Sorption modelling by Gibbs energy minimisation: Towards a uniform thermodynamic database for surface complexes of radionuclides
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SummaryRadionuclide sorption on mineral-water interfaces can be thermodynamically modelled, similar to solid-solution aqueous-solution systems (only in chemical elemental stoichiometry), if definitions of the standard and reference states, surface activity terms (SAT), and elemental stoichiometries of surface-bound species are unequivocally established. A pre-requisite is that a unique common value of the reference (site) density (Γ
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2000 ◽
Vol 72
(3)
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pp. 463-477
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1998 ◽
Vol 62A
(2)
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pp. 822-823
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2016 ◽
Vol 58
(10)
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pp. 2095-2100
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2018 ◽
Vol 127
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pp. 1-7
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