The Application of Silver Oxide Thin Films to Plasmon Photonic Devices

2002 ◽  
Vol 728 ◽  
Author(s):  
Junji Tominaga ◽  
Dorothea Büchel ◽  
Christophe Mihalcea ◽  
Takayuki Shima ◽  
Toshio Fukaya

AbstractRF-magnetron sputtered thin films of silver oxide (AgOx) were recently applied to ultra-high density optical data storage. It has been elucidated that the AgOx film sandwiched by protection layers shows very attractive characteristics in strong light-scattering, local plasmon generation and super-resolution by focussing a laser beam on it. Especially, the combination with an active recording film (optical phase change or magneto-optical) used in the currently recordable optical disks improves the storage density and overcomes the diffraction limit. In this paper, we describe the basic characteristics of nano-scale light scattering centers generated in the AgOx films and the interaction with ultra-high density recorded mark patterns in a near-field region. In addition, we provide the structural transition of the AgOx film by thermal and laser annealing treatment.

2001 ◽  
Vol 674 ◽  
Author(s):  
Dorothea Büchel ◽  
Christophe Mihalcea ◽  
Toshio Fukaya ◽  
Nobufumi Atoda ◽  
Junji Tominaga

ABSTRACTThin silver oxide films used as mask layers in super-Resolution Nearfield Structure (super-RENS) disks for high density optical data storage were reactively sputter-deposited and their composition was determined by spectroscopic means. We found that the stoichiometry of the films changed with the oxygen content in the sputtering gas atmosphere. With a stepwise increase in the percentage of O2 from 0 - 100%, the corresponding layers consist of Ag, mixtures of Ag and Ag2O, Ag2O, mixtures of Ag2O and AgO and AgO. Laser activation of such oxidic phase containing deposits results in the decomposition of the material and excitation of strong local plasmons in the remaining silver clusters. This was confirmed by acquiring surface enhanced Raman spectra (SERS) of benzoic acid (BA), copper phthalocyanine (CP) and internal carbon impurities on silver oxide substrates. From this data, we conclude that the sub-wavelength resolution obtained in super-RENS disks is mediated by local surface plasmons on small silver particles forming in the mask layer.


Author(s):  
M. S. Shahriar ◽  
L. Wong ◽  
M. Bock ◽  
B. Ham ◽  
P. R. Hemmer

2003 ◽  
Vol 803 ◽  
Author(s):  
J. Kalb ◽  
F. Spaepen ◽  
M. Wuttig

ABSTRACTBoth the crystal nucleation rate and the crystal growth velocity of sputtered amorphous Ag0.055In0.065Sb0.59Te0.29 and Ge4Sb1Te5 thin films used for optical data storage were determined as a function of temperature. Crystals were directly observed using ex-situ atomic force microscopy, and their change in size after each anneal was measured. Between 140°C and 185°C, these materials exhibited similar crystal growth characteristics, but differed in their crystal nucleation characteristics. These observations provide an explanation for the different re-crystallization mechanisms observed upon laser-induced crystallization of amorphous marks.


1988 ◽  
Vol 82 (1) ◽  
pp. 99-104 ◽  
Author(s):  
S. Mancha ◽  
J. Bullington ◽  
R. Carter ◽  
C. Dehainaut

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