scholarly journals New data about the distribution of nickel, lead and chromium in the coal seams of the DonetskMakiivka geological and industrial district of the Donbas

2020 ◽  
Vol 29 (4) ◽  
pp. 722-730
Author(s):  
Mykola A. Kozar ◽  
Valerii V. Ishkov ◽  
Yevhen S. Kozii ◽  
Pavlo S. Pashchenko

A modern and scientifically based indicators forecast of toxic and potentially toxic element concentrations allows us to develop and plan organizational and technicaltechnological measures aimed at reducing the negative impact of the coal industry and heating enterprises on the ecological state of the environment. For this purpose it is necessary to have data about concentration, character and features of the distribution of toxic and potentially toxic elements, including nickel, lead and chromium in coal and the rocks that contain it. Toxic elements are one of the main sources of environmental pollution thatnegatively affects human health. Research in this direction is conducted to reduce the degree of negative effects and additional pollution of the environment. Increasing requirements for environmental protection in the coal-mining industry sector of Ukraine stipulates the need for new scientifically grounded methods for forecasting the content of toxic and potentially toxic elements in the rock mass which is extracted by mines, the waste of coal extraction and coal enrichment and also the influence of the coal-heating enterprises on the environment. In the article, the results of investigations of toxic elements in coal seams of the Donetsk-Makiivka geological and industrial area of the Donbas are considered. The research covered the whole territory of one of the most studied geological and industrial districts of the Donbas – Donetsk-Makiivka. As a result of the study, correlation coefficients were calculated that allow us to predict the concentration of nickel, lead and chromium in the products and wastes of coal enrichment and correct the technological schemes of coal enrichment taking into account their content. We also calculated the regression equation between these elements and the ash content of the coal, which will allow us to predict their concentration in the main working coal seams of the DonetskMakiivka geological and industrial districts relative to the values of coal ash content. The character of the distribution is established and the weighted average concentrations and basic descriptive statistics for nickel, lead, and chromium in the coal seams and suites are calculated. The composition and character of their typomorphic geochemical associations, as well as the features and regularities of their accumulation in the coal seams of the Donetsk-Makiivka geological and industrial districts are revealed.

Author(s):  
Pavlo Pashchenko ◽  
◽  
Yana Antipovych ◽  
Olga Karamushka

Purpose. Analysis of the distribution of mercury concentrations in the whole district; identification of links between mercury content and other toxic and potentially toxic elements, petrographic composition of coal and its main technological parameters. Methodology. The methods of mathematical statistics with the construction of histograms of distribution and dendrograms of clustering of coal seams of the region by Hg concentrations are also used in the work. Results. Peculiarities of distribution and the nature of mercury distribution in 56 coal seams, which belong to the suites С14, С21, С22, С23, С25, С26, and С27 of the lower and middle divisions of the coal period of the Krasnoarmeysk geologicalindustrial area, have been determined. Simple and cumulative histograms are constructed and analyzed. The calculations of the weighted average concentrations in the coal of the main layers and suites were performed, the composition of the typomorphic geochemical association of mercury with other toxic and potentially toxic elements in the coal of the region is clarified. The main factors influencing the mercury content in the nearest stratigraphic section of coal seams in the process of coal accumulation and epigenetic transformations of the coal seam were significantly varied. The average value of mercury content in coal of the main working seams of the area is significantly below the maximum allowable concentration in coal. In the district as a whole, there is no significant connection between mercury concentrations and ash content and sulfur content of total coal, at the same time there is an increase in mercury content with increasing degree of coal carbonization. Scientific novelty. The nature of the distribution and the main statistical indicators of mercury concentrations in the main coal seams and suites of the Krasnoarmeysky geological-industrial region of Donbass were established. A typomorphic geochemical association of mercury with other toxic and potentially toxic elements in the coal seams of the district has been established. Practical significance. The practical significance of the obtained results is to identify the absence of a significant relationship between mercury concentrations and ash content and sulfur content of total coal, as well as to calculate the regression equations between the elements included in the geochemical association with mercury. Key words: mercury, mine, coal height, coal ash content, depth, sulfur content, regression equation, correlation coefficient.


Author(s):  
Наталья Алексеевна Бойко ◽  
Наталья Владимировна Ромашева

Представлена характеристика угольной отрасли России по таким направлениям как организационная структура, объем и регионы добычи, потребители угля. Выявлены положительные тенденции, определены проблемы в развитии угольной промышленности. Исследованы негативное воздействие угольного производство на такие компоненты окружающей среды, как атмосферный воздух, водные ресурсы, земная поверхность. The characteristic of the Russian coal industry in such areas as the organizational structure, volume and regions of production, coal consumers has been presented. Positive trends and problems in the development of the coal industry have been identified. The negative impact of coal production on environmental components such as atmospheric air, water, the earth’s surface has been investigated.


Author(s):  
Shufeng She ◽  
Bifeng Hu ◽  
Xianglin Zhang ◽  
Shuai Shao ◽  
Yefeng Jiang ◽  
...  

Potentially toxic elements (PTEs) pollution in the agricultural soil of China, especially in developed regions such as the Yangtze River Delta (YRD) in eastern China, has received increasing attention. However, there are few studies on the long-term assessment of soil pollution by PTEs over large regions. Therefore, in this study, a meta-analysis was conducted to evaluate the current state and temporal trend of PTEs pollution in the agricultural land of the Yangtze River Delta. Based on a review of 118 studies published between 1993 and 2020, the average concentrations of Cd, Hg, As, Pb, Cr, Cu, Zn, and Ni were found to be 0.25 mg kg−1, 0.14 mg kg−1, 8.14 mg kg−1, 32.32 mg kg−1, 68.84 mg kg−1, 32.58 mg kg−1, 92.35 mg kg−1, and 29.30 mg kg−1, respectively. Among these elements, only Cd and Hg showed significant accumulation compared with their background values. The eastern Yangtze River Delta showed a relatively high ecological risk due to intensive industrial activities. The contents of Cd, Pb, and Zn in soil showed an increasing trend from 1993 to 2000 and then showed a decreasing trend. The results obtained from this study will provide guidance for the prevention and control of soil pollution in the Yangtze River Delta.


2021 ◽  
pp. 112285
Author(s):  
Neus González ◽  
Eudald Correig ◽  
Isa Marmelo ◽  
António Marques ◽  
Rasmus la Cour ◽  
...  

Author(s):  
Zahra Biglari Quchan Atigh ◽  
Pourya Sardari ◽  
Ebrahim Moghiseh ◽  
Behnam Asgari Lajayer ◽  
Andrew S. Hursthouse

Water ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 613
Author(s):  
Samantha Jiménez-Oyola ◽  
Kenny Escobar Segovia ◽  
María-Jesús García-Martínez ◽  
Marcelo Ortega ◽  
David Bolonio ◽  
...  

Anthropogenic activities performed in the Ecuadorian Amazon have released potentially toxic elements (PTEs) into the rivers, causing severe environmental pollution and increasing the risk of exposure to the residents of the surrounding areas. This study aims to carry out a human health risk assessment using deterministic and probabilistic methods to estimate the hazard index (HI) and total cancer risk (TCR) related to multi-pathway human exposure to PTEs in polluted rivers. Concentrations of Al, Cd, Cr, Cu, Hg, Ni, Pb, and Zn in surface water and sediment samples from rivers on the Ecuadorian Amazon were considered to assess the potential adverse human health effects. As a result, deterministic and probabilistic estimations of cancer and non-cancer risk through exposure to surface waters and sediments were above the safety limit. A sensitivity analysis identified the concentration of PTEs and the exposure duration (ED) as the two most important variables for probabilistic health risk assessment. The highest risk for receptors was related to exposure to polluted sediments through incidental ingestion and dermal contact routes. According to the deterministic estimation, the human health risk through ingestion of water was above the threshold in specific locations. This study reveals the potential health risk to which the population is exposed. This information can be used as a baseline to develop public strategies to reduce anthropogenic pollution and exposure to PTEs in Ecuadorian Amazon rivers.


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