Zur Kristallchemie der Barium-Oxometallat-Tellurite: Ba2M6Te2O21 (M = Niob und Tantal) / On the Crystal Chemistry of the Barium Oxometallate-Tellurites Ba2M6Te2O21 (M = Niobium and Tantalum)
1996 ◽
Vol 51
(10)
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pp. 1411-1414
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Keyword(s):
X Ray
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Single crystals of Ba2Nb6Te2O21 (I) and Ba2Ta6Te2O21 (II) have been prepared by solid state reactions in air. X-ray investigations led to monoclinic symmetry, space group C32h -C2/m, (I): a = 16.699(3), b = 5.671(2), c = 9.611(2) Å, β = 96.92(2), (II): a = 16.655(8), b = 5.667(2), c = 9.576(4) Å, β = 96.64(7), Z = 2. Nb5+ or Ta5+ show octahedral and Te4+ a one sided triangular coordination by O2- . The position and distance of the lone pair on Te4+ have been estimated by calculations of the Coulomb terms of the lattice energy. The polyhedron around Ba2+ may be described by a triply capped BaO8 cube. The crystal structures are dominated by a 3∞ [Nb6O21]12- network with incorporated Ba2+ and Te4+ ions.
1996 ◽
Vol 51
(6)
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pp. 817-821
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1997 ◽
Vol 52
(8)
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pp. 989-993
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1994 ◽
Vol 49
(11)
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pp. 1463-1466
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1996 ◽
Vol 51
(4)
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pp. 489-492
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