Al-Doped ZnO Film as a Transparent Conductive Substrate in Indoline-Sensitized Nanoporous ZnO Solar Cell.

2012 ◽  
Vol 1494 ◽  
pp. 345-350
Author(s):  
B. Onwona-Agyeman ◽  
M. Nakao ◽  
G.R.A. Kumara ◽  
T. Kitaoka

ABSTRACTWe have deposited porous ZnO films on aluminum-doped ZnO (ZnO/AZO) and fluorine-doped tin oxide (ZnO/FTO) transparent substrates, and annealed both in air at 500°C. X-ray diffraction measurements of the nanoporous ZnO films after heat treatment showed that, ZnO/AZO film exhibited a dominant (002) diffraction while the ZnO/FTO showed mixed diffraction peaks with the (100) and (101) being dominant. Dye-sensitized solar cells (DSC) based on the sensitization of the porous ZnO films on AZO and FTO substrates with an indoline dye were constructed. The photoaction spectrum, which is a measure of the degree of sunlight harvesting, was broad and higher in the ZnO/AZO DSC than that of the ZnO/FTO DSC. Conversion efficiency of 7.3 % was obtained for the ZnO/AZO DSC while 4.5 % was recorded for the ZnO/FTO. The superior photovoltaic performance of the ZnO/AZO DSC is attributed to better ZnO film orientation after thermal treatment and the higher sunlight harvesting.

2017 ◽  
Vol 11 (3) ◽  
pp. 213-219 ◽  
Author(s):  
Amrik Singh ◽  
Devendra Mohan ◽  
Singh Ahlawat ◽  
R Richa

Dye sensitized solar cells (DSSCs) were fabricated using silver doped ZnO films deposited on ITO glass by spin coating method. The crystalline nature of ZnO films was analysed with XRD and SEM technique was used for morphological studies. The XRD pattern confirmed the presence of single phase hexagonal wurtzite ZnO structure, without the presence of secondary phase. The crystallite size of ZnO decreased from 31 nm to 25 nm with increase in doping to 1.5mol% of silver. The UV-visible transmission of the prepared ZnO film was found to be 70-90% and it decreased with increase in doping to 0.5mol% Ag and increased in the film doped with 1.5mol% Ag. The band gap values of the ZnO films with 0, 0.5 and 1.5mol% of silver, determined from Tauc plot, were 3.269, 3.235 and 3.257 eV, respectively. The absorbance peaks of the N719 dye loaded ZnO films were obtained at the wavelengths 310, 350 and 538 nm. The N719 dye loaded ZnO film doped with 0.5mol% Ag has the highest absorbance in the visible region as compared to other two samples. The fill factor values of the pure and ZnO doped with 0.5 and 1.5mol% Ag were 0.47, 0.48 and 0.42, respectively. The short circuit density values for ZnO, ZnO:Ag0.5% and ZnO:Ag1.5% were found to be 1.50, 1.55 and 1.15 A?m/cm2, respectively. The calculated photon to electron efficiencies for the ZnO films with 0, 0.5 and 1.5mol% of silver were 0.42%, 0.44% and 0.27%, respectively. Consequently future prospective of such type of dopants in ZnO film based dye sensitized solar cells seems to be bright.


2012 ◽  
Vol 60 (12) ◽  
pp. 2025-2028 ◽  
Author(s):  
Ji-Hong Kim ◽  
Kyung-Ju Lee ◽  
Ji-Hyung Roh ◽  
Sang-Woo Song ◽  
Jae-Ho Park ◽  
...  

2008 ◽  
Vol 1102 ◽  
Author(s):  
Qifeng Zhang ◽  
Samson A Jenekhe ◽  
Guozhong Cao

AbstractWe report the synthesis of ZnO aggregates in the presence of lithium salt and the enhancement on the energy conversion efficiency of dye sensitized solar cells when the photoelectrode films consist of as-synthesized ZnO aggregates. The conversion efficiency for ZnO film consisting of aggregates synthesized with lithium involvement is significantly improved up to 5.8%, which is 32% higher than that of 4.4% obtained for pure ZnO film. Such an enhancement can be attributed to the effect of lithium-induced changes on the morphology and crystallinity of aggregates, the optical absorption of films, and the surface chemistry of ZnO, which provides the film with decreased electron trapping and increased refractive index, and enhances the electronic coupling between the dye molecules and ZnO.


2011 ◽  
Vol 196 (23) ◽  
pp. 10518-10525 ◽  
Author(s):  
Lijuan Luo ◽  
Wei Tao ◽  
Xiaoyan Hu ◽  
Ting Xiao ◽  
Bojun Heng ◽  
...  

2014 ◽  
Vol 875-877 ◽  
pp. 1899-1903
Author(s):  
Hong Quan Zhou ◽  
Xiao Ping Zou ◽  
Gang Qiang Yang ◽  
Gong Qing Teng ◽  
Zong Bo Huang ◽  
...  

ZnO was a promising n-type conductive semiconductor material for dye-sensitized solar cells. Stable and efficient preparation of high quality p-type ZnO films became the main difficulty in current research. In this paper, a nitrogen-doped ZnO columnar film on an indium tin oxide (ITO) substrate was successfully obtained by gas phase method. The absorption of visible light was improved by nitrogen-doped ZnO columnar films. This experiment provided a good strategy for the full utilization of solar energy.


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