Thermal Stability of FeS2 Cathode Material in “Thermal” Batteries: Effect of Dissolved Oxides in Molten Salt Electrolytes

2008 ◽  
Vol 63 (9) ◽  
pp. 596-602 ◽  
Author(s):  
Patrick J. Masset

The thermal stability of FeS2 cathode material for thermal batteries is investigated in the LiCl-KCl eutectic containing up to 10 wt% Li2O (used as anti-peak). The results show that the decomposition of pyrite shifts to higher temperatures in the presence of molten salts as the S2 gas is repressed by the liquid phase. For high lithium oxide contents the decomposition temperature of pyrite decreases by 100 °C. In addition Li2FeS2 as reaction product is evidenced whereas Li3Fe2S4 is expected from literature data.

2014 ◽  
Vol 1073-1076 ◽  
pp. 66-72
Author(s):  
Wei Zhai ◽  
Guang Ming Liu ◽  
Fei Yu ◽  
Yuan Kui Wang

In this paper, additive A and additive B were added into Hitec molten salts in order to optimize the properties of the molten salt. The melting point, latent heat of phase transformation, specific heat capacity, thermal gravity, and thermal stability of the modified Hitec molten salt was characterized. The results showed that compare to Hitec molten salt the modified Hitec molten salt showed low melting point, proper latent heat of phase transformation, greater heat of fusion, wide using temperature range and other advantages. The modified molten salt had good thermal properties and thermal stability. This modified Hitec molten salt has good application prospect in the aspect of high temperature heat storage/transfer.


Author(s):  
Hongtao Zhang ◽  
Youjing Zhao ◽  
Jingli Li ◽  
Lijie Shi ◽  
Min Wang

AbstractThis paper focuses on thermal stability of molten salts, operating temperature range and latent heat of molten salts at a high temperature. In this experiment, multi-component molten salts (purified Solar Salt) composed of purified NaNO


2020 ◽  
Vol 49 (11) ◽  
pp. 3570-3579
Author(s):  
Dickson O. Ojwang ◽  
Lennart Häggström ◽  
Tore Ericsson ◽  
Jonas Ångström ◽  
William R. Brant

Sodium content dictates the thermal stability, decomposition temperature and hydration degree of Prussian white.


2020 ◽  
Vol 990 ◽  
pp. 106-110
Author(s):  
Mohd Zulkifli Mohamad Noor ◽  
Mohamad Anas Mohd Azmi ◽  
Mohd Shaiful Zaidi Mad Desa ◽  
Mohd Bijarimi Mat Piah ◽  
Azizan Ramli

Neoprene reinforced polymer has become an attraction in current research and development of new material blend. In this invention, neoprene was chosen to be enhance to polyurethane because of their superior properties that possess extraordinary mechanical, electrical, optical and thermal properties on prosthetic foot. In this research, polyurethane was chosen due to good rigidity, easy processing and low cost. The reinforcement polyurethane with neoprene is expected to improve the properties of polyurethane. The objective of this research was conducted to investigate the effect of neoprene contents on thermal properties of polyurethane reinforced neoprene on prosthetic foot. The effect of neoprene on thermal properties neoprene reinforced polyurethane was analysed in term of its thermal stability by thermal gravimetric analysis (TGA). Moreover, the visual of small topographic details on the surface of polyurethane/neoprene blends will be examined by scanning electron microscope (SEM). Based on result, the thermal properties show the great enhancement at high neoprene contents which is 1.0wt%. The thermal stability of polyurethane reinforced neoprene improves when the temperature where decomposition starts to occurs are higher than decomposition temperature of pure polyurethane. Then, thermal conductivity of polyurethane shows the great improvement after the addition of neoprene. Lastly, the smooth surface and visible of sheets pattern on surface represent the present of neoprene disperse into polymer that enhance brittleness. Thus, the presence of neoprene has clearly enhanced the thermal stability of the polyurethane. Table 1 shows formulation of neoprene and polyurethane.


Sign in / Sign up

Export Citation Format

Share Document