scholarly journals Study of Thermodynamic Functions for Iron Monoboride FeB

2015 ◽  
Vol 16 (1) ◽  
pp. 136-139
Author(s):  
N. Yu. Filonenko
Keyword(s):  
Heat Capacity ◽  
High Temperature ◽  
Temperature Dependence ◽  
Binary Alloy ◽  
Thermodynamic Functions ◽  
Thermodynamic Potential ◽  
Thermodynamic Quantities ◽  
Zeroth Order ◽  
Temperature Expansion ◽  
High Temperature Expansion

The thermodynamic quantities for iron monoboride FeB, such as entropy, enthalpy, heat capacity and their temperature dependence, are considered. It is shown, that accounting for contribution to the zeroth-order high-temperature expansion of thermodynamic potential for Fe-B binary alloy enables to describe forming monoboride FeB in more complete way from the viewpoint of thermodynamics.

HIGH-TEMPERATURE SERIES FOR THERMODYNAMIC FUNCTIONS

2003 ◽  
Vol 02 (01) ◽  
pp. 1-5 ◽  
Author(s):  
FRANCISCO M. FERNÁNDEZ
Keyword(s):  
Free Energy ◽  
Perturbation Theory ◽  
High Temperature ◽  
Thermodynamic Functions ◽  
Temperature Series ◽  
Present Approach ◽  
Rigid Rotor ◽  
Temperature Expansion ◽  
High Temperature Expansion

We propose a high-temperature expansion for thermodynamic functions. As an example we calculate the free energy for a restricted plane rigid rotor and compare present approach with perturbation theory.

ABOUT HEAT CAPACITY OF TITANIUM CARBIDE TiCx

2019 ◽  
pp. 56-66
Author(s):  
I. Khidirov ◽  
V. V. Getmanskiy ◽  
A. S. Parpiev ◽  
Sh. A. Makhmudov
Keyword(s):  
Heat Capacity ◽  
High Temperature ◽  
Titanium Carbide ◽  
Temperature Dependence ◽  
Carbon Concentration ◽  
Room Temperature ◽  
Thermodynamic Characteristics ◽  
Liquid Nitrogen Temperature ◽  
Analysis Data ◽  
Thermal Excitation

This work relates to the field of thermophysical parameters of refractory interstitial alloys. The isochoric heat capacity of cubic titanium carbide TiCx has been calculated within the Debye approximation in the carbon concentration  range x = 0.70–0.97 at room temperature (300 K) and at liquid nitrogen temperature (80 K) through the Debye temperature established on the basis of neutron diffraction analysis data. It has been found out that at room temperature with decrease of carbon concentration the heat capacity significantly increases from 29.40 J/mol·K to 34.20 J/mol·K, and at T = 80 K – from 3.08 J/mol·K to 8.20 J/mol·K. The work analyzes the literature data and gives the results of the evaluation of the high-temperature dependence of the heat capacity СV of the cubic titanium carbide TiC0.97 based on the data of neutron structural analysis. It has been proposed to amend in the Neumann–Kopp formula to describe the high-temperature dependence of the titanium carbide heat capacity. After the amendment, the Neumann–Kopp formula describes the results of well-known experiments on the high-temperature dependence of the heat capacity of the titanium carbide TiCx. The proposed formula takes into account the degree of thermal excitation (a quantized number) that increases in steps with increasing temperature.The results allow us to predict the thermodynamic characteristics of titanium carbide in the temperature range of 300–3000 K and can be useful for materials scientists.

MONTE CARLO STUDY OF THE SPIN-1/2 HEISENBERG MODEL IN 1, 2, AND 3 DIMENSIONS

1991 ◽  
Vol 05 (13) ◽  
pp. 907-914 ◽  
Author(s):  
RICHARD J. CRESWICK ◽  
CYNTHIA J. SISSON
Keyword(s):  
Monte Carlo ◽  
High Temperature ◽  
Spin Wave ◽  
Heisenberg Model ◽  
Transition Probability ◽  
Lattice Models ◽  
Wave Theory ◽  
Temperature Expansion ◽  
High Temperature Expansion ◽  
Good Agreement

The properties of the spin-1/2 Heisenberg model on 1, 2, and 3-dimensional lattices are calculated using the Decoupled Cell Method of Homma et al., and these results are compared with high temperature and spin-wave expansions, and with other numerical approaches. The DCM has advantages over other Monte Carlo methods currently in wide use in that the transition probability is positive definite, there is no need to introduce an additional imaginary time, or Trotter, dimension, and the acceptance rate for transitions is comparable to that of classical lattice models. We find very good agreement between the DCM and the high temperature expansion in the temperature region where the high temperature expansion is valid, and reasonably good agreement at low temperatures with spin wave theory. The DCM fails for temperatures T < Tc which decreases with the size of the cell.

scholarly journals Temperature dependence of the specific heat and thermodynamic functions AК1М2 alloy, doped strontium

2019 ◽  
Vol 21 (1) ◽  
pp. 35-42 ◽  
Author(s):  
I. N. Ganiev ◽  
S. E. Otajonov ◽  
N. F. Ibrohimov ◽  
M. Mahmudov
Keyword(s):  
Heat Capacity ◽  
Gibbs Energy ◽  
Specific Heat ◽  
Temperature Dependence ◽  
Specific Heat Capacity ◽  
Thermodynamic Functions ◽  
Inverse Relationship ◽  
Alloying Element ◽  
Enthalpy And Entropy ◽  
Increasing Temperature

In the heat «cooling» investigated the temperature dependence of the specific heat capacity and thermodynamic functions doped strontium alloy AK1М2 in the range 298,15—900 K. Mathematical models are obtained that describe the change in these properties of alloys in the temperature range 298.15—900 K, as well as on the concentration of the doping component. It was found that with increasing temperature, specific heat capacity, enthalpy and entropy alloys increase, and the concentration up to 0.5 wt.% of the alloying element decreases. Gibbs energy values have an inverse relationship, i.e., temperature — decreases the content of alloying component — is up to 0.5 wt.% growing.

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