Main Controlling Factors and Empirical Models for Total Mercury and Methylmercury Accumulation in Rice (Oryza Sativa L.)

It has been reported that rice consumption is the main mercury (Hg) exposure pathway for humans, and soil properties could significantly affect the methylation and accumulation process of Hg in soil-rice system. In this study, 19 paddy soil with various properties were spiked with exogenous Hg(II) at three concentration levels to conduct a pot experiment after a 60-days aging period. Stepwise multiple linear regression was applied to determine the controlling soil factors and develop prediction models for the methylmercury (MeHg) concentration in soil and total Hg (THg) and MeHg in brown rice. The results showed that THg in brown rice was positively correlated with THg in soil, while it had a negative correlation with soil pH and clay content. Soil organic matter (OM) promoted Hg methylation and inhibited the accumulation of MeHg in brown rice. Soil pH and clay content were negative factors when soil MeHg was used to predict MeHg in brown rice. THg and MeHg in brown rice could be well predicted by soil THg, pH and clay content. These results may provide a theoretical basis for safe production of rice in Hg contaminated paddy field.

Fracturing Height Growth Restriction Technique Successfully Extended into Horizontal Wells in Ostracod Formation

The Ostracod formation in the Awali brownfield is an extremely challenging layer to develop because the tight carbonate rock is interbedded with shaly streaks and because of the presence of a nearby water-bearing zone. Although the Ostracod formation has been in development since 1960, oil recovery has not yet reached 5% because past stimulation attempts experienced rapid production decline. The current project incorporated aggressive fracture design coupled with a unique height growth control (HGC) workflow, improving the development of Ostracod reserves. The HGC technology is a combination of an engineering workflow supported by geomechanical modeling and an advanced simulator of in-situ kinetics and materials transport to model the placement of a customized, impermeable mixture of particles that will restrict fracture growth. The optimized treatment design included injections of the HGC mixture prior to the main fracturing treatment. This injection was done with a nonviscous fluid to improve settling to create an artificial barrier. After the success of a trial campaign in vertical wells, the technique was adjusted for the horizontal wellbores. The high clay content within the Ostracod layers creates a significant challenge for successful stimulation. The high clay content prevents successful acid fracturing and leads to severe embedment with conventional proppant fracturing designs. We introduced a new approach to stimulate this formation with an aggressive tip-screenout design incorporating a large volume of 12/20-mesh proppant to obtain greater fracture width and conductivity, resulting in a significant and sustained oil production gain. The carefully designed HGC technique was efficient in avoiding fracture breakthrough into the nearby water zone, enabling treatments of up to 450,000 lbm to be successfully contained above a 20-ft-thick shaly barrier with small horizontal stress contrast. Independent measurements proved that the fracture height was successfully contained. This trial campaign in vertical wells proved that the combination of aggressive, large fracture designs with the HGC method could help unlock the Ostracod’s potential. Three horizontal wells were drilled and simulated, each with four stages of adjusted HGC technique to verify if this aggressive method was applicable to challenging sand admittance in case of transverse fractures. This rare implementation of HGC mixtures in horizontal wells showed operational success and proof of fracture containment based on pressure signatures and production monitoring. The applied HGC technique was modified with additional injections and improved by advanced modeling that only recently became available. These contributed to a significant increase of treatment volume, making the jobs placed in the Ostracod some of the world’s largest utilizing HGC techniques. The experience gained in this project can be of a paramount value to any project dealing with hydraulic fracturing near a water formation with insufficient or uncertain stress barriers.

Distributions and Risk Assessment of the Natural Radionuclides in the Soil of Shoubra El Kheima, South Nile Delta, Egypt

Due to heightening concern about radiation hazards protection, activity concentrations of 226Ra, 232Th, 40K in forty soil samples collected from Shoubra El Kheima in the South Nile Delta were measured using gamma-ray spectrometry. The mean activity concentrations of 226Ra and 40K were higher in 20% of the considered samples than the world average values. A comprehensive comparison with up-to-date data was carried out. Spatial distribution maps of the measured radionuclides and radiological parameters were generated. The distributions of natural radionuclides were influenced by the soil organic matter, clay content, and scavenger metals oxides, as well as differences in the physical and chemical attributes and solubility of these radionuclides. The results revealed that industrial activity and agricultural practices in the study area caused an incremental increase in 226Ra and 40K activity concentrations. It can be deduced that although there are intensive industrial activities in this area, the natural radiation that comes from the soil is normal and does not pose a significant radiological hazard to the public. The natural radioactivity of soil in this area needs to be monitored periodically to prevent unnecessary radiation exposure to inhabitants.

Climate Data to Predict Geometry of Cracks in Expansive Soils in a Tropical Semiarid Region

The nonlinear dynamics of the determining factors of the morphometric characteristics of cracks in expansive soils make their typification a challenge, especially under field conditions. To overcome this difficulty, we used artificial neural networks to estimate crack characteristics in a Vertisol under field conditions. From July 2019 to June 2020, the morphometric characteristics of soil cracks (area, depth and volume), and environmental factors (soil moisture, rainfall, potential evapotranspiration and water balance) were monitored and evaluated in six experimental plots in a tropical semiarid region. Sixty-six events were measured in each plot to calibrate and validate two sets of inputs in the multilayer neural network model. One set was comprised of environmental factors with significant correlations with the morphometric characteristics of cracks in the soil. The other included only those with a significant high and very high correlation, reducing the number of variables by 35%. The set with the significant high and very high correlations showed greater accuracy in predicting crack characteristics, implying that it is preferable to have fewer variables with a higher correlation than to have more variables of lower correlation in the model. Both sets of data showed a good performance in predicting area and depth of cracks in the soils with a clay content above 30%. The highest dispersion of modeled over predicted values for all morphometric characteristics was in soils with a sand content above 40%. The model was successful in evaluating crack characteristics from environmental factors within its limitations and may support decisions on watershed management in view of climate-change scenarios.

Evaluating Soil Water Matric Pressure and Sorptivity Relationship as Affected by some Properties of a Clay Soil

Sorptivity (S) is the fundamental variable controlling the early infiltration process. Besides soil properties, soil initial water content (θi) and/or matric pressure (hi) are key factors determining extent of S. Assessment of interrelationship among S, hi and soil properties can provide a considerable insight into understanding the behaviour of dry soils to rainfall or irrigation water. This study was conducted to evaluate relationship between S and some selected soil parametric and morphometric properties within a range of hi. Sixteen undisturbed soil samples (5 cm id, 5 cm length) were taken from the topsoil (0-15 cm) of a paddy soil with clay texture. Sorptivity was measured with a mini-disc infiltrometer (MDI) on the samples equilibrated at h, ranging from -20 to -1500 kPa. A parameter (η), representing the relationship between S and hi, was introduced. Correlation analysis was conducted between η and selected soil morphometric and parametric properties. Soil structure and clay content appeared the most important soil attributes influencing S-hi relation between -200 and -1500 kPa. The results provided a fundamental understanding on S-hi-soil properties interrelations in a clay soil. The methodology developed in this study can be used to evaluate S-hi relationship across different soils and scales.

Effects of Clay in Nylon Fibe

Since the introduction of nylon 6:6, and nylon 6, the nylon fiber was in significant demand in home textile and technical textile articles. Its uses in hosiery, sail cloth, parachute, blouses, gowns and veils, swim suit, parachute, and lingerie etc. Improving the performance of any nylon matrix with the loading of clay content, for the desired effects, can be an important subject to expand the utilization of nylon in automotive, technical textiles etc. This review study is to find out how clay may contribute in the performance of nylon fiber, and what research directions are appealing in achieving the desired effects in nylon fibers. The known effects on orientation and crystal structure of any nylon polymer; and how the advantageous effects in the utilization of nylon are achievable through the incorporation of clay mineral particularly in composite fiber. Strength, fatigue and thermal stability are some improved effects possible. Heat resistance and flame retardancy are particularly discussed. The aim of this review study is to realize how the nylon fiber was modified using the montmorillonite clay; and to explore what are the possible effects, and improvement achieved.

The Effect of Both Moisture and Clay Content on The Soil Corrosion Process for Different Periods of Time as A Geomorphological Study in Al-Kut City

Soil corrosion is a major hazard to subterranean infrastructure including gas and oil transmission pipes, underground storage tanks and others. The impacts of soil engineering characteristics on buried mild steel coupons’ metal loss are investigated in this work. Soil characteristics such as soil clay and moisture content are the focus of the present research in Al-Kut city near Tigris River. For a twelve month period, 100 pieces of mild steel coupons were put underground in five different sites across to look into the effects of the aforementioned variables on loss of metal owing to corrosion of soil. Every three months, the samples were recovered to evaluate the rate of weight loss and corrosion rate development. The data show that the high moisture content of the soil is linked to rapid corrosion development. Corrosion on clay soil, on the other hand, takes longer to start. According to the qualitative assessment, soil moisture content has a greater impact on corrosion dynamics than clay content.

Interpretation of Construction Procedure and Physicochemical Characteristics for Soil Layers from Sowangneung (Small Royal Tomb) of Ssangneung (Twin Tombs) in Iksan, Korea

The Iksan Ssangneung (twin tombs), a pair of tombs comprising the Daewangneung (large royal tomb) and the Sowangneung (small royal tomb), were constructed in the typical style of stone tunnel and chamber tombs in the Baekje Kingdom during the Sabi period (538 to 660 AD) of ancient Korea. Soil layers exposed during excavation of Sowangneung in a trench east of the tomb are: the bottommost layer, the ground level layer, the Panchuk (rammed earth) layer of the Baekje, the layer created by a grave robbery, and soil recovered during the Japanese colonial period. Soil samples were obtained by segmenting an easy stratigraphic horizon into sub categorized soil layers, and their material properties were analyzed; they are composed mainly of sandy loam based on the particle size distributions. In the site foundation, loamy sand is packed in the bottommost layer, and sandy loam with high sand and silty sand fills most of the overlying layer. The central and topmost portion of the Baekje layer is composed of loam with high clay content. All soil layers show geochemical behaviors similar to those of the bottommost layer. X-ray diffraction analysis verified kaolinite in all layers, also observed in soil layers displaying high crystallinity. Kaolinite and halloysite were identified by scanning electron microscopy. Thus, we conclude that the Baekje layer of the Sowangneung is composed of sandy loam containing kaolin procured from near the site. An impermeable middle to upper layer was created using viscous loam. The top of the tomb was closed tightly.

Estimating cation exchange capacity and clay content from agricultural soil testing data

Clay content and the ability to reversibly retain cations affect many essential chemical and physical properties of soil, such as pH buffering and carbon sequestration. Cation exchange capacity (CEC) and base saturation are also commonly used as criteria in soil classification. However, determination of CEC and particle-size distribution is laborious and not included in routine soil testing. In this study, pedotransfer functions including soil test cations (STCat; Ca2+ + Mg2+ + K+), pH and soil organic carbon (SOC, %) as explanatory variables were developed for estimating CEC, titratable acidity (TA; H+ + Al3+) and clay content (clay, %). In addition, reference values for potential CEC and its components were determined for Finnish mineral and organic soils. The mean of potential CEC extracted by 1 M ammonium acetate at pH 7.0 ranged from 14 (range 6.4−25) in coarse soils to 33 (21−45) cmol(+) kg-1 in heavy clay soils, and from 42 (24−82) in mull soils to 77 (25−138) cmol(+) kg-1 in peat soils. The average CEC of clay and SOC were 27 and 160 cmol(+) kg-1, respectively. Titratable acidity occupied 53% and around 40% of the CEC sites in organic and mineral soils, respectively, evidencing that it is a prominent component of the potential CEC in these predominantly acidic soils. STCat, pH and SOC explained 96% of the variation in potential CEC. STCat and pH can be used in estimating the clay content especially for soils containing over 30% clay. In coarse textured soils, in contrast, SOC hampers the STCat based estimation of clay content.