scholarly journals Effect of Spacer and Alkyl Chain Groups of the Synthesized Cationic Gemini Surfactants on the Surface Modification of Nano Na-Montmorillonite and its Dye Adsorption from Textile Waste Water

2016 ◽  
Vol 9 (S1) ◽  
Author(s):  
AJavad Ahmadishoar ◽  
Hajir Bahrami ◽  
Brahman Movassagh ◽  
S. Hossain Amirshahi ◽  
Mokhtar Arami
2011 ◽  
Vol 23 (2) ◽  
pp. 243-251 ◽  
Author(s):  
Ola M. Gomaa ◽  
Hussein Abd El Kareem ◽  
Reham Fatahy

2019 ◽  
Vol 233 (5) ◽  
pp. 707-720 ◽  
Author(s):  
Manorama Panda ◽  
Nazish Fatma ◽  
Mohammad Kamil

Abstract The present investigation involves the synthesis of a series of novel green ethylene oxide-linked diester-functionalized cationic gemini surfactants 2,2′-[(oxybis(ethane-1,2-diyl))bis(oxy)]bis(N-alkyl-N,N-dimethyl-2-oxoethanaminium) dichloride (Cm-DEG-Cm; m = 12, 14, 16). These compounds were characterized by 1H-NMR, MS-ESI (+), FT-IR spectroscopy and elemental analysis; their solution properties were evaluated by surface tension and rheology measurements. The dimeric surfactant, Cm-DEG-Cm, possesses improved physicochemical properties as compared to its monomeric counterpart. Much lower critical micelle concentration (cmc) makes the cationic gemini surfactants more useful for the biomedical, pharmaceutical, industrial and academic sectors. Longer the alkyl chain of surfactants lower are the cmc values, the order is C16-DEG-C16 < C14-DEG-C14 < C12-DEG-C12. For all the three synthesized gemini surfactants no cloud point was noticed in between the temperatures 0 °C to 100 °C at the concentrations 0.002 mM, 0.02 mM and 0.2 mM of the aqueous surfactant solutions which is a beneficial factor for the use of these amphiphiles in various areas of application.


2018 ◽  
Vol 103 ◽  
pp. 323-328
Author(s):  
Héctor Salas ◽  
Víctor Lopez-Grimau ◽  
Mercedes Vilaseca ◽  
Martí Crespi ◽  
Carmen Gutierrez-Bouzán

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