scholarly journals Effect of Transparent Electrode on the Performance of Bulk Heterojunction Solar Cells

2010 ◽  
Vol 1270 ◽  
Author(s):  
A.A. Damitha T Adikaari ◽  
Joe Briscoe ◽  
Steve Dunn ◽  
David Carey ◽  
Ravi Silva

AbstractWe present a performance comparison of polythiophene/fullerene derivative bulk heterojunction solar cells fabricated on fluorinated tin oxide (FTO) and indium tin oxide (ITO) in the presence and absence of the commonly used poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) hole extraction layer. From a potential commercial perspective the performance of cheaper and more readily available FTO compares well with the more expensive ITO in terms of measured device efficiency (FTO:2.8 % and ITO:3.1%). The devices show similar fill factors (FTO:63% and ITO:64%) with the same open circuit voltage of 0.6 V. The short circuit current density is lower for FTO devices at 7.5 mA/cm2 which compares with 8.0 mA/cm2 for ITO; a behaviour that is mainly attributed to the reduced optical transmission of the FTO layer. Importantly, these devices were part fabricated and wholly characterized under atmospheric conditions. The quoted device performance is the best reported for FTO based bulk heterojunction systems in the absence of the highly acidic PEDOT:PSS hole extraction layer, which is believed to degrade conductive oxides.

2013 ◽  
Vol 27 (28) ◽  
pp. 1350167 ◽  
Author(s):  
SHUAI ZHOU ◽  
JIU-XUN SUN

As a suitable recombination process, recombination via tail state in organic bulk-heterojunction solar cells (OBHJs) is capable of reproducing both dark and illuminated current–voltage curves. The characteristic parameters of OBHJs based on recombination via tail are governed by transportation and extraction efficiency, and both processes are strongly dependent on the charge carrier mobility. Using a macroscopic simulation, we calculate the mobility dependent power conversion efficiency, open-circuit voltage, short-circuit current and fill factor. The open-circuit voltage is determined by not only carrier density n(p), but also by carrier density gradient. Furthermore, open-circuit voltage is more affected by majority charge carriers and less affected by minority ones.


2019 ◽  
Vol 7 (6) ◽  
pp. 2754-2763 ◽  
Author(s):  
Jieming Zhen ◽  
Weiran Zhou ◽  
Muqing Chen ◽  
Bairu Li ◽  
Lingbo Jia ◽  
...  

A novel pyridine-functionalized fullerene derivative (C60-PyP) as an additive in regular bulk heterojunction perovskite (CH3NH3Pbl3) solar cells (PSCs) enables a power conversion efficiency of 19.82% with markedly suppressed hysteresis.


2012 ◽  
Vol 209-211 ◽  
pp. 1719-1722
Author(s):  
Ming Guo Zhang ◽  
Nan Hai Sun

A thin Ag layer embedded between layers of zinc tin oxide (ZTO) are compared to cells using an indium tin oxide electrode was investigated for inverted organic bulk heterojunction solar cells employing a multilayer electrode. ZTO/Ag/ ZTO (ZAZ) electrode is the preparation at room temperature, a high transparency in the visible part of the spectrum, and a very low sheet resistance comparable to treated ITO without the need for any thermal post deposition treatment as it is necessary for ITO. The In-free ZAZ electrodes exhibit a favorable work function of 4.3 eV and are shown to allow for excellent electron extraction even without a further interlayer. This renders ZAZ a perfectly suited bottom electrode for inverted organic solar cells with simplified cell architecture.


2018 ◽  
Vol 6 (39) ◽  
pp. 19190-19200 ◽  
Author(s):  
Mary Allison Kelly ◽  
Qianqian Zhang ◽  
Zhengxing Peng ◽  
Victoria Noman ◽  
Chenhui Zhu ◽  
...  

Comparing the efficiency of terpolymers vs. ternary blends, this study focuses on two polymers with structurally similar backbones (monoCNTAZ and FTAZ) yet markedly different open circuit voltages.


2016 ◽  
Vol 6 (4) ◽  
pp. 918-923 ◽  
Author(s):  
Rania Alqurashi ◽  
Jonathan Griffin ◽  
Abdullah Alsulami ◽  
Alastair Buckley

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