Effects of Gas Environments on Porous Silicon Photoluminescence

1999 ◽  
Vol 560 ◽  
Author(s):  
G. Di Francia ◽  
V. La Ferrara ◽  
L. Lancellotti ◽  
L. Quercia ◽  
T. Fasolino

ABSTRACTThe photoluminescence response of a series of porous silicon samples, obtained by electrochemical etching of n-type CZ-silicon, has been recorded in various gas environments. A quenching is reported when porous silicon is in the presence of an oxidising ambient (dry air or acetone vapours in dry air). Process reversibility depends on the duration of laser illumination. Quenching is also recorded if porous silicon is in the presence of acetone vapours in nitrogen ambient, where complete reversibility is however shown. Moreover, the peak wavelength is red shifted in dry air and blue shifted in acetone vapours. Irreversible quenching is related to the growth of a thin oxide layer on the emitting nanostrucures.

2021 ◽  
Vol 506 ◽  
pp. 230209
Author(s):  
Hideyuki Nakano ◽  
Takao Inoue ◽  
Takeshi Uyama ◽  
Takamasa Nonaka ◽  
Kazuhiko Mukai

1993 ◽  
Vol 34 (12) ◽  
pp. 2099-2104 ◽  
Author(s):  
G.M. Brown ◽  
K. Shimizu ◽  
K. Kobayashi ◽  
G.E. Thompson ◽  
G.C. Wood

1995 ◽  
Vol 38 (8) ◽  
pp. 1465-1471 ◽  
Author(s):  
M Depas ◽  
B Vermeire ◽  
P.W Mertens ◽  
R.L Van Meirhaeghe ◽  
M.M Heyns

1984 ◽  
Vol 23 (Part 1, No. 3) ◽  
pp. 283-285 ◽  
Author(s):  
Teruya Shinjo ◽  
Takashi Iwasaki ◽  
Toshihiko Shigematsu ◽  
Toshio Takada

2011 ◽  
Vol 107 (3) ◽  
Author(s):  
Na Cai ◽  
Guangwen Zhou ◽  
Kathrin Müller ◽  
David E. Starr

2019 ◽  
Vol 11 (12) ◽  
pp. 1218-1224
Author(s):  
Dao Tran Cao ◽  
Cao Tuan Anh ◽  
Luong Truc Quynh Ngan

So far, while producing porous silicon (PSi) with anodic etching of silicon in an aqueous solution of hydrofluoric acid, many researchers (including us) have obtained the crack-into-pieces (or mosaic) structure. Most of the authors believed that the cause of this structure is the collapse and the cracking of the porous, especially highly porous, silicon layer which took place during the drying of PSi after fabrication. However, our study showed that the mosaic structure was formed right during the course of silicon anodization at high anodic current density. Furthermore, our study also showed that at high anodic current density the real silicon etching has been replaced by the growth of a silicon oxide layer. This is a layer of another substance that grows on silicon, so when the layer is too thick (which is obtained when the anodic current density is too high and/or the anodization time is too long) it will crack, creating mosaic pieces. When the silicon oxide layer is cracked, the locations around the cracks will be etched more violently than elsewhere, creating trenches. Thus, the mosaic structure with mosaic pieces emerged between the trenches has formed.


1976 ◽  
Vol 13 (4) ◽  
pp. 873-873 ◽  
Author(s):  
E. H. Nicollian ◽  
B. Schwartz ◽  
D. J. Coleman ◽  
R. M. Ryder ◽  
J. R. Brews

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