Hexaphosphaferrocene [Fe(η5-P3C2tBu2)2] as a Connecting Moiety in Oligomeric and Polymeric Compounds

2009 ◽  
Vol 64 (11-12) ◽  
pp. 1429-1437 ◽  
Author(s):  
Andrea Schindler ◽  
Manfred Zabel ◽  
John F. Nixon ◽  
Manfred Scheer
Keyword(s):  
Dynamic Behaviour ◽  
Stoichiometric Ratio ◽  
Ladder Structure ◽  
Polymeric Compound ◽  
One Dimensional ◽  
Polymeric Compounds

The hexaphosphaferrocene complex [Fe(η5-P3C2tBu2)2] (1) derived from the corresponding 1,2,4-triphosphospholyl anion reacts with CuX (X = Cl, Br, I) in a 1 : 1 stoichiometry to give the isostructural, one-dimensional polymeric compounds [{Cu(μ3-X)}4{Fe(μ,η5:η1-P3C2tBu2)2}2]n (X = Cl (2), Br (3), I (4)), which display a unique sinusoidal (CuX)n ladder structure. In the reaction with CuI a second one-dimensional polymeric compound [{Cu3(μ-I)(μ3-I)2}(CH3CN){Fe(μ,η5:η1- P3C2tBu2)(μ3,η5:η1-P3C2tBu2)}]n (5) is formed. The reaction of 1 with CuX (X= Cl, Br, I) in a 1 : 2 stoichiometric ratio leads only in the case of CuCl to the formation of the new, oligomeric compound [{Cu(μ3-Cl)}4(CH3CN)2{Fe(μ,η5:η1-P3C2tBu2)2}2] (6), whereas in the case of CuBr and CuI the polymeric compounds 3 and 5 were isolated. The reaction of 1 with Ag[Al{OC(CF3)3}4] in a 1:1 stoichiometric ratio results in the formation of [Ag{Fe(μ,η5:η1-P3C2tBu2)2}2][Al{OC(CF3)3}4] (7), which shows dynamic behaviour in solution

scholarly journals Synthesis and Structural Characterization of (E)-4-[(2-Hydroxy-3-methoxybenzylidene)amino]butanoic Acid and Its Novel Cu(II) Complex

Molbank ◽  
10.3390/m1179 ◽  
2021 ◽  
Vol 2021 (1) ◽  
pp. M1179
Author(s):  
Eleftherios Halevas ◽  
Antonios Hatzidimitriou ◽  
Barbara Mavroidi ◽  
Marina Sagnou ◽  
Maria Pelecanou ◽  
...  
Keyword(s):  
Schiff Base ◽  
Gamma Aminobutyric Acid ◽  
X Ray Diffraction ◽  
Reaction Conditions ◽  
Polymeric Compound ◽  
Bridging Ligands ◽  
1H And 13C Nmr ◽  
One Dimensional ◽  
Ft Ir

A novel Cu(II) complex based on the Schiff base obtained by the condensation of ortho-vanillin with gamma-aminobutyric acid was synthesized. The compounds are physico-chemically characterized by elemental analysis, HR-ESI-MS, FT-IR, and UV-Vis. The complex and the Schiff base ligand are further structurally identified by single crystal X-ray diffraction and 1H and 13C-NMR, respectively. The results suggest that the Schiff base are synthesized in excellent yield under mild reaction conditions in the presence of glacial acetic acid and the crystal structure of its Cu(II) complex reflects an one-dimensional polymeric compound. The molecular structure of the complex consists of a Cu(II) ion bound to two singly deprotonated Schiff base bridging ligands that form a CuN2O4 chelation environment, and a coordination sphere with a disordered octahedral geometry.

Polysulfonylamine, CXXV [1]. Neue Komplexe von Disulfonylaminen mit Kronenethern - im voraus entworfen oder zufällig entdeckt / Polysulfonylamines, CXXV [1]. New Complexes of Disulfonylam ines with Crown Ethers - Preconceived or Discovered by Serendipity

2000 ◽  
Vol 55 (3-4) ◽  
pp. 299-316 ◽  
Author(s):  
Dagmar Henschel ◽  
Karna Wijaya ◽  
Oliver Moers ◽  
Armand Blaschette ◽  
Peter G. Jones
Keyword(s):  
Hydrogen Bonds ◽  
X Ray Diffraction ◽  
Ladder Structure ◽  
Triclinic Space Group ◽  
One Dimensional ◽  
X Ray ◽  
Bonding System ◽  
Supramolecular Aggregate ◽  
Guest Species ◽  
The One

Abstract In a study aim ed at the „deconstruction“ of the supramolecular aggregate 3(18C6) · 2HN( SO2Me)2 (1,18C6 = 18-crown-6), which is known to display a ladder structure with two isotactic [18C6 - Me SO2N(H)SO2Me···)∞ polymers forming the uprights and symmetrically N - H···O bonded 18C6 rings providing the rungs, the following crystalline complexes were isolated and (except for 2b) characterized by low-temperature X-ray diffraction: 18C6-ClN (SO2Me)2 (2a, triclinic, space group P1̅, Z = 2), 18C6-PhN (SO2Me)2 (2b), 18C6 -MeN(SO2Me)2 (3, monoclinic, P21/c, Z = 8), Bz18C6-HN(SO2Me)2 (4, Bz18C6 = benzo-18-crown-6, monoclinic, P21/n, Z = 4), 18C6-2 MeN (SO2Me)2 (5, triclinic, P1̅, Z = 1), 18C6-Me2SO- HN( SO2Me) (SO2Ph) (13, triclinic, P1̅, Z = 2), and 18C6-H2OMe2SO·2HN(SO2Me)2 (14, triclinic, P1̅, Z = 2). Each of the one-dimensional polymers 2a (syndiotactic), 3 (disyndiotactic) and 4 (isotactic) mimics a single upright of 1; in contrast to 1 and 2a, where the intra-catemer connectivity solely relies on S - Me ··· crow n and crown ··· O = S hydrogen bonds, this bonding system is reinforced in 3 by N -Me ··· crown and in 4 by N - H ··· crown hydrogen bonds. Complex 5 is monomeric and matches a fragment formally extruded from the catemer 3; moreover, 3 and 5 represent a rare case of two structurally characterized 18C6 complexes containing the same uncharged guest species in distinct molecular ratios. The surprising structure of the quaternary adduct 14 exhibits an [18C6 ··· MeSO2N(H)SO2Me ··· ]∞ chain, which can be regarded both as an isolated, though unmodified upright from the ladder 1 and, being syndiotactic, as a stereochemical analogue of 2a; the potentially rung-forming *NH functions in the chain are blocked by hydrogenbonded side chains of the type * N - H ··· water ··· sulfoxide ··· H - N (SO2Me)2. The ternary complex 13 consists of chains [18C6 ··· Me2SO ··· H - N (SO2Ph)SO2Me···]∞ and is not closely related to the other structures

Numerical Simulation of Thermal and Fluid-Dynamic Behaviour of Reciprocating Compressor

2000 ◽  
Author(s):  
Zhilong He ◽  
Xueyuan Peng ◽  
Pengcheng Shu
Keyword(s):  
Numerical Simulation ◽  
Fluid Flow ◽  
Heat Balance ◽  
Dynamic Behaviour ◽  
Fluid Dynamic ◽  
Reciprocating Compressor ◽  
One Dimensional ◽  
Compressor Design ◽  
Suction Line ◽  
Hermetic Compressor

Abstract This paper presents a numerical method for simulating the thermal and fluid-dynamic behavior of hermetic compressors in the whole compressor domain. The model of fluid flow is developed by integrating transient one-dimensional conservation equations of continuity, momentum and energy through all of the elements from suction line to discharge line. The model describing thermal behavior is based on heat balance in the components such as muffler, connecting tubes and orifices. The calculation of the thermodynamic and transport properties for different refrigerants at various conditions has been considered, and some numerical results for a hermetic compressor are presented. The present study has demonstrated that the numerical simulation is a fest and reliable tool for compressor design.

scholarly journals Polar state induced by block-type lattice distortions in BaFe2Se3 with quasi-one-dimensional ladder structure

2019 ◽  
Vol 99 (24) ◽  
Author(s):  
Takuya Aoyama ◽  
Satoshi Imaizumi ◽  
Takuya Togashi ◽  
Yoshifumi Sato ◽  
Kazuki Hashizume ◽  
...  
Keyword(s):  
Block Type ◽  
Ladder Structure ◽  
One Dimensional ◽  
Polar State ◽  
Lattice Distortions ◽  
Type Lattice

A one-dimensional coordination polymer with a three-dimensional supramolecular framework:catena-poly[[[(3,4,7,8-tetramethyl-1,10-phenanthroline)cadmium(II)]-μ3-4,4′-sulfonyldibenzoato] trihydrate]

2013 ◽  
Vol 69 (3) ◽  
pp. 241-243 ◽  
Author(s):  
Jun Wang ◽  
Jian-Qing Tao ◽  
Xiao-Juan Xu ◽  
Chun-Yun Tan
Keyword(s):  
Three Dimensional ◽  
Water Molecules ◽  
X Ray Diffraction ◽  
Polymeric Compound ◽  
Chain Polymer ◽  
One Dimensional ◽  
X Ray ◽  
Carboxylate Groups ◽  
Metal Organic ◽  
Coordination Patterns

In the title mixed-ligand metal–organic polymeric compound, {[Cd(C14H8O6S)(C16H16N2)]·3H2O}n, the asymmetric unit contains a crystallographically unique CdIIatom, one doubly deprotonated 4,4′-sulfonyldibenzoic acid (H2SDBA) ligand, one 3,4,7,8-tetramethyl-1,10-phenanthroline (TMPHEN) molecule and three solvent water molecules. Each CdIIcentre is six-coordinated by two O atoms from a chelating carboxylate group of a SDBA2−ligand, two O atoms from monodentate carboxylate groups of two different SDBA2−ligands and two N atoms from a chelating TMPHEN ligand. There are two coordination patterns for the carboxylate groups of the SDBA2−ligand, with one in a μ1-η1:η1chelating mode and the other in a μ2-η1:η1bis-monodentate mode. Single-crystal X-ray diffraction analysis revealed that the title compound is a one-dimensional double-chain polymer containing 28-membered rings based on the [Cd2(CO2)2] rhomboid subunit. More interestingly, a chair-shaped water hexamer cluster is observed in the compound.

Mechanically flexible polymeric compound one-dimensional photonic crystals for terahertz frequencies

2010 ◽  
Vol 96 (11) ◽  
pp. 111108 ◽  
Author(s):  
Christian Jansen ◽  
Steffen Wietzke ◽  
Victoria Astley ◽  
Daniel M. Mittleman ◽  
Martin Koch
Keyword(s):  
Photonic Crystals ◽  
Polymeric Compound ◽  
One Dimensional ◽  
Terahertz Frequencies

Theoretical Foucault Images of Superconducting Fluxons

1997 ◽  
Vol 3 (S2) ◽  
pp. 509-510
Author(s):  
M. Beleggia ◽  
G. Pozzi ◽  
K. Harada ◽  
H. Kasai ◽  
T. Matsuda ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Dynamic Behaviour ◽  
Structural Defects ◽  
Experimental Conditions ◽  
Transmitted Beam ◽  
Factors Affecting ◽  
One Dimensional ◽  
Flux Lines ◽  
Main Disadvantage ◽  
Individual Flux

Individual flux lines in superconducting specimens have been recently observed using a 300kV holography electron microscope equipped with a cold field emission gun in the transmission mode by means of the out-of-focus method. In this way it has been possible to observe the dynamic behaviour of fluxons depending upon the variations of the temperature and/or the applied magnetic field or current. The main disadvantage of this method is that correlation with structural defects is troublesome owing to the large defocus distance (of the order of 1 cm for conventional superconductors) necessary for the detection of flux lines.This drawback is not present in the Foucault technique, where the contrast is generated in the focused image by masking part of the transmitted beam by means of an aperture. Therefore, some preliminary calculations have been made recently using one-dimensional models, which allow for a quick and easy simulation of the factors affecting the experimental conditions .

scholarly journals Stability Boundaries in Laterally-Coupled Pairs of Semiconductor Lasers

Photonics ◽  
2019 ◽  
Vol 6 (2) ◽  
pp. 74
Author(s):  
Martin Vaughan ◽  
Hadi Susanto ◽  
Nianqiang Li ◽  
Ian Henning ◽  
Mike Adams
Keyword(s):  
Semiconductor Lasers ◽  
Normal Mode ◽  
Dynamic Behaviour ◽  
Normal Modes ◽  
Stability Boundaries ◽  
Pumping Rate ◽  
One Dimensional ◽  
Coupled Mode ◽  
Normal Mode Theory ◽  
Laser Separation

The dynamic behaviour of coupled pairs of semiconductor lasers is studied using normal-mode theory, applied to one-dimensional (slab) and two-dimensional (circular cylindrical) real index confined structures. It is shown that regions of stable behaviour depend not only on pumping rate and laser separation, but also on the degree of guidance in the structures. Comparison of results between normal-mode and coupled-mode theories for these structures leads to the tentative conclusion that the accuracy of the latter is determined by the strength of self-overlap and cross-overlap of the symmetric and antisymmetric normal modes in the two lasers.

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