Structure and Device Characteristics of SrBi2Ta2O9-Based Nonvolatile Random-Access Memories

MRS Bulletin ◽  
1996 ◽  
Vol 21 (7) ◽  
pp. 33-39 ◽  
Author(s):  
J.F. Scott ◽  
F.M. Ross ◽  
C.A. Paz de Araujo ◽  
M.C. Scott ◽  
M. Huffman

Recently there has been a paradigm shift in nonvolatile computer memories from silicon-technology-based EEPROMs (electrically erasable, programmable read-only memories) to devices in which the stored information is coded into + and − polarizations in thin-film ferroelectric capacitors. Such devices have read and erase/rewrite speeds of the order of 1–35 ns, many orders of magnitude faster than the erase/rewrite speeds of the best EEPROMs (Table I). However, fundamental questions concerning their lifetimes had delayed full commercialization. Because ferroelectrics normally have extremely large dielectric constants, their use as nonswitching capacitors in dynamic random-access memories (DRAMs) is also rapidly evolving. The majority of studies to date have emphasized lead zirconate titanate (PZT)-based capacitors for nonvolatile ferroelectric random-access memories (NVFRAMs) and barium strontium titanate-based capacitor DRAMs (see Table II).

1998 ◽  
Vol 541 ◽  
Author(s):  
J Robertson ◽  
C W Chen

AbstractSchottky barrier heights of various metals on tantalum pentoxide, barium strontium titanate, lead zirconate-titanate and strontium bismuth tantalate have been calculated as a function of metal work function. These oxides have a dimensionless Schottky barrier pinning factor, S, of 0.28 – 0.4 and not close to 1, because S is controlled by the Ti-O type bonds not Sr-O type bonds, as assumed previously. Band offsets on silicon are asymmetric with much smaller offset at the conduction band, so that Ta2O5 and barium strontium titanate (BST) are relatively poor barriers to electrons on Si.


2005 ◽  
Vol 471 (1-2) ◽  
pp. 71-75 ◽  
Author(s):  
Tomokazu Tanase ◽  
Yoshio Kobayashi ◽  
Toshihide Nabatame ◽  
Takao Miwa ◽  
Mikio Konno

2002 ◽  
Vol 17 (8) ◽  
pp. 1884-1887 ◽  
Author(s):  
Santiranjan R. Shannigrahi ◽  
Sun-Hwa Lee ◽  
Hyun M. Jang

The development of lead zirconate titanate (PZT)-based capacitors using common Pt electrodes has been a long-time goal of ferroelectric random access memories (FRAM).In this work, a series of Pb1−xLax(Zr0.55Ti0.45)O3 capacitors (for 0.01 < x < 0.05) having fatigue-free characteristics have been grown on Pt/ Ti/SiO2/Si substrates. Typically 2–3 mol% La-modified PZT capacitors fabricated at 580 °C by applying a PZT seed layer exhibited fatigue-free behavior up to 6.5 × 1010 switching cycles, a low coercive field of 50–55 kV/cm, and a stable charge retention profile with time, all of which assure their suitability for the future nonvolatile FRAM.


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