Metal Tetrahydroborates and Tetrahydroborato Metalates, 15 [1]. An 11B and 113Cd NMR Study of MBH4–CdCl2 Systems in Dimethylformamide and the X-Ray Structure of CdCl2 · 2 DMF
1990 ◽
Vol 45
(11)
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pp. 1463-1471
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Keyword(s):
X Ray
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CdCl2 dissociates in dimethylformamide into the species Cd(DMF)62+, CdCl(DMF)5+ and CdCl3- as determined by 113Cd NMR spectroscopy. 11B and 113Cd NMR spectra of MBH4/CdCl2 solutions in this solvent show the presence of complexes [CdCl2-n(BH4)n+1]- with rapid exchange of BH4- and Cl- at ambient temperature. There is no evidence that Cd(BH4)2 is formed in a metathetical reaction.The crystal structure of CdCl2 · 2 DMF has been determined. It is a coordination polymer containing hexacoordinated Cd atoms with the DMF molecules in cis-position. Coordination of DMF occurs via the carbonyl oxygen atoms.
1982 ◽
Vol 60
(11)
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pp. 1304-1316
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2000 ◽
Vol 55
(7)
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pp. 576-582
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Keyword(s):
2009 ◽
Vol 74
(11)
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pp. 1249-1258
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1997 ◽
Vol 62
(5)
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pp. 746-751
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