Relationship between soil composition and retention capacity of terbumeton onto chalky soils

2009 ◽  
Vol 6 (3) ◽  
pp. 245 ◽  
Author(s):  
Achouak El Arfaoui ◽  
Stéphanie Sayen ◽  
Eric Marceau ◽  
Lorenzo Stievano ◽  
Emmanuel Guillon ◽  
...  

Environmental context. The wide use of pesticides for pest and weed control contributes to their presence in underground and surface waters, which has led to a continuously growing interest in their environmental fate. Soils play a key role in the transfer of these compounds from the sprayer to the water as a result of their capacity to retain pesticides depending on the soil components. The knowledge of soil composition should enable one to predict pesticide behaviour in the environment. Abstract. Eight calcareous soils of Champagne vineyards (France) were studied to investigate the adsorption of the herbicide terbumeton (TER). A preliminary characterisation of the soil samples using X-ray diffraction (XRD), elemental and textural analyses, revealed a wide range of soil properties for the selected samples. The adsorption isotherms of TER were plotted for all samples. The determination of soil properties, which significantly correlated with the Kd distribution coefficient, allowed identification of organic matter and CaCO3 as the two main soil components that govern the retention of the herbicide. Organic matter was the predominant phase involved in the retention but its role was limited by the presence of calcite. Finally, the ratio of CaCO3 content to organic matter content was proposed as a useful parameter to predict the adsorption of terbumeton in chalky soils. The evolution of Kd as a function of this ratio was successfully described using an empirical model.

Weed Science ◽  
2014 ◽  
Vol 62 (4) ◽  
pp. 657-663 ◽  
Author(s):  
Travis W. Gannon ◽  
Adam C. Hixson ◽  
Kyle E. Keller ◽  
Jerome B. Weber ◽  
Stevan Z. Knezevic ◽  
...  

Saflufenacil, a pyrimidinedione herbicide, is used for contact and residual broadleaf weed control in various crops. Bioactivity of saflufenacil in soil was tested in greenhouse and laboratory studies on 29 soils representing a wide range of soil properties and geographic areas across the United States. A greenhouse bioassay method was developed using various concentrations of saflufenacil applied PPI to each soil. Whole canola plants were harvested 14 d after treatment, and fresh and dry weights were recorded. Nonlinear regression analysis was used to determine the effective saflufenacil doses for 50% (ED50,), 80% (ED80), and 90% (ED90) inhibition of total plant fresh weight. Bioactivity of saflufenacil in soil was strongly correlated to soil organic (R= 0.85) and humic matter (R= 0.81), and less correlated to cation exchange capacity (R= 0.49) and sand content (R= −0.32). Stepwise regression analysis indicated that organic matter was the major soil constituent controlling bioactivity in soil and could be used to predict the bioactivity of saflufenacil. Saflufenacil phytotoxicity was found to be dependent on soil property; therefore, efficacy and crop tolerance from PRE and PPI applications may vary based on soil organic matter content and texture classification.


Author(s):  
Trina Stephens

Land‐use change can have a major impact on soil properties, leading to long‐term changes in soilnutrient cycling rates and carbon storage. While a substantial amount of research has been conducted onland‐use change in tropical regions, empirical evidence of long‐term conversion of forested land toagricultural land in North America is lacking. Pervasive deforestation for the sake of agriculturethroughout much of North America is likely to have modified soil properties, with implications for theglobal climate. Here, we examined the response of physical, chemical and biological soil properties toconversion of forest to agricultural land (100 years ago) on Roebuck Farm near Perth, Ontario, Canada.Soil samples were collected at three sites from under forest and agricultural vegetative cover on bothhigh‐ and low‐lying topographic positions (12 locations in total; soil profile sampled to a depth of 40cm).Our results revealed that bulk density, pH, and nitrate concentrations were all higher in soils collectedfrom cultivate sites. In contrast, samples from forested sites exhibited greater water‐holding capacity,porosity, organic matter content, ammonia concentrations and cation exchange capacity. Many of these characteristics are linked to greater organic matter abundance and diversity in soils under forestvegetation as compared with agricultural soils. Microbial activity and Q10 values were also higher in theforest soils. While soil properties in the forest were fairly similar across topographic gradients, low‐lyingpositions under agricultural regions had higher bulk density and organic matter content than upslopepositions, suggesting significant movement of material along topographic gradients. Differences in soilproperties are attributed largely to increased compaction and loss of organic matter inputs in theagricultural system. Our results suggest that the conversion of forested land cover to agriculture landcover reduces soil quality and carbon storage, alters long‐term site productivity, and contributes toincreased atmospheric carbon dioxide concentrations.


Author(s):  
Juliana Vantellingen ◽  
Sean C. Thomas

Log landings are areas within managed forests used to process and store felled trees prior to transport. Through their construction and use soil is removed or redistributed, compacted, and organic matter contents may be increased by incorporation of wood fragments. The effects of these changes to soil properties on methane (CH<sub>4</sub>) flux is unclear and unstudied. We quantified CH<sub>4</sub> flux rates from year-old landings in Ontario, Canada, and examined spatial variability and relationships to soil properties within these sites. Landings emitted CH<sub>4</sub> throughout the growing season; the average CH<sub>4</sub> emission rate from log landings was 69.2 ± 12.8 nmol m<sup>-2</sup> s<sup>-1</sup> (26.2 ± 4.8 g CH<sub>4</sub> C m<sup>-2</sup> y<sup>-1</sup>), a rate comparable to CH<sub>4</sub>-emitting wetlands. Emission rates were correlated to soil pH, organic matter content and quantities of buried woody debris. These properties led to strong CH<sub>4</sub> emissions, or “hotspots”, in certain areas of landings, particularly where processing of logs occurred and incorporated woody debris into the soil. At the forest level, emissions from landings were estimated to offset ~12% of CH<sub>4</sub> consumption from soils within the harvest area, although making up only ~0.5% of the harvest area. Management practices to avoid or remediate these emissions should be developed as a priority measure in “climate-smart” forestry.


2008 ◽  
Vol 53 (No. 5) ◽  
pp. 225-238 ◽  
Author(s):  
N. Finžgar ◽  
P. Tlustoš ◽  
D. Leštan

Sequential extractions, metal uptake by <i>Taraxacum officinale</i>, Ruby&rsquo;s physiologically based extraction test (PBET) and toxicity characteristic leaching procedure (TCLP), were used to assess the risk of Pb and Zn in contaminated soils, and to determine relationships among soil characteristics, heavy metals soil fractionation, bioavailability and leachability. Regression analysis using linear and 2nd order polynomial models indicated relationships between Pb and Zn contamination and soil properties, although of small significance (<i>P</i> < 0.05). Statistically highly significant correlations (<i>P</i> < 0.001) were obtained using multiple regression analysis. A correlation between soil cation exchange capacity (CEC) and soil organic matter and clay content was expected. The proportion of Pb in the PBET intestinal phase correlated with total soil Pb and Pb bound to soil oxides and the organic matter fraction. The leachable Pb, extracted with TCLP, correlated with the Pb bound to carbonates and soil organic matter content (<i>R</i><sup>2</sup> = 69%). No highly significant correlations (<i>P</i> < 0.001) for Zn with soil properties or Zn fractionation were obtained using multiple regression.


Weed Science ◽  
1983 ◽  
Vol 31 (3) ◽  
pp. 368-372 ◽  
Author(s):  
Josef Kozak ◽  
Jerome B. Weber

Adsorption of five phenylurea herbicides, metobromuron [3-(p-bromophenyl)-1-methoxy-1-methylurea], monolinuron [3-(p-chlorophenyl)-1-methoxyl-1-methylurea], linuron [3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea], chlorbromuron [3-(4-bromo-3-chlorophenyl)-1-methoxy-1-methylurea], and CGA-15646 [3-(3-chloro-4-methylphenyl)-1,1-dimethylurea] by eight selected soils of Czechoslovakia were studied. Constants from Freundlich and Langmuir equations were calculated and correlated with the major soil properties. Freundlich K values ranged from 1.84 to 128, and the Freundlich equation was better fitted to the adsorption isotherms than was the Langmuir equation. Soil organic-matter content was the most important factor influencing the range of adsorption.


1974 ◽  
Vol 54 (1) ◽  
pp. 7-14 ◽  
Author(s):  
L. S. CROSSON ◽  
R. PROTZ

Many soil mapping units (MU) have not been adequately sampled to provide a true measure of their variability; therefore, their descriptions must be regarded as incomplete, and valid statistical comparisons cannot be made with other closely related MU. The number of samples required to detect the differences in means of 18 soil properties between Brantford and Beverly Silt Loam MU were calculated and they ranged from 4 at the 80% probability level (10 at the 95% probability level) for organic matter content of the Ap horizon to several thousand for pH of the Ap horizon. Calculation of required sample numbers indicated that sufficient samples had been collected to make valid statistical comparisons between seven of the soil properties. All seven properties were found to be significantly different between the two MU at the 95% probability level. However, only two of the properties, hue and organic matter content of the Ap horizon, had distinctly different modal values between the two MU and neither of these properties is easily measured in the field. Therefore, it was concluded that the 18 soil properties examined were impractical and unreliable criteria for separating the MU in the field. But, the MU separations can be readily and validly made on the basis of landscape position.


1982 ◽  
Vol 62 (4) ◽  
pp. 631-639 ◽  
Author(s):  
G. T. PATTERSON ◽  
G. J. WALL

Replicate soil samples (2–20) from the A, B and C horizons of 41 pedons were collected to measure within-pedon variability of particle size distribution, organic matter content, calcium carbonate equivalent and pH. Variability in soil properties was examined in relation to the mode of origin of the soil material, soil horizonation and soil drainage. Variance in particle size distribution was significantly influenced by mode of deposition as well as by soil horizons, while soil drainage had no significant influence on the variation in particle size distribution. Variance in calcium carbonate equivalent and organic matter content was not influenced by soil drainage or mode of deposition. The number of replicate samples required for statistically reliable evaluation of a pedon at given confidence limits was determined for the soil properties studied. The results of these calculations indicate the need for up to five replicate samples to achieve satisfactory levels of accuracy at the 95% confidence level for some of the soil properties studied.


2020 ◽  
Vol 12 (4) ◽  
pp. 3189-3204
Author(s):  
Anne Hartmann ◽  
Markus Weiler ◽  
Theresa Blume

Abstract. Soil physical properties highly influence soil hydraulic properties, which define the soil hydraulic behavior. Thus, changes within these properties affect water flow paths and the soil water and matter balance. Most often these soil physical properties are assumed to be constant in time, and little is known about their natural evolution. Therefore, we studied the evolution of physical and hydraulic soil properties along two soil chronosequences in proglacial forefields in the Central Alps, Switzerland: one soil chronosequence developed on silicate and the other on calcareous parent material. Each soil chronosequence consisted of four moraines with the ages of 30, 160, 3000, and 10 000 years at the silicate forefield and 110, 160, 4900, and 13 500 years at the calcareous forefield. We investigated bulk density, porosity, loss on ignition, and hydraulic properties in the form of retention curves and hydraulic conductivity curves as well as the content of clay, silt, sand, and gravel. Samples were taken at three depths (10, 30, 50 cm) at six sampling sites at each moraine. Soil physical and hydraulic properties changed considerably over the chronosequence. Particle size distribution showed a pronounced reduction in sand content and an increase in silt and clay content over time at both sites. Bulk density decreased, and porosity increased during the first 10 millennia of soil development. The trend was equally present at both parent materials, but the reduction in sand and increase in silt content were more pronounced at the calcareous site. The organic matter content increased, which was especially pronounced in the topsoil at the silicate site. With the change in physical soil properties and organic matter content, the hydraulic soil properties changed from fast-draining coarse-textured soils to slow-draining soils with high water-holding capacity, which was also more pronounced in the topsoil at the silicate site. The data set presented in this paper is available at the online repository of the German Research Center for Geosciences (GFZ; Hartmann et al., 2020b). The data set can be accessed via the DOI https://doi.org/10.5880/GFZ.4.4.2020.004.


2018 ◽  
Vol 189 (2) ◽  
pp. 9 ◽  
Author(s):  
Maxime Debret ◽  
Yoann Copard ◽  
Antonin Van Exem ◽  
Geneviève Bessereau ◽  
Frank Haeseler ◽  
...  

Organic matter studies find an echo within different topics such as biogeochemical cycles, processes occurring in continental surfaces, anthropogenic activities, climate science, earth and planetary sciences, etc. Today’s challenges include finding and developing the most appropriate method(s) supporting the differentiation and characterisation of various types of recalcitrant organic matter in modern environments. In this study, we focus on combustion residues and coals as these two types of organic matter contain a significant amount of so-called recalcitrant organic carbon (black carbon and fossil organic carbon). Both these materials are ubiquitous, broadly stem from the same living organisms and have similar polyaromatic structures. In this respect, we tested a spectrophotometry method, classically used for sedimentology, as a very fast method for preliminary investigations. Analyses were performed with a wide range of standards and referenced samples. The results discriminate three different spectral signatures related to the degree of transformation of organic matter related to the degree of aromaticity (i.e. carbonisation). Using calibration curves, total organic carbon content can be estimated in experimental mixes with mineral matter and in a real context using subsurface sample (Gironville 101 borehole, Paris Basin, France). This method has particularly high sensitivity to very low organic matter content and is shown to be promising for a rapid evaluation of the organic carbon content.


2019 ◽  
Vol 53 (3) ◽  
pp. 177-186 ◽  
Author(s):  
M. K. Patsyuk ◽  
I. P. Onyshchuk

Abstract Taxonomy of naked amoebae and specifics of their distribution in water bodies of Sumy Region are presented. Our research identified 12 species of naked amoebae of 11 morphotypes. We established their ecological groups relative to abiotic aquatic factors: euryoxidic, stenooxidic, stenobiotic and those that survive in a wide range of organic matter content. According to the species composition, swamp and riparian species complexes of naked amoebae were identified. It was found that species complexes of amoeba are influenced by such factors as temperature, concentration of dissolved oxygen and organic compounds.


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