scholarly journals Isoterm Sorpsi Air pada Tepung Ubi Jalar Terfermentasi dengan Angkak

2017 ◽  
Vol 3 (1) ◽  
pp. 71-78 ◽  
Author(s):  
Yulinda Eka Ayu Rukmawati ◽  
Sri Hartini ◽  
Margaretha Novian Cahyanti

The research was aimed to obtain moisture sorption curve , moisture sorption isotherm models and obtain determine the water content monoleyer of fermented sweet potato flour with red yeast rice.The moisture sorption isotherm model used are GAB (Guggenheim Anderson deBoer), BET (Brunauer Emmet Teller) and Caurie.Meanwhile, the test of modelling accuray by MRD (Mean Relative Deviation). The results showed that the water sorption isotherm curve of sweet potato flour fermented with red yeast rice Sigmoid shaped the approach of type II. The precise mathematical models are models of GAB (Guggenheim Anderson deBoer) with a value of MRD at a temperature of 30 °C, 35 °C, 40 °C respectively at 4.41%, to 2.50%, 3.37%. Moisture content of the monolayer at temperature of 30 °C, 35 °C and 40 °C in GAB model was 7.34%, 6.57%, 16.09%, BET model was 2.09%, 1.05%, 4.26%, and Caurie model was 1.41%, 1.36%, 1.42%.DOI: http://dx.doi.org/10.15408/jkv.v0i0.4814  

2017 ◽  
Vol 13 (1) ◽  
pp. 29 ◽  
Author(s):  
Mutiara Nur Alfiah ◽  
Sri Hartini ◽  
Margareta Novian Cahyanti

<p>This research aims to determine moisture sorption isotherm curves, moisture sorption isotherm models and thermodynamic properties of fermented cassava flour by red yeast rice. The moisture sorption isotherm model used are Guggenheim Anderson deBoer (GAB), Brunauer Emmet Teller (BET) and Caurie. Meanwhile, the test of modelling accuray by Mean Relative Deviation (MRD) and Root Mean Square Error (RMSE). The thermodynamic properties, i.e., enthalpy and entropy were calculated by Clausius - Clapeyron equation. The result shows that the moisture sorption isotherm curve on fermented cassava flour in a sigmoid form (type II). The GAB model is the best model for moisture sorption isotherm of fermented cassava flour by red yeast rice. The MRD and RMSE values at 30˚C, 35˚C and 40˚C are 3.12%, 2.71%, 3.81%, and 1.01, 0.35, 0.42, respectively. The monolayer moisture content at 30˚C, 35˚C and 40˚C are 6.61%, 6.27% and 6.91%, based on GAB model. Meanwhile, when the BET model was used, the monolayer moisture content are 4.92%, 4.86% and 5.19%, while by Caurie model are 6.37%, 6.18% and 5.30%, at 30˚C, 35˚C and 40˚C, respectively. The enthalpy and entropy of water sorption process were decreased when moisture content increased.</p>


2017 ◽  
Vol 13 (1) ◽  
pp. 29 ◽  
Author(s):  
Mutiara Nur Alfiah ◽  
Sri Hartini ◽  
Margareta Novian Cahyanti

<p>This research aims to determine moisture sorption isotherm curves, moisture sorption isotherm models and thermodynamic properties of fermented cassava flour by red yeast rice. The moisture sorption isotherm model used are Guggenheim Anderson deBoer (GAB), Brunauer Emmet Teller (BET) and Caurie. Meanwhile, the test of modelling accuray by Mean Relative Deviation (MRD) and Root Mean Square Error (RMSE). The thermodynamic properties, i.e., enthalpy and entropy were calculated by Clausius - Clapeyron equation. The result shows that the moisture sorption isotherm curve on fermented cassava flour in a sigmoid form (type II). The GAB model is the best model for moisture sorption isotherm of fermented cassava flour by red yeast rice. The MRD and RMSE values at 30˚C, 35˚C and 40˚C are 3.12%, 2.71%, 3.81%, and 1.01, 0.35, 0.42, respectively. The monolayer moisture content at 30˚C, 35˚C and 40˚C are 6.61%, 6.27% and 6.91%, based on GAB model. Meanwhile, when the BET model was used, the monolayer moisture content are 4.92%, 4.86% and 5.19%, while by Caurie model are 6.37%, 6.18% and 5.30%, at 30˚C, 35˚C and 40˚C, respectively. The enthalpy and entropy of water sorption process were decreased when moisture content increased.</p>


Author(s):  
J Roy ◽  
MA Alim ◽  
MN Islam

The study was carried out for the purpose of determining the drying kinetics as well as moisture sorption isotherm of hybrid-81 corn. Corn at about 31% moisture content (wb) was dried in a forced convective hot air cabinet dryer at different drying conditions, such as variable air dry bulb temperature (40°C, 50°C and 60°C) and loading density (3.56 kg/m2, 7.12 kg/m2, and 10.68 kg/m2) as well as in shining sun at different layers (3.56 kg/m2, 7.12 kg/m2, and 10.68 kg/m2). The water sorption isotherm of the dried corn was developed using vacuum desiccators, which contained saturated salt solutions in the range of 11-93% RHs. The mono-layer moisture content calculated by the Brunauer–Emmett–Teller (BET) model (6.76 g/100 g solid) was lesser than that calculated by the Guggenheim–Anderson–De Boer (GAB) model (10.53 g/100 g solid). The energy constants were 10.45 and 4.64 as per BET and GAB equation, respectively. Both models gave suitable fits for corn. The activation energy (Ea) for diffusion of water was found to be 11.09 kcal/gm-mole for corn. Furthermore, it was noticed that, with the increase of corn layer, the drying rate decreased in case of both sun and mechanical drying. However, higher loading density resulted in efficient drying, at least up to 10.7 kg/m2. It was shown that the drying time to obtain stability was the lowest for moisture content (12.08 %) corresponding to aw of 0.65 in case of BET or GAB monolayer moisture content. This finding could be helpful in predicting the storage life of corn.J. Bangladesh Agril. Univ. 15(2): 309-317, December 2017


2015 ◽  
Vol 40 (1) ◽  
pp. 35-51 ◽  
Author(s):  
Md Masud Alam ◽  
Md Nazrul Islam

The water sorption characteristics of dehydrated onion and onion solutes composite by vacuum drying (VD) and air drying (AD) were developed at room temperature using vacuum desiccators containing saturated salt solutions at various relative humidity levels (11-93%). From moisture sorption isotherm data, the monolayer moisture content was estimated by Brunauer-Emmett-Teller (BET) and Guggenheim-Anderson-de Boer (GAB) equation using data up to a water activity of 0.52 and 0.93 respectively. Results showed that in case of non treated samples the monolayer moisture content values (Wo) of BET gave slightly higher values than GAB (9.7 vs 8.2) for VD, while GAB gave higher value than BET (11.0 vs 9.8) for AD. It is also seen that the treated and non treated onion slice and onion powder absorbed approximately the same amount of water at water activities below about 0.44 and above 0.44 the treated samples begin to absorb more water than the non treated samples. It was observed that 10-20% added of sugar gave no change in water sorption capacity while the amount of sorbed water increases with increasing amount added salt for mix onion product.Bangladesh J. Agril. Res. 40(1): 35-51, March 2015


2015 ◽  
Vol 11 (6) ◽  
pp. 833-840 ◽  
Author(s):  
Seyedehzahra Ghazihoseini ◽  
Niloofar Alipoormazandarani ◽  
Abdorreza Mohammadi Nafchi

In this research, a novel polysaccharide-based bionanocomposite film was prepared via dispersion casting method. Nano-silicon dioxide (SiO2-N) was incorporated into soluble soybean polysaccharide (SSPS) at different concentrations (i.e., 0%, 1%, 3%, and 5% w/w dried SSPS). Mechanical (tensile strength, elongation at break, and Young’s modulus), physical (moisture content, water solubility, and moisture uptake), and barrier properties of bionanocomposite films were evaluated. Incorporation of 5% SiO2-N to SSPS matrix decreased water vapor permeability (WVP) from 7.96×10−11 to 4.75×10−11 g m−1 s−1 Pa−1 and oxygen permeability from 215 to 96 cm3 µm m−2 day−1 atm−1. Heat seal strength and mechanical properties of SSPS films were improved. Moisture sorption isotherm of SSPS films supported by SiO2-N was shifted to lower moisture content, and monolayer moisture content of the films decreased significantly (p<0.05). In summary, SiO2-N is a potential filler in SSPS-based films for packaging materials.


2020 ◽  
Vol 24 (1) ◽  
pp. 1-5
Author(s):  
Vangelce Mitrevski ◽  
Cvetanka Mitrevska ◽  
Mirko Babić ◽  
Borce Mitrevski

2019 ◽  
Vol 27 (9) ◽  
pp. 536-545
Author(s):  
AA Mohamed ◽  
MS Alamri ◽  
S Hussain ◽  
MA Ibraheem ◽  
Akram A Abdo Qasem

The moisture sorption isotherm of wheat gluten/epoxydized sesame or sunflower oil resin was determined at 25, 40, and 55°C. The resin was prepared by cross-linking epoxydized oil and wheat gluten using 1, 2, and 3% zinc chloride as the catalyst. The experiment was carried out over 0.1–0.9 water activity ( a w) range using gravimetric sorption analyzer (Q 2000, TA Instruments, New Castle, PA, USA). The resin isotherms were found to be type III shape where the equilibrium moisture content (EMC) was higher at lower temperatures. The EMC of gluten epoxy resin was dependent on the degree of cross-linking because more cross-linking decreased EMC. The Guggenheim Anderson-de Boer (GAB) parameters support the theory of the free volume as it relates to monolayer absorption. This could be attributed to the decrease in the number of water binding sites due to the development of dense areas during cross-linking and increase in the free volume. The GAB and Brunauer–Emmett–Teller were found to be suitable for predicting the water sorption isotherm for gluten protein resin because it provided low root mean square error. The heat of sorption based on the Clausius–Clapeyron equation (qst) increased with decrease in moisture content.


2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
M. S. Alamri ◽  
A. A. Mohamed ◽  
S. Hussain ◽  
M. A. Ibraheem ◽  
Akram A. Abdo Qasem

Epoxy resin was prepared by crosslinking epoxidized oil and millet flour. The reaction was carried out at three different temperatures (25, 40, and 55°C) and zinc chloride levels (1, 2, and 3%). Moisture sorption isotherms were determined at 0.1 to 0.9 water activity (aw) using a gravimetric sorption analyzer (Q 2000). The sigmoidal shape (type II) of the resin isotherms exhibited lower equilibrium moisture content (EMC) at higher temperature. The experimental data were modeled using GAB (Guggenheim–Anderson–de Boer) and BET (Brunauer–Emmett–Teller). The EMC of the resin was significantly lower than that of the flour, which could be attributed to the decrease in the number of water-binding sites due to the creation of dense areas during crosslinking. The low root-mean-square error (RMSE) indicates that GAB and BET were suitable for predicting the water sorption isotherm for millet flour resin. The heat of sorption of the resin was large at low moisture content and increased at higher relative humidity. It is recommended that millet flour resin be used at relative humidity below 60%.


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