of holes on the sample aperture. Enough agreement for the standard deviation of the individual neutron beams was found between the calculations and the measurements to give confidence in this approach. Good agreement was found between the standard deviations obtained from calculations and simulations as well. Excellent agreement was found for the mean location of these individual spots.


1995 ◽  
Vol T57 ◽  
pp. 107-111 ◽  
Author(s):  
M Pionke ◽  
W Schweika ◽  
T Springer ◽  
R Sonntag ◽  
D Hohlwein

JETP Letters ◽  
2005 ◽  
Vol 81 (6) ◽  
pp. 292-295 ◽  
Author(s):  
N. K. Chumakov ◽  
V. V. Tugushev ◽  
S. V. Gudenko ◽  
O. A. Nikolaeva ◽  
V. N. Lazukov ◽  
...  

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