scholarly journals Phase Stresses as the Cause of Inhibiting Action for the Decomposition of a Metastable State in Superplastic Eutectic Alloys

2017 ◽  
Vol 39 (6) ◽  
pp. 839-854
Author(s):  
V. F. Korshak ◽  
Author(s):  
E. F. Koch ◽  
E. L. Hall ◽  
S. W. Yang

The plane-front solidified eutectic alloys consisting of aligned tantalum monocarbide fibers in a nickel alloy matrix are currently under consideration for future aircraft and gas turbine blades. The MC fibers provide exceptional strength at high temperatures. In these alloys, the Ni matrix is strengthened by the precipitation of the coherent γ' phase (ordered L12 structure, nominally Ni3Al). The mechanical strength of these materials can be sensitively affected by overall alloy composition, and these strength variations can be due to several factors, including changes in solid solution strength of the γ matrix, changes in they γ' size or morphology, changes in the γ-γ' lattice mismatch or interfacial energy, or changes in the MC morphology, volume fraction, thermal stability, and stoichiometry. In order to differentiate between these various mechanisms, it is necessary to determine the partitioning of elemental additions between the γ,γ', and MC phases. This paper describes the results of such a study using energy dispersive X-ray spectroscopy in the analytical electron microscope.


2021 ◽  
Vol 194 ◽  
pp. 113645
Author(s):  
Evan B. Baker ◽  
Sangho Jeon ◽  
Olga Shuleshova ◽  
Ivan Kaban ◽  
Yeqing Wang ◽  
...  

2021 ◽  
Author(s):  
Naotaka Yoshikawa ◽  
Hiroki Suganuma ◽  
Hideki Matsuoka ◽  
Yuki Tanaka ◽  
Pierre Hemme ◽  
...  

2021 ◽  
Vol 184 (1) ◽  
Author(s):  
Gianmarco Bet ◽  
Vanessa Jacquier ◽  
Francesca R. Nardi

AbstractWe consider the problem of metastability for stochastic dynamics with exponentially small transition probabilities in the low temperature limit. We generalize previous model-independent results in several directions. First, we give an estimate of the mixing time of the dynamics in terms of the maximal stability level. Second, assuming the dynamics is reversible, we give an estimate of the associated spectral gap. Third, we give precise asymptotics for the expected transition time from any metastable state to the stable state using potential-theoretic techniques. We do this in a general reversible setting where two or more metastable states are allowed and some of them may even be degenerate. This generalizes previous results that hold for a series of only two metastable states. We then focus on a specific Probabilistic Cellular Automata (PCA) with configuration space $${\mathcal {X}}=\{-1,+1\}^\varLambda $$ X = { - 1 , + 1 } Λ where $$\varLambda \subset {\mathbb {Z}}^2$$ Λ ⊂ Z 2 is a finite box with periodic boundary conditions. We apply our model-independent results to find sharp estimates for the expected transition time from any metastable state in $$\{\underline{-1}, {\underline{c}}^o,{\underline{c}}^e\}$$ { - 1 ̲ , c ̲ o , c ̲ e } to the stable state $$\underline{+1}$$ + 1 ̲ . Here $${\underline{c}}^o,{\underline{c}}^e$$ c ̲ o , c ̲ e denote the odd and the even chessboard respectively. To do this, we identify rigorously the metastable states by giving explicit upper bounds on the stability level of every other configuration. We rely on these estimates to prove a recurrence property of the dynamics, which is a cornerstone of the pathwise approach to metastability.


2008 ◽  
Vol 100 (25) ◽  
Author(s):  
Sergei B. Orlinskii ◽  
Jan Schmidt ◽  
Pavel G. Baranov ◽  
Matthias Bickermann ◽  
Boris M. Epelbaum ◽  
...  

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