Electrochemical Properties of Blockcopolymer Templated Mesoporous Silicates with Heteropolyacids clusters

2002 ◽  
Vol 756 ◽  
Author(s):  
Hui Suk Yun ◽  
Makoto Kuwabara ◽  
Hao Shen Zhou ◽  
Itaru Honma

ABSTRACTIn this paper, we have studied a method of loading 12-tungstophosphoric acid (H3PW12O40; PWA) into blockcopolymer templated (designated EO20PO70EO20; Pluronic P-123) mesoporous SiO2 framework without a disordering of mesostructure and without remarkable decrease of specific surface area through one-step condensation process. A precursor solution is initially prepared by TEOS (tetraethoxysilane) hydrolyzed with templating polymer (eg. triblock copolymer), and then mixed directly with PWA to condense mesoporous silicate products that incorporate PWA clusters in the framework. Heteropolyanions are possibly incorporated in the framework silicates. Electrochemical properties of these PWA impregnated mesoporous silicates were studied as electrode materials of Li ion battery as well as solid proton conductors.

RSC Advances ◽  
2016 ◽  
Vol 6 (29) ◽  
pp. 24320-24330 ◽  
Author(s):  
Junkai He ◽  
Ying Liu ◽  
Yongtao Meng ◽  
Xiangcheng Sun ◽  
Sourav Biswas ◽  
...  

A new one-step microwave method was designed for synthesis of rGO/Co3O4, and the Li-ion battery showed high capacity and long life.


Author(s):  
Daniel J. Lyons ◽  
Jamie L. Weaver ◽  
Anne C. Co

Li distribution within micron-scale battery electrode materials is quantified with neutron depth profiling (NDP). This method allows the determination of intra- and inter-electrode parameters such as lithiation efficiency, electrode morphology...


Carbon ◽  
2010 ◽  
Vol 48 (10) ◽  
pp. 3002
Author(s):  
Sang-Min Jang ◽  
Jin Miyawaki ◽  
Masaharu Tsuji ◽  
Isao Mochida ◽  
Seong-Ho Yoon ◽  
...  

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