The Silver(I) Mercury(II) Oxide Nitrate with the Empirical Formula AgHg2NO5
1999 ◽
Vol 54
(12)
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pp. 1489-1494
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Keyword(s):
The title compound was prepared by solid state reaction of Ag2O with Hg(NO3)2· H2O in air at 350 °C. Its crystal structure was determined from single-crystal diffractometer data: Pnma, a = 620.1(1) pm, b = 670.1(1) pm, c = 1267.5(2) pm, Z = 4, R = 0.026 for 586 structure factors and 33 variable parameters. The compound may be represented by the formula Ag(HgO)2NO3 . The mercury(II) together with the oxygen atoms form zig-zag chains with linear coordination of the mercury atoms. The oxygen atoms of these chains are linked via silver(I) atoms, thus forming two-dimensionally infinite nets, which contain the trigonal planar nitrate groups in interstices. Thus, only secondary Hg-O and Ag-O bond are formed between the nets.
2014 ◽
Vol 70
(2)
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pp. i9-i10
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Keyword(s):
1995 ◽
Vol 50
(2)
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pp. 196-200
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2015 ◽
Vol 71
(10)
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pp. 1255-1258
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Keyword(s):
2015 ◽
Vol 71
(5)
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pp. 558-560
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Keyword(s):
2007 ◽
Vol 62
(1)
◽
pp. 1-4
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2016 ◽
Vol 72
(8)
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pp. 1143-1146
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Keyword(s):