Soil Properties Influence Saflufenacil Phytotoxicity

Weed Science ◽  
2014 ◽  
Vol 62 (4) ◽  
pp. 657-663 ◽  
Author(s):  
Travis W. Gannon ◽  
Adam C. Hixson ◽  
Kyle E. Keller ◽  
Jerome B. Weber ◽  
Stevan Z. Knezevic ◽  
...  

Saflufenacil, a pyrimidinedione herbicide, is used for contact and residual broadleaf weed control in various crops. Bioactivity of saflufenacil in soil was tested in greenhouse and laboratory studies on 29 soils representing a wide range of soil properties and geographic areas across the United States. A greenhouse bioassay method was developed using various concentrations of saflufenacil applied PPI to each soil. Whole canola plants were harvested 14 d after treatment, and fresh and dry weights were recorded. Nonlinear regression analysis was used to determine the effective saflufenacil doses for 50% (ED50,), 80% (ED80), and 90% (ED90) inhibition of total plant fresh weight. Bioactivity of saflufenacil in soil was strongly correlated to soil organic (R= 0.85) and humic matter (R= 0.81), and less correlated to cation exchange capacity (R= 0.49) and sand content (R= −0.32). Stepwise regression analysis indicated that organic matter was the major soil constituent controlling bioactivity in soil and could be used to predict the bioactivity of saflufenacil. Saflufenacil phytotoxicity was found to be dependent on soil property; therefore, efficacy and crop tolerance from PRE and PPI applications may vary based on soil organic matter content and texture classification.

2008 ◽  
Vol 53 (No. 5) ◽  
pp. 225-238 ◽  
Author(s):  
N. Finžgar ◽  
P. Tlustoš ◽  
D. Leštan

Sequential extractions, metal uptake by <i>Taraxacum officinale</i>, Ruby&rsquo;s physiologically based extraction test (PBET) and toxicity characteristic leaching procedure (TCLP), were used to assess the risk of Pb and Zn in contaminated soils, and to determine relationships among soil characteristics, heavy metals soil fractionation, bioavailability and leachability. Regression analysis using linear and 2nd order polynomial models indicated relationships between Pb and Zn contamination and soil properties, although of small significance (<i>P</i> < 0.05). Statistically highly significant correlations (<i>P</i> < 0.001) were obtained using multiple regression analysis. A correlation between soil cation exchange capacity (CEC) and soil organic matter and clay content was expected. The proportion of Pb in the PBET intestinal phase correlated with total soil Pb and Pb bound to soil oxides and the organic matter fraction. The leachable Pb, extracted with TCLP, correlated with the Pb bound to carbonates and soil organic matter content (<i>R</i><sup>2</sup> = 69%). No highly significant correlations (<i>P</i> < 0.001) for Zn with soil properties or Zn fractionation were obtained using multiple regression.


2009 ◽  
Vol 6 (3) ◽  
pp. 245 ◽  
Author(s):  
Achouak El Arfaoui ◽  
Stéphanie Sayen ◽  
Eric Marceau ◽  
Lorenzo Stievano ◽  
Emmanuel Guillon ◽  
...  

Environmental context. The wide use of pesticides for pest and weed control contributes to their presence in underground and surface waters, which has led to a continuously growing interest in their environmental fate. Soils play a key role in the transfer of these compounds from the sprayer to the water as a result of their capacity to retain pesticides depending on the soil components. The knowledge of soil composition should enable one to predict pesticide behaviour in the environment. Abstract. Eight calcareous soils of Champagne vineyards (France) were studied to investigate the adsorption of the herbicide terbumeton (TER). A preliminary characterisation of the soil samples using X-ray diffraction (XRD), elemental and textural analyses, revealed a wide range of soil properties for the selected samples. The adsorption isotherms of TER were plotted for all samples. The determination of soil properties, which significantly correlated with the Kd distribution coefficient, allowed identification of organic matter and CaCO3 as the two main soil components that govern the retention of the herbicide. Organic matter was the predominant phase involved in the retention but its role was limited by the presence of calcite. Finally, the ratio of CaCO3 content to organic matter content was proposed as a useful parameter to predict the adsorption of terbumeton in chalky soils. The evolution of Kd as a function of this ratio was successfully described using an empirical model.


Weed Science ◽  
1998 ◽  
Vol 46 (1) ◽  
pp. 132-138 ◽  
Author(s):  
Brian M. Jenks ◽  
Fred W. Roeth ◽  
Alex R. Martin ◽  
Dennis L. McCallister

Studies to predict pesticide fate often lack measurements of model input parameters. Using independent data sets and understanding how soil properties affect herbicide retention and degradation may result in more accurate prediction of herbicide fate. We conducted laboratory studies to determine the influence of soil properties on atrazine adsorption and degradation. These data will be used in a separate study involving a pesticide fate model. Atrazine adsorption and desorption isotherms were constructed for six soil depths of a Hastings silty clay loam (fine, montmorillonitic, mesic Udic Argiustoll) using batch equilibration. The Freundlich adsorption constants (logKf) ranged from 0.38 (60 to 90 cm) to 2.91 (0 to 30 cm). Adsorption was higher in the low pH, high organic matter-containing surface soil compared to the lower soil depths. Multiple regression of the adsorption constants against selected soil properties indicated that organic matter content was the best single predictor of atrazine adsorption (R2= 0.98) followed by soil pH (R2= 0.82). Combining organic matter and cation exchange capacity in the model produced the lowestCpstatistic (2.33) and highestR2value (0.99). We observed hysteresis in atrazine adsorption–desorption isotherms by higher adsorption slopes (1/n)adscompared to desorption slopes (1/n)des. Soils that adsorbed more atrazine also desorbed less atrazine. Desorption correlated negatively with organic matter content and positively with soil pH. Atrazine degradation after 84 d of incubation generally decreased with increasing depth. The first-order degradation rate was highest 0 to 30 cm deep (0.0187 day−1) and lowest 270 to 300 cm deep (0.0031 day−1). Atrazine degradation was faster in soil treated annually for 12 yr than in soil with no previous atrazine history (p = 0.01).


Author(s):  
Trina Stephens

Land‐use change can have a major impact on soil properties, leading to long‐term changes in soilnutrient cycling rates and carbon storage. While a substantial amount of research has been conducted onland‐use change in tropical regions, empirical evidence of long‐term conversion of forested land toagricultural land in North America is lacking. Pervasive deforestation for the sake of agriculturethroughout much of North America is likely to have modified soil properties, with implications for theglobal climate. Here, we examined the response of physical, chemical and biological soil properties toconversion of forest to agricultural land (100 years ago) on Roebuck Farm near Perth, Ontario, Canada.Soil samples were collected at three sites from under forest and agricultural vegetative cover on bothhigh‐ and low‐lying topographic positions (12 locations in total; soil profile sampled to a depth of 40cm).Our results revealed that bulk density, pH, and nitrate concentrations were all higher in soils collectedfrom cultivate sites. In contrast, samples from forested sites exhibited greater water‐holding capacity,porosity, organic matter content, ammonia concentrations and cation exchange capacity. Many of these characteristics are linked to greater organic matter abundance and diversity in soils under forestvegetation as compared with agricultural soils. Microbial activity and Q10 values were also higher in theforest soils. While soil properties in the forest were fairly similar across topographic gradients, low‐lyingpositions under agricultural regions had higher bulk density and organic matter content than upslopepositions, suggesting significant movement of material along topographic gradients. Differences in soilproperties are attributed largely to increased compaction and loss of organic matter inputs in theagricultural system. Our results suggest that the conversion of forested land cover to agriculture landcover reduces soil quality and carbon storage, alters long‐term site productivity, and contributes toincreased atmospheric carbon dioxide concentrations.


Author(s):  
Juliana Vantellingen ◽  
Sean C. Thomas

Log landings are areas within managed forests used to process and store felled trees prior to transport. Through their construction and use soil is removed or redistributed, compacted, and organic matter contents may be increased by incorporation of wood fragments. The effects of these changes to soil properties on methane (CH<sub>4</sub>) flux is unclear and unstudied. We quantified CH<sub>4</sub> flux rates from year-old landings in Ontario, Canada, and examined spatial variability and relationships to soil properties within these sites. Landings emitted CH<sub>4</sub> throughout the growing season; the average CH<sub>4</sub> emission rate from log landings was 69.2 ± 12.8 nmol m<sup>-2</sup> s<sup>-1</sup> (26.2 ± 4.8 g CH<sub>4</sub> C m<sup>-2</sup> y<sup>-1</sup>), a rate comparable to CH<sub>4</sub>-emitting wetlands. Emission rates were correlated to soil pH, organic matter content and quantities of buried woody debris. These properties led to strong CH<sub>4</sub> emissions, or “hotspots”, in certain areas of landings, particularly where processing of logs occurred and incorporated woody debris into the soil. At the forest level, emissions from landings were estimated to offset ~12% of CH<sub>4</sub> consumption from soils within the harvest area, although making up only ~0.5% of the harvest area. Management practices to avoid or remediate these emissions should be developed as a priority measure in “climate-smart” forestry.


2021 ◽  
Vol 1 (42) ◽  
pp. 109-115
Author(s):  
Binh Phan Khanh Huynh ◽  
Tho Van Nguyen ◽  
Vien My Tran

This study aimed to use charcoal derived from the bamboo and melaleuca produced by traditional kiln applied to sandy soil growing mustard green (Brassica juncea L.). The charcoals were applied at three ratio (1%,2%, and 3%, which correspond to 10, 20, and 30 g charcoal/kg soil in pots) and the control treatment without charcoal. Soil properties were investigated including bulk density, pH, electrical conductivity (EC), cation exchange capacity (CEC), organic matter content, total nitrogen, and total phosphorous. The results showed that bulk density decreased in charcoal-treated soils. pH and EC were in the suitable range for plants.Nutrients and CEC of the soil in the charcoal treatment were significantly higher compared with the control (CEC increase 6.8% to 16%; TC increase 80% to 115%; TN increase 37.5 to 75%). Green mustard growing on charcoalamended soil had greater height (higher 3% to 21%), bigger leaves, and higher yield (increase18% to 81%) than those of plants groomed in the control treatment. This study showed the potential of using charcoal as supplying nutrient to the poor soil. Moreover, the abundant of raw material and easy to produce, it is suitable for applying in the Mekong Delta, Viet Nam, and other countries with similar conditions and infrastructure. 


2016 ◽  
Vol 2 (2) ◽  
pp. 37
Author(s):  
B.H. Prasetyo ◽  
N. Suharta ◽  
Subagyo H. ◽  
Hikmatullah Hikmatullah

Ultisols are a major group of marginal soils extensively found in the upland area of Indonesia. To better understand the potential of the Ultisols developed from claystone and sandstone in the Sasamba Integrated Economical Development Area in East Kalimantan, chemical and mineralogical characteristics of 27 Ultisols pedons consisting of 76 topsoil and 118 subsoil samples were investigated. Besides analysis and interpretation of data, relationships of several soil characteristics were constructed using simple regression. The results indicated that Ultisols showed acid to very acid reaction, had low content of organic matter and low base saturation. Soils generally exhibited net negative charge, and the point of zero charge was reached at pH 3.6. Both potential and available phosphates were low, and there was a trend that amorphous aluminum was responsible for phosphate fixation. The low content of exchangeable potassium in topsoil and subsoil indicated a positive correlation with potential potassium. Clay mineral was composed chiefly of kaolinite, with small amounts of illite, vermiculite, and quartz. The domination of kaolinite and low organic matter content causes the soils to have low cation exchange capacity. Soil management in this area should be focused on building up and maintaining soil fertility, and applying appropriate soil conservation techniques to minimize erosion. To obtain sustained productivity, various soil amendments including the use of farm and/or green manure, liming with agricultural lime, and application of rock phosphate and K fertilizers were highly recommended.


Weed Science ◽  
1983 ◽  
Vol 31 (3) ◽  
pp. 368-372 ◽  
Author(s):  
Josef Kozak ◽  
Jerome B. Weber

Adsorption of five phenylurea herbicides, metobromuron [3-(p-bromophenyl)-1-methoxy-1-methylurea], monolinuron [3-(p-chlorophenyl)-1-methoxyl-1-methylurea], linuron [3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea], chlorbromuron [3-(4-bromo-3-chlorophenyl)-1-methoxy-1-methylurea], and CGA-15646 [3-(3-chloro-4-methylphenyl)-1,1-dimethylurea] by eight selected soils of Czechoslovakia were studied. Constants from Freundlich and Langmuir equations were calculated and correlated with the major soil properties. Freundlich K values ranged from 1.84 to 128, and the Freundlich equation was better fitted to the adsorption isotherms than was the Langmuir equation. Soil organic-matter content was the most important factor influencing the range of adsorption.


Weed Science ◽  
1979 ◽  
Vol 27 (4) ◽  
pp. 456-459 ◽  
Author(s):  
A. Loh ◽  
S. J. Parka ◽  
R. Albritton ◽  
C. C. Lin

The rate of herbicide required to reduce growth of grain sorghum (Sorghum vulgare, Per. ‘Pioneer 8417′) by 50% (GR50) and soil adsorption coefficients (Ka) were determined for the experimental herbicide, fluridone {1-methyl-3-phenyl-5-[3-(trifluoromethyl)phenyl]-4(1H)-pyridinone}, in 14 soils. A linear correlation analysis was conducted between GR50values and the chemical and physical properties and fluridone absorption coefficient (Ka) for 14 soils. The GR50values were significantly correlated to soil organic matter and Ka. A stepwise regression analysis suggests that Kaor organic matter content can be used to predict the rate of fluridone application required for herbicidal activity.


1974 ◽  
Vol 54 (1) ◽  
pp. 7-14 ◽  
Author(s):  
L. S. CROSSON ◽  
R. PROTZ

Many soil mapping units (MU) have not been adequately sampled to provide a true measure of their variability; therefore, their descriptions must be regarded as incomplete, and valid statistical comparisons cannot be made with other closely related MU. The number of samples required to detect the differences in means of 18 soil properties between Brantford and Beverly Silt Loam MU were calculated and they ranged from 4 at the 80% probability level (10 at the 95% probability level) for organic matter content of the Ap horizon to several thousand for pH of the Ap horizon. Calculation of required sample numbers indicated that sufficient samples had been collected to make valid statistical comparisons between seven of the soil properties. All seven properties were found to be significantly different between the two MU at the 95% probability level. However, only two of the properties, hue and organic matter content of the Ap horizon, had distinctly different modal values between the two MU and neither of these properties is easily measured in the field. Therefore, it was concluded that the 18 soil properties examined were impractical and unreliable criteria for separating the MU in the field. But, the MU separations can be readily and validly made on the basis of landscape position.


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