Influence of Physical and Chemical Properties on the Activity of Fly Ashes

1987 ◽  
Vol 113 ◽  
Author(s):  
F. Sybertz

ABSTRACTIn an experimental program, the suitability of various methods for testing the pozzolanic activity of fly ash was investigated. The research was conducted on virtually all fly ashes approved as concrete additives in Germany. This paper discusses differences in the particle size distribution and the solubility on dissolution with hydrochloric acid and potassium hydroxide of the fly ashes. It also reports on interrelationships between the physical and chemical properties of the fly ashes and the workability and strength of mortars containing fly ash.

1987 ◽  
Vol 113 ◽  
Author(s):  
Scott Schlorholtz ◽  
Ken Bergeson ◽  
Turgut Demirel

ABSTRACTThe physical and chemical properties of fly ash produced at Ottumwa Generating Station have been monitored since April, 1985. The fly ash is produced from burning a low sulfur, sub-bituminous coal obtained from the Powder River Basin near Gillette, Wyoming. One-hundred and sixty samples of fly ash were obtained during the two year period. All of the samples were subjected to physical testing as specified by ASTM C 311. About one-hundred of the samples were also subjected to a series of tests designed to monitor the self-cementing properties of the fly ash. Many of the fly ash samples were subjected to x-ray diffraction and fluorescence analysis to define the mineralogical and chemical composition of the bulk fly ash as a function of sampling date. Hydration products in selected hardened fly ash pastes, were studied by x-ray diffraction and scanning electron microscopy. The studies indicated that power plant operating conditions influenced the compressive strength of the fly ash paste specimens. Mineralogical and morphological studies of the fly ash pastes indicated that stratlingite formation occurred in the highstrength specimens, while ettringite was the major hydration product evident in the low-strength specimens.


2014 ◽  
Vol 899 ◽  
pp. 409-414 ◽  
Author(s):  
Alena Struhárová ◽  
Stanislav Unčík ◽  
Svetozár Balkovic ◽  
Mária Hlavinková

Fluidized fly ash has different physical and chemical properties compared to fly ash emerging from classic combustion. It contains amorphous phases resulting from a dehydration of clay minerals as well as unreacted sorbent of CaCO3, free CaO and anhydrite (CaSO4). Work targets the possibilities of production of an autoclaved aerated concrete (AAC) from fluidized fly ash, and its influence on particular physical-mechanical properties of autoclaved aerated concrete.


1993 ◽  
Vol 23 (5) ◽  
pp. 941-955 ◽  
Author(s):  
K. Van Cleve ◽  
C.T. Dyrness ◽  
G.M. Marion ◽  
R. Erickson

Alluvial soils on the Tanana River floodplain near Fairbanks, Alaska, were examined for development of physical and chemical properties in relation to soil depth and across a 200-year vegetation development sequence. Development was mediated by ecosystem controls including successional time, vegetation, terrace height, soil physical and chemical properties, and microclimate. These controls interact and are conditioned by the state factors time, flora, topography, parent material, and climate, respectively. On early-successional (<5 years) lower alluvial surfaces, terrace height above groundwater, soil particle size, and microclimate (through soil surface evaporation) interacted through capillary rise to produce salt-affected surface soil. Calcium salts of carbonate and sulfate were the principal chemicals encountered in these soils. Establishment of a vegetation cover between 5 and 10 years introduced evapotranspiration as a new mechanism, along with capillarity, to control moisture suction gradients. In addition, newly formed surface litter layers further helped eliminate evaporation and formation of high salt content surface soil. Continued sedimentation raised terrace elevation, so on older terraces only infrequent flood events influenced soil development. Moreover, in these successional stages, only the highest river stages raised groundwater levels, so transpiration and capillarity influenced water movement to tree root systems. During the first 25–30 years of succession, plant deposition of organic matter and nitrogen, associated with the growth of alder, markedly changed soil properties. Nearly 60% (or 240 g•m−2) of the 400 g•m−2 nitrogen encountered at 100 years was accumulated during this early period. After 100 years of vegetation development, soil carbonate content dropped to about half the peak values of about 1600 g•m−2 encountered between 4 and 25 years. By the time white spruce was the dominant forest type at 180 years, carbonate carbon declined to about 500 g•m−2, one-third that of the 1600 g•m−2 high. By this time surface soil pH declined from high values of 7.5 to between 5.5 and 6.0. Organic carbon continued to accumulate to about 6300 g•m−2 in the white spruce stage, twice that encountered in the alder–poplar stage at 25 years. Indices of moisture retention were most strongly related to either soil particle size (low moisture tension and available moisture range) or vegetation-mediated soil organic matter content (high moisture tension). Cation exchange capacity was most strongly related to a vegetation-mediated index of organic matter (OM) content (%N, %C, or %OM).


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