scholarly journals  Bioavailability and mobility of Pb after soil treatment with different remediation methods

2011 ◽  
Vol 52 (No. 1) ◽  
pp. 25-34 ◽  
Author(s):  
N. Finžgar ◽  
B. Kos ◽  
D. Leštan

The risk of Pb contaminated soil after treatment with different remediation techniques was assessed. Soil vitrification (microwaves) reduced Pb orally available from the stomach and intestinal phase measured by a physiologically based extraction test. Solidification of Pb (Slovakite) did not reduce the concentration of orally available Pb and increased the Pb uptake by Thlaspi goesingens for 2-times compared to plants grown on the original soil. Soil extraction with 40 mmol/kg EDTA removed 57.6% of Pb. However, the concentration of orally available Pb and Pb uptake by T. goesingens increased. The concentration of mobile soil Pb also increased for 14-times measured by a toxicity characteristic leaching procedure. Soil leaching with 10 mmol/kg biodegradable chelator [S,S] ethylenediamine disuccinate and using a horizontal permeable reactive barrier for Pb accumulation from the washing solution removed 17.8% of Pb, but increased Pb uptake by T. goesingens by 3-times and slightly increased the concentration of Pb in the intestinal phase. Leaching did not significantly effects Pb availability from the stomach phase or Pb mobility.

1996 ◽  
Vol 30 (2) ◽  
pp. 422-430 ◽  
Author(s):  
Michael V. Ruby ◽  
Andy Davis ◽  
Rosalind Schoof ◽  
Steve Eberle ◽  
Christopher M. Sellstone

2020 ◽  
Vol 55 (4) ◽  
pp. 370-381
Author(s):  
Zhibin Zhang ◽  
Xianhui Shi ◽  
Yanhao Zhang ◽  
Shengrui Wang ◽  
Meng Wang ◽  
...  

Abstract The immobilization performances of Diatomite, Ca(H2PO4)2, CaCO3, Hydroxyapatite (HAP) and Nano-HAP (n-HAP) for Zn, Mn, Pb, and Cd contaminated sediments were investigated by immobilization experiments and evaluated by the European Community Bureau of Reference (BCR) extraction test, toxicity characteristic leaching procedure (TCLP). The result of BCR indicated that HAP and Nano-HAP (n-HAP) had a better immobilization effect on metal contaminated sediments, and the residual fractions of Zn, Mn, Pb, and Cd increased from 30.4, 31.9, 55.49 and 54.27% to 36, 39, 72, and 57%, respectively. The order for immobilized effects of additive was: n-HAP > HAP > CaCO3 > Ca(H2PO4)2 > diatomite. However, the cost-effectiveness of HAP was slightly higher than that of n-HAP, so HAP was more suitable for immobilization of heavy metals in sediment. The TCLP test showed that with HAP as immobilization the leaching amount was reduced by approximately 76, 28, 78, and 85% for Zn, Mn, Pb, and Cd, respectively, compared to the blank group. The results also proved that HAP would be an effective and economical agent for immobilizing heavy metals in sediment, with the optimum mass dosage of 10% (the mass ratios of HAP/sediment (dry weight)) of the sediment.


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