STABILITY OF EMULSIONS : A MODEL DESCRIBING COALESCENCE OF HEAVY OILS IN GRAVITY FIELDS

Author(s):  
Jason Stoyel ◽  
T. Sontvedt
Keyword(s):  
Author(s):  
V.A. Munoz ◽  
R.J. Mikula ◽  
C. Payette ◽  
W.W. Lam

The transformation of high molecular weight components present in heavy oils into useable liquid fuels requires their decomposition by means of a variety of processes. The low molecular weight species produced recombine under controlled conditions to generate synthetic fuels. However, an important fraction undergo further recombination into higher molecular weight components, leading to the formation of coke. The optical texture of the coke can be related to its originating components. Those with high sulfur and oxygen content tend to produce cokes with small optical texture or fine mosaic, whereas compounds with relatively high hydrogen content are likely to produce large optical texture or domains. In addition, the structure of the parent chemical components, planar or nonplanar, determines the isotropic or anisotropic character of the coke. Planar molecules have a tendency to align in an approximately parallel arrangement to initiate the formation of the nematic mesophase leading to the formation of anisotropic coke. Nonplanar highly alkylated compounds and/or those rich in polar groups form isotropic coke. The aliphatic branches produce steric hindrance to alignment, whereas the polar groups participate in cross-linking reactions.


2008 ◽  
Author(s):  
Birol Demiral ◽  
Serhat Akin ◽  
Cagdas Acar ◽  
Berna Hascakir

Author(s):  
Pedro Romero Rojas ◽  
◽  
Alexandrina Cristea ◽  
Paul Pavlakos ◽  
Okan Ergündüz ◽  
...  

10.2118/98-63 ◽  
1998 ◽  
Author(s):  
Y. Zhang ◽  
C.L. Hyndman ◽  
B. Maini
Keyword(s):  

2021 ◽  
Vol 13 (16) ◽  
pp. 3075
Author(s):  
Ming Xu ◽  
Xiaoyun Wan ◽  
Runjing Chen ◽  
Yunlong Wu ◽  
Wenbing Wang

This study compares the Gravity Recovery And Climate Experiment (GRACE)/GRACE Follow-On (GFO) errors with the coseismic gravity variations generated by earthquakes above Mw8.0s that occurred during April 2002~June 2017 and evaluates the influence of monthly model errors on the coseismic signal detection. The results show that the precision of GFO monthly models is approximately 38% higher than that of the GRACE monthly model and all the detected earthquakes have signal-to-noise ratio (SNR) larger than 1.8. The study concludes that the precision of the time-variable gravity fields should be improved by at least one order in order to detect all the coseismic gravity signals of earthquakes with M ≥ 8.0. By comparing the spectral intensity distribution of the GFO stack errors and the 2019 Mw8.0 Peru earthquake, it is found that the precision of the current GFO monthly model meets the requirement to detect the coseismic signal of the earthquake. However, due to the limited time length of the observations and the interference of the hydrological signal, the coseismic signals are, in practice, difficult to extract currently.


Fuel ◽  
1980 ◽  
Vol 59 (9) ◽  
pp. 647-653 ◽  
Author(s):  
Speros E. Moschopedis ◽  
Randall W. Hawkins ◽  
John F. Fryer ◽  
James G. Speight
Keyword(s):  

2013 ◽  
Vol 91 (9) ◽  
pp. 872-878 ◽  
Author(s):  
Stanislav R. Stoyanov ◽  
Cindy-Xing Yin ◽  
Murray R. Gray ◽  
Jeffrey M. Stryker ◽  
Sergey Gusarov ◽  
...  

The vanadium and nickel components in heavy oils and bitumen are important impurities in catalytic processing and form aggregates with other asphaltene components. Metalloporphyrins are commonly analyzed using the characteristic Soret band in the UV–vis absorption spectrum. However, the Soret band of metalloporphyrins in petroleum is broadened and weaker than expected based on the concentration of Ni and V in heavy oils and the extinction coefficients of isolated porphyrins. We hypothesize that the low intensity and broadening of the Soret band could be due to axial coordination of the metal center or fusion (annelation) of aromatic rings on the porphyrin π-system. This hypothesis is examined using the density functional theory for geometry optimization and time-dependent density functional theory (TD-DFT) for calculation of excited states of nickel(II) and vanadyl porphyrins with axially coordinated ligands and annelated polyaromatic hydrocarbons. Predictions of the excited electronic states performed using the tandem of TD-DFT and conductor-like polarizable continuum model of solvation support this hypothesis and provide insight into the extent of Soret band broadening and intensity decrease due to coordination and annelation. These computational results, validated with respect to visible absorption spectra, are important for understanding asphaltene aggregation and spectroscopic characterization and suggest methods for removal of transition metals from heavy oil.


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