scholarly journals Organophosphate Flame Retardants in Car Dust from Thailand and Implications for Human Exposure

Author(s):  
Premrudee Kanchanapiya ◽  
◽  
Benjawan Nilyok ◽  
Supachai Songngam ◽  
Sun Olapiriyakul ◽  
...  

Organophosphorus flame retardants (PFRs) are a group of compounds frequently detected in indoor dust that pose high health risks to exposure subjects. The present study reports on the investigation of the levels and profiles of seven target PFRs in car dust samples from Thailand. The samples were collected from the discarded air conditioning (AC) filter of 14 private cars (called AC dust samples) and from the bag filter installed in vacuum cleaners of 10 car washing services (called settled dust samples) in 2019. The concentrations of 7PFRs in AC dust samples were approximately 3,800-91,000 ng/g, whereas those from settled dust samples were about 11,000 to 15,000 ng/g. Tris (2-butoxyethyl) phosphate (TBEP) was found to be the most prominent of PFRs detected in both types of car dust with the highest concentration of 39,000 ng/g for AC filter dust and 10,000 ng/g for settled dust. The main PFR contributors in both dust types were TBEP (80%, 75%), followed by Tris (2-ethylhexyl) phosphate (TEHP) (9%, 5%) and tris(1-chloro-2-propyl)phosphate (TCPP) (7%, 4%), respectively. Tris(2-chloroethyl)phosphate (TCEP) and tri cresyl phosphate (TCP) were not detected in both types of car dust and tris(1,3-dichloro-2-propyl) phosphate (TDCPP) was found only in settled dust samples. According to the results of exposure assessment to PFRs in car dust, the human exposures via ingestion for adults and toddlers ranged from 1.69×10-2 to 2.67 and 10.6 to 2,360 ng/kg/day. The human exposures via inhalation for adults and toddlers ranged from 3.27×10-4 to 5.17x10-2 and 2.58×10-1 to 40.9 ng/kg/day. The highest exposure among PFRs corresponded to TBEP for both adults and toddlers and the risk through ingestion was higher than inhalation intake. Toddlers were more exposed to PFR contaminants in comparison to adults. When comparing the estimated average daily intake (ADI) values with the reference doses (RfDs) for PFRs, it was found that exposure to PFRs in car cabins via inhalation and dust ingestion is unlikely to have adverse human health effects.

Author(s):  
Nadeem Ali ◽  
Nabil A. Alhakamy ◽  
Iqbal M. I. Ismail ◽  
Ehtisham Nazar ◽  
Ahmed Saleh Summan ◽  
...  

In this study, we measured the occurrence of organophosphate esters (OPEs) and phthalates in the settled dust (floor and air conditioner filter dust) and in suspended particulate matter (PM10) from different microenvironments (households (n = 20), offices (n = 10) and hotels (n = 10)) of Jeddah, Saudi Arabia. Bis (2-Ethylhexyl) phthalate (DEHP) was the major pollutant (contributing >85% of total chemicals burden) in all types of indoor dust with a concentration up to 3,901,500 ng g−1. While dibutyl phthalate (DBP) and DEHP together contributed >70% in PM10 (1900 ng m−3), which indicate PM10 as a significant source of exposure for DBP and DEHP in different Saudi indoor settings. Tris (1-chloro-2-propyl) phosphate (TCPP) was the major OPE in PM10 with a concentration of up to 185 ng m−3 and the occurrence of OPEs in indoor dust varied in studied indoor settings. The estimated daily intake (EDI) of studied chemicals via dust ingestion and inhalation of PM10 was below the reference dose (RfD) of individual chemicals. However, estimated incremental lifetime cancer risk (ILCR) with moderate risk (1.5 × 10−5) for Saudi adults and calculated hazardous index (HI) of >1 for Saudi children from DEHP showed a cause of concern to the local public health.


Chemosphere ◽  
2015 ◽  
Vol 133 ◽  
pp. 47-52 ◽  
Author(s):  
Chun-Tao He ◽  
Jing Zheng ◽  
Lin Qiao ◽  
She-Jun Chen ◽  
Jun-Zhi Yang ◽  
...  

2018 ◽  
Vol 237 ◽  
pp. 695-703 ◽  
Author(s):  
Joyce Cristale ◽  
Tiago Gomes Aragão Belé ◽  
Silvia Lacorte ◽  
Mary Rosa Rodrigues de Marchi

Chemosphere ◽  
2017 ◽  
Vol 184 ◽  
pp. 185-191 ◽  
Author(s):  
Xiaobo Zheng ◽  
Lin Qiao ◽  
Adrian Covaci ◽  
Runxia Sun ◽  
Huiying Guo ◽  
...  

2019 ◽  
Vol 253 ◽  
pp. 120-129 ◽  
Author(s):  
Martin Brits ◽  
Sicco H. Brandsma ◽  
Egmont R. Rohwer ◽  
Jayne De Vos ◽  
Jana M. Weiss ◽  
...  

2019 ◽  
Vol 31 (1) ◽  
Author(s):  
Li Li ◽  
Yanling Qiu ◽  
Åsa Gustafsson ◽  
Annette M. Krais ◽  
Jana M. Weiss ◽  
...  

Abstract Background Physical and biological properties of dust particles might affect the availability and distribution of chemicals associated to indoor dust; however it has not been adequately examined. In this study, household dust from Shanghai was fractionated into five particle sizes and size distribution, morphology, surface area, organic matter, microorganisms, elemental composition, metals and organophosphorus flame retardants (OPFRs) compositions were characterized. Also, household dust samples from Stockholm that has previously been characterized were included in the analysis of OPFRs for comparison. Results The respirable fraction had a yield of 3.3% in mass percentage, with a particle size of 2.22 ± 2.04 µm. As expected, both metals and OPFRs concentrations increased with decreased particle size. Al and Fe dominated (66–87%) followed by the concentrations of Zn (5–14%) and Ga (1.8–5%) of the sum of 16 metals in the dust. The concentrations of OPFRs in Shanghai dust ranged from 5.34 to 13.7 µg/g (median: 7.21 µg/g), compared to household dust from Stockholm that ranged from 16.0 to 28.3 µg/g (median: 26.6 µg/g). Tris(2-chloroisopropyl) phosphate (TCIPP) and tris(2-chloroethyl) phosphate (TCEP) dominated in Shanghai dust samples while tris(2-butoxyethyl) phosphate (TBOEP) dominated in dust from Stockholm homes. Conclusion The results showed that mass percentage for each particle size fraction was not evenly distributed. Furthermore, the particle-bound microorganisms and OPFRs increased with decreased particle size, whereas metals had the highest concentrations at specific dust sizes. Therefore, it is essential to select the proper particle size in order to assess any specific human exposure study to indoor pollutants.


Author(s):  
Rui-Xin Qin ◽  
Bin Tang ◽  
Xi Zhuang ◽  
Wei-Xiang Lei ◽  
Mei-Huan Wang ◽  
...  

Indoor dust ingestion is one of the main pathways for human exposure to organophosphate flame retardants (PFRs). The urinary concentrations of diesters (DAPs) are usually used as biomarkers to assess...


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