scholarly journals Reactions of Chiral N-Tert-Butanesulfinyl Imines with Ethyl Nitroacetate

2017 ◽  
Vol 1 (6) ◽  
Author(s):  
Miguel Yus ◽  
Francisco Foubelo
Keyword(s):  
Ethyl Nitroacetate

Enantioselective total synthesis of the highly selective sphingosine-1-receptor VPC01091 by the Heck desymmetrization of a non-activated cyclopentene-fused spiro-pyrrolidinone

2016 ◽  
Vol 14 (40) ◽  
pp. 9476-9480 ◽  
Author(s):  
Ismat Ullah Khan ◽  
Shivashankar Kattela ◽  
Abbas Hassan ◽  
Carlos Roque Duarte Correia
Keyword(s):  
Total Synthesis ◽  
Enantioselective Total Synthesis ◽  
Ethyl Nitroacetate

The total synthesis of VPC01091 was accomplished in a concise manner, in a good overall yield of 40% from ethyl nitroacetate and 94% ee.

scholarly journals Synthesis and Single Crystal X-Ray Structure of Bis[4-oxo-3- (2-ethoxycarbonylphenyl)-3,4-dihydroquinazolin-2-yl]disulfide

2009 ◽  
Vol 64 (9) ◽  
pp. 1065-1069 ◽  
Author(s):  
Mehdi Rimaz ◽  
Jabbar Khalafy ◽  
Khadijeh Tavana ◽  
Katarzyna Ślepokura ◽  
Tadeusz Lis ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Single Crystal ◽  
Elemental Analysis ◽  
Structure Determination ◽  
Room Temperature ◽  
Sodium Ethoxide ◽  
Reaction Conditions ◽  
X Ray ◽  
Ethyl Nitroacetate ◽  
C Nmr

Diethyl 2,2´-thiocarbonyl-bis(azanediyl)dibenzoate was synthesized from the reaction of ethyl anthranilate with thiophosgene. Its treatment with sodium ethoxide in ethanol at room temperature gave ethyl 2-(4-oxo-2-thioxo-1,2-dihydroquinazolin-3(4H)-yl) benzoate, whereas in the presence of ethyl nitroacetate and under the same reaction conditions, the corresponding bis(quinazolin)disulfide was formed. Its structure was confirmed by IR, 1H and 13C NMR spectroscopy elemental analysis and single crystal X-ray structure determination.

Divergent behaviour in the isocyanate-induced and thermal generation of nitrile oxides from ethyl nitroacetate

1994 ◽  
Vol 35 (49) ◽  
pp. 9251-9254 ◽  
Author(s):  
Morag G. Leslie-Smith ◽  
R.Michael Paton ◽  
Nigel Webb
Keyword(s):  
Thermal Generation ◽  
Nitrile Oxides ◽  
Ethyl Nitroacetate

ChemInform Abstract: Formation of γ-Oxoacids and 1H-Pyrrol-2(5H)-ones from α,β-Unsaturated Ketones and Ethyl Nitroacetate.

ChemInform ◽  
2011 ◽  
Vol 42 (8) ◽  
pp. no-no
Author(s):  
Maialen Aginagalde ◽  
Tamara Bello ◽  
Carme Masdeu ◽  
Yosu Vara ◽  
Ana Arrieta ◽  
...  
Keyword(s):  
Unsaturated Ketones ◽  
Ethyl Nitroacetate

ChemInform Abstract: Ethyl Nitroacetate in Aza-Henry Addition on Trifluoromethyl Aldimines: A Solvent-Free Procedure to Obtain Chiral Trifluoromethyl α,β-Diamino Esters.

ChemInform ◽  
2016 ◽  
Vol 47 (32) ◽  
Author(s):  
Luca Parise ◽  
Alessia Pelagalli ◽  
Lucio Pellacani ◽  
Fabio Sciubba ◽  
Maria Cecilia Vergari ◽  
...  
Keyword(s):  
Solvent Free ◽  
Ethyl Nitroacetate

Ethyl Nitroacetate as a Useful Synthon for the Synthesis of Orthogonally Protected, Polyfunctional C[α,α]- Disubstituted Amino Acids

ChemInform ◽  
2003 ◽  
Vol 34 (21) ◽  
Author(s):  
Yanwen Fu ◽  
Lars G. J. Hammarstrom ◽  
Tod J. Miller ◽  
Mark L. McLaughlin ◽  
Robert P. Hammer
Keyword(s):  
Amino Acids ◽  
Ethyl Nitroacetate ◽  
Disubstituted Amino Acids
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