The EPR Zero-Field Splitting D and its Pressure and Temperature Dependence for Trigonal Mn2+ Centers in [Zn(H2O)6](BF4)2:Mn2+ Crystal
2006 ◽
Vol 61
(5-6)
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pp. 289-292
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The EPR zero-field splitting D (= b02 ) and its pressure and temperature dependence for trigonal Mn2+ centers in low and room temperature phases in [Zn(H2O)6](BF4)2 :Mn2+ crystal are studied by a high-order perturbation formula based on the dominant spin-orbit coupling mechanism. From the studies, the local trigonal distortion angles, the local angular compressibilities and the local angular thermal expansion coefficients for Mn2+ centers in both phases of the [Zn(H2O)6](BF4)2 crystal are estimated. The results are discussed
2004 ◽
Vol 59
(12)
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pp. 961-963
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1997 ◽
Vol 9
(24)
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pp. 5081-5088
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1986 ◽
Vol 84
(8)
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pp. 4142-4145
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2010 ◽
Vol 645-648
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pp. 403-406
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1994 ◽
Vol 49
(11)
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pp. 1013-1015
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