Electrochemical-microscopy analysis of bio-functionalized diamond surfaces

2007 ◽  
Vol 1039 ◽  
Author(s):  
Hiroshi Uetsuka ◽  
Nianjun Yang ◽  
Norio Tokuda ◽  
Christoph E. Nebel

AbstractDNA sensors fabricated on single-crystalline B-doped diamond (SBDD) electrodes were characterized by scanning electrochemical microscopy (SECM). These experiments show that circular arranged DNA sensors of typically 2 mm diameter show some spatial variations in electrochemical response. The variation of the diamond electrode with respect to DNA bonding is electrochemically characterized and discussed in the context of ion attraction/repulsion by the negatively charged backbones of DNA and the negatively charged diamond surface. Our results show that repulsive forces affect the mediator propagation of Fe(CN)64- in the close vicinity of the DNA layer which can be used to investigate DNA density variations on sensor areas.

PLoS ONE ◽  
2014 ◽  
Vol 9 (4) ◽  
pp. e93618 ◽  
Author(s):  
Adithya Sridhar ◽  
Hans L. de Boer ◽  
Albert van den Berg ◽  
Séverine Le Gac

2020 ◽  
Vol 9 (11) ◽  
pp. 115028
Author(s):  
Yen-Tzu Lin ◽  
Anant Preet ◽  
Yi-Pin Chiu ◽  
Bak-Sau Yip ◽  
Hubert H. Girault ◽  
...  

Sensors ◽  
2021 ◽  
Vol 21 (4) ◽  
pp. 1132 ◽  
Author(s):  
Rejane M. P. da Silva ◽  
Javier Izquierdo ◽  
Mariana X. Milagre ◽  
Abenchara M. Betancor-Abreu ◽  
Isolda Costa ◽  
...  

Amperometric and potentiometric probes were employed for the detection and characterization of reactive sites on the 2098-T351 Al-alloy (AA2098-T351) using scanning electrochemical microscopy (SECM). Firstly, the probe of concept was performed on a model Mg-Al galvanic pair system using SECM in the amperometric and potentiometric operation modes, in order to address the responsiveness of the probes for the characterization of this galvanic pair system. Next, these sensing probes were employed to characterize the 2098-T351 alloy surface immersed in a saline aqueous solution at ambient temperature. The distribution of reactive sites and the local pH changes associated with severe localized corrosion (SLC) on the alloy surface were imaged and subsequently studied. Higher hydrogen evolution, lower oxygen depletion and acidification occurred at the SLC sites developed on the 2098-T351 Al-alloy.


Nanoscale ◽  
2021 ◽  
Author(s):  
Katarina A. Novčić ◽  
Christian Iffelsberger ◽  
Siowwoon Ng ◽  
Martin Pumera

MoS2 and WS2 and their heterojunctions are used to modify thermally activated 3D-printed nanocarbon structures. Herein, the local electrochemical performance for HER of the modified structures is demonstrated by scanning electrochemical microscopy.


Author(s):  
Dylan T. Jantz ◽  
Ryan J. Balla ◽  
Siao-Han Huang ◽  
Niraja Kurapati ◽  
Shigeru Amemiya ◽  
...  

2011 ◽  
Vol 83 (5) ◽  
pp. 1485-1492 ◽  
Author(s):  
Isabelle Beaulieu ◽  
Sabine Kuss ◽  
Janine Mauzeroll ◽  
Matthias Geissler

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