scholarly journals EFFECT OF PHASE CHANGES OF DISPERSAL PHASE STRAINS ON HYDRODYNAMICS OF LIQUID EMULSIONS

Author(s):  
A.K. Rozentsvaig
Keyword(s):  
Author(s):  
J. M. Cowley ◽  
Sumio Iijima

The imaging of detailed structures of crystal lattices with 3 to 4Å resolution, given the correct conditions of microscope defocus and crystal orientation and thickness, has been used by Iijima (this conference) for the study of new types of crystal structures and the defects in known structures associated with fluctuations of stoichiometry. The image intensities may be computed using n-beam dynamical diffraction theory involving several hundred beams (Fejes, this conference). However it is still important to have a suitable approximation to provide an immediate rough estimate of contrast and an evaluation of the intuitive interpretation in terms of an amplitude object.For crystals 100 to 150Å thick containing moderately heavy atoms the phase changes of the electron wave vary by about 10 radians suggesting that the “optimum defocus” theory of amplitude contrast for thin phase objects due to Scherzer and others can not apply, although it does predict the right defocus for optimum imaging.


Metrologiya ◽  
2020 ◽  
pp. 25-42
Author(s):  
Dmitrii V. Khablov

This paper describes a promising method for non-contact vibration diagnostics based on the use of Doppler microwave sensors. In this case, active irradiation of the object with electromagnetic waves and the allocation of phase changes using two-channel quadrature processing of the received reflected signal are used. The modes of further fine analysis of the resulting signal using spectral or wavelet transformations depending on the nature of the active vibration are considered. The advantages of this non-contact and remote vibration analysis method for the study of complex dynamic objects are described. The convenience of the method for machine learning and use in intelligent systems of non-destructive continuous monitoring of the state of these objects by vibration is noted.


Author(s):  
Suresh Akella ◽  
◽  
B Ramesh Kumar ◽  
Keyword(s):  

2018 ◽  
Author(s):  
C. Michael McGuirk ◽  
Tomče Runčevski ◽  
Julia Oktawiec ◽  
Ari Turkiewicz ◽  
mercedes K. taylor ◽  
...  

<p>Metal–organic frameworks that display step-shaped adsorption profiles arising from discrete pressure-induced phase changes are promising materials for applications in both high-capacity gas storage and energy-efficient gas separations. The thorough investigation of such materials through chemical diversification, gas adsorption measurements, and <i>in situ </i>structural characterization is therefore crucial for broadening their utility. We examine a series of isoreticular, flexible zeolitic imidazolate frameworks (ZIFs) of the type M(bim)<sub>2</sub> (SOD; M = Zn<sup> </sup>(ZIF-7), Co (ZIF-9), Cd (CdIF-13); bim<sup>–</sup> = benzimidazolate), and elucidate the effects of metal substitution on the pressure-responsive phase changes and the resulting CO<sub>2</sub> and CH<sub>4</sub> step positions, pre-step uptakes, and step capacities. Using ZIF-7 as a benchmark, we reexamine the poorly understood structural transition responsible for its adsorption steps and, through high-pressure adsorption measurements, verify that it displays a step in its CH<sub>4 </sub>adsorption isotherms. The ZIF-9 material is shown to undergo an analogous phase change, yielding adsorption steps for CO<sub>2</sub> and CH<sub>4</sub> with similar profiles and capacities to ZIF-7, but with shifted threshold pressures. Further, the Cd<sup>2+</sup> analogue CdIF-13 is reported here for the first time, and shown to display adsorption behavior distinct from both ZIF-7 and ZIF-9, with negligible pre-step adsorption, a ~50% increase in CO<sub>2</sub> and CH<sub>4</sub> capacity, and dramatically higher threshold adsorption pressures. Remarkably, a single-crystal-to-single-crystal phase change to a pore-gated phase is also achieved with CdIF-13, providing insight into the phase change that yields step-shaped adsorption in these flexible ZIFs. Finally, we show that the endothermic phase change of these frameworks provides intrinsic heat management during gas adsorption. </p>


Author(s):  
С.П. Исаев ◽  
К.А. Шевчук

Современное развитие деревоперерабатывающей отрасли сопровождается существенным ростом объемов готовой продукции, производимой на основе клееной древесины. Качество выпускаемой клееной продукции во многом определяется свойствами применяемых клеев. Экспериментально исследовано влияние электромагнитного поля СВЧ-диапазона на структуру клеев, применяемых для склеивания древесины. Установлено, что СВЧ-обработка оказывает существенное влияние на микроструктуру поливинилацетатного клея Dorus 072. Структура клеевой пленки, обработанной СВЧ-излучением, имеет более высокую дисперсность, по сравнению с исходным полимером, которая выражается в среднем уменьшении глобул в 1,4 раза. Исследование фазового контраста пленки поливинилацетатного клея, обработанного СВЧ-излучением, позволило установить, что после обработки уменьшается фазовая неоднородность клеевой пленки и имеет место углубление дисперсности глобул полимера, приводящее к увеличению степени его упаковки с образованием однородной по структуре пленки. Экспериментальные исследования пленок карбамидоформальдегидного клея Dorus FU 406, подвергнутого СВЧ-обработке, показали, что структуры образцов пленок как обработанного, так и необработанного, клея не отличаются значительными изменениями. Исследование фазового сдвига по поверхности образца пленки карбамидоформальдегидного клея отражает распределение свойств материала и показывает, что СВЧ-обработка клея способствует образованию квазигомогенной структуры, формирование которой подтверждается уменьшением различий в границах фазовых переходов микроструктур отвержденного полимера. На основании проведенных экспериментов по исследованию структуры пленок клеев, применяемых для склеивания древесины, установлено, что в результате воздействия электромагнитного поля СВЧ-диапазона на клеевые растворы осуществляется нетепловая модификация, сопровождающаяся уменьшением размеров макромолекул полимера и формированием плотно упакованной структуры пленки. Полученные результаты позволяют сделать вывод о целесообразности дальнейших исследований по модификации клеев СВЧ-обработкой. Modern development of woodworking branches is accompanied by essential growth of volumes of the finished goods manufactured on the basis of glued wood. Quality of let out glued production in many respects is defined by properties of applied glues. Influence of an electromagnetic field of a microwave range on frame of the glues applied to coagglutination of wood is experimentally investigated. It is positioned that microwave processing makes essential impact on a microstructure of polyvinyl acetate glue Dorus 072. The frame of the adhesive film treated by microwave radiation, has higher dispersity in comparison with initial polymer which is expressed on the average reduction of globules in 1,4 times. Research of phase contrast of a film of the treated polyvinyl acetate glue by microwave radiation has allowed to position that after processing phase heterogeneity of an adhesive film decreases and the excavation of dispersity of globules of the polymer, leading to augmentation of degree of its packaging, forming an unimodal film on frame takes place. Experimental researches of films of amino-formaldehyde glue Dorus FU 406, subjected to microwave processing, have shown that Frames of samples of films both treated, and untreated glue do not differ significant changes. Research of phase alteration on a surface of the sample of a film of amino-formaldehyde glue reflects allocation of properties of a stuff and shows that glue microwave processing promotes formation of the quasi-homogeneous frame which formation proves to be true reduction of distinctions in borders of phase changes of microstructures hardning polymer. On the basis of the made experiments on research of frame of films of the glues applied to coagglutination of wood it is positioned that as a result of influence of an electromagnetic field of the microwave oven of a range on glutinous solutions not thermal modification accompanied by reduction of the dimensions of macromolecules of polymer and formation of densely packed frame of a film is carried out. The received results allow to draw a conclusion on expediency of the further researches on modification of glues by microwave processing.


2009 ◽  
Author(s):  
Arthur Huang ◽  
David Matthew Levinson
Keyword(s):  

2012 ◽  
Vol 9 (1) ◽  
pp. 162-164
Author(s):  
S.V. Khabirov

Distribution of plane, spherical and cylindrical waves in steam-gaseous mixes with unequigranular particles and drops when one of fractions participates in phase changes is studied. The dispersion ratio is received, dispersion curves are calculated. Influence of a polydispersity of particles and drops on dispersion and a dissipation of small indignations is analysed.


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