scholarly journals Solid-phase microextraction of benzophenones coupled with gas chromatography analysis

2016 ◽  
Vol 4 (2) ◽  
pp. 55-62
Author(s):  
Valentyna Levchyk ◽  
M. Zui
Keyword(s):  
Gas Chromatography ◽  
Solid Phase Microextraction ◽  
Solid Phase ◽  
Enrichment Factors ◽  
Chromatography Analysis ◽  
Fiber Coating ◽  
Flame Ionization ◽  
Gas Chromatography Analysis ◽  
Relative Standard ◽  
Ph Range

In this study, solid-phase microextraction method combines with gas chromatography-flame ionization detector. The proposed method is used for the preconcentration of some benzophenones. Influence of different factors on the efficiency of extraction is described in detail. The analytical procedure was optimized for fiber coating selection, extraction time, temperature, sample pH, ionic strength. For all benzophenones, the highest enrichment factors were achieved using carboxen/polydimethylsiloxane/divinylbenzene fibre immersed directly into the water samples, containing 100 mg/mL of sodium chloride, at room temperature. The optimum pH range is 5.0 – 7.0. The relative standard deviations (RSDs) were from 1.3 to 10.0 % (n = 3). The method was applied to the determination of benzophenone, benzophenone-3, 2-hydroxybenzophenone in the lake water and urine.

scholarly journals Headspace solid-phase microextraction procedure for gas-chromatography analysis of toluene in urine

2008 ◽  
Vol 19 (6) ◽  
pp. 1201-1206 ◽  
Author(s):  
Diego C. Netto ◽  
Rafael M. Reis ◽  
Camila B. Mendes ◽  
Paulo C. F. L. Gomes ◽  
Isarita Martins ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Solid Phase Microextraction ◽  
Solid Phase ◽  
Headspace Solid Phase Microextraction ◽  
Chromatography Analysis ◽  
Gas Chromatography Analysis

Assessment of the effect of the non-volatile wine matrix on the volatility of typical wine aroma compounds by headspace solid phase microextraction/gas chromatography analysis

2011 ◽  
Vol 91 (13) ◽  
pp. 2484-2494 ◽  
Author(s):  
Juan José Rodríguez-Bencomo ◽  
Carolina Muñoz-González ◽  
Inmaculada Andújar-Ortiz ◽  
Pedro Jose Martín-Álvarez ◽  
Maria Victoria Moreno-Arribas ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Solid Phase Microextraction ◽  
Solid Phase ◽  
Aroma Compounds ◽  
Wine Aroma ◽  
Headspace Solid Phase Microextraction ◽  
Chromatography Analysis ◽  
Gas Chromatography Analysis ◽  
Wine Matrix

scholarly journals Ionic Liquid-modified NiTi Composite Nanosheets Coating for Efficient Solid Phase Microextraction of Octadecylamine in Brine

2019 ◽  
pp. 1-8
Author(s):  
Huiju Wang
Keyword(s):  
Ionic Liquid ◽  
Solid Phase Microextraction ◽  
Extraction Efficiency ◽  
Solid Phase ◽  
Correlation Coefficients ◽  
Fiber Coating ◽  
Relative Standard ◽  
Optimized Conditions ◽  
As Solid Phase

Ionic     liquid (IL), 1-dodecyl-3-methylimidazolium-3-hydroxy-2-naphthoate (C12mimHNC) was synthesized and coated on the surface of NiTi as solid phase microextractiom fiber coating for determination the octadecylamine in brine. Prior to modification with IL, the NiTi was hydrothermally treated for in-situ growth of titanium and nickel oxide composite nanosheets (TiO2/NiOCNSs). The TiO2/NiOCNSs fibers coating was oriented  around the NiTi  substrate and  presented  double-faced  open  access  sites,  which provided a desired support framework for the further modification with IL. The extraction performance of C12mimHNC-TiO2/NiOCNSs fiber coating was evaluated for       detection of octadecylamine (ODA) coupled to HPLC with UV detection. As a result, the C12mimHNC-TiO2/NiOCNSs fiber coating illustrated excellent adsorption and extraction capability for ODA. The main factors affected extraction efficiency were optimized. Under the optimized  conditions,  good  linearity was  obtained  in  the  range of  1-150  µg/L with correlation  coefficients  (r2)  above  0.985.  Limits of detection (LODs) for  the  developed method was 0.280 µg/L. The proposed method was first applied to extract the ODA in brine samples. Relative recoveries varied from 78.3% to 96.5% at spiking level of 15µg/L and 30 µg/L with the relative standard deviations (RSDs) less than 8.7%.

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