Key Stages of the Formation of AlPO4-11 via Crystallization of Aluminophosphate Gel Prepared with Boehmite

2018 ◽  
Vol 18 (6) ◽  
pp. 6-13
Author(s):  
M. R. Agliullin ◽  
Z. R. Khairullina ◽  
A. V. Faizullin ◽  
A. I. Petrov ◽  
A. A. Badretdinova ◽  
...  

The one-dimensional channel pore system and the moderately strong acid centers inherent in aluminophosphate (AlPO4-11) and silicoaluminophosphate (SAPO-11) molecular sieves make them promising catalyst for hydroisomerization of higher n-paraffins. However, the mechanism of crystallization of these materials is not well understood as yet. XRD,27Al and31P MAS NMR, lowtemperature adsorption-desorption of nitrogen, and SEM techniques were used for the first time for studying the stage crystallization of aluminophosphate AlPO4-11 for commercial boehmite based aluminium source. AlPO4-11 was shown to form via an intermediate phase based on layered crystalline aluminophosphate. It was established that highly crystalline and phase-pure AlPO4-11 was formed at 200 °C during 6 to 24 hours. When the crystallization at 200 °C lasted for more than two days, AlPO4-11 turned into non-porous cristobalite. The results obtained will be used for developing methods for deliberate control of the phase composition and crystallinity of industrially important silicoaluminophosphate sieves SAPO-11 with required properties to develop promising catalysts based thereon for large-scale processes of hydroisomerization of n-paraffins.

2011 ◽  
Author(s):  
Βασίλειος Μαρδύρης

In last decades exponential reduction of integrated circuits feature size and increase in operating frequency was achieved in VLSI fabrication industry using the conventional CMOS technology. However the CMOS technology faces serious challenges as the CMOS transistor reaches its physical limits, such as ultra thin gate oxides, short channel effects, doping fluctuations and increased difficulty and consequently increased lithography cost in the nanometer scale. It is projected that the CMOS technology, in its present state will reach its limits when the transistors channel length reaches approximatly 7 nm, probably near 2019. Emerging technologies have been a topic of great interest in the last few years. The emerging technologies in nanoelectronics provide new computing possibilities that arise from their extremely reduced feature sizes. Quantum Cellular Automata (QCA) is one of the most promising emerging technologies in the fast growing area of nanoelectronics. QCA relies mostly on Coulombic interactions and uses innovative processing techniques which are very different from the CMOS-based model. QCAs are not only a new nanoelectronic model but also provide a new method of computation and information process. In QCA circuits computation and data transfer occurs simultaneously. Appling the QCA technology, the elementary building component (QCA cells) cover an area of a few nanometers. For this feature sizes the integration can reach values of 1012 cells/cm2 and the circuit switching frequency the THz level. The implementation of digital logic using QCA nanoelectronic circuits not only drives the already developed systems based on conventional technology to the nanoelectronic era but improves their performance significantly. At the present Ph.D. thesis, a study of QCA circuit clocking schemes is presented showing how these schemes contribute to the robustness of QCA circuits. A novel design of a QCA 2 to 1 multiplexer is presented. The QCA circuit is simulated and its operation is analyzed. A modular design and simulation methodology is developed for the first time. This methodology can be used to design 2n to 1 QCA multiplexers using the 2 to 1 QCA multiplexer as a building block. The design methodology is formulated in order to increase the circuit stability.Furthermore in this Ph.D. thesis, a novel design of a small size, modular quantum-dot cellular automata (QCA) 2n to 1 multiplexer is proposed, These multiplexers can be used for memory addressing. The design objective is to develop an evolving modular design methodology which can produce QCA 2n to 1 multiplexer circuits, improved in terms of circuit area and operating frequency. In these implementations the circuit stability was a major issue and was considered carefully. In the recent years, Cellular Automata (CAs) have been widely used in order to model and simulate physical systems and also to solve scientific problems. CAs have also been successfully used as a VLSI architecture and proved to be very efficient in terms of silicon-area utilization and clock-speed maximization. In the present Ph.D. thesis a design methodology is developed for the first time, which can be used to design CA models using QCA circuitry. The implementation of CAs using QCA nanoelectronic circuits significantly improves their performance due to the unique properties of the nanoelectronic circuits. In this Ph.D. thesis a new CAD system we develope for the first time, and was named Design Automation Tool of 1-D Cellular Automata using Quantum Cellular Automata (DATICAQ), that builds a bridge between one-dimensional CAs as models of physical systems and processes and one-dimensional CAs as a nanoelectronic architecture. The CAD system inputs are the CA dimensionality, size, local rule, and the initial and boundary conditions imposed by the particular problem. DATICAQ produces as output the layout of the QCA implementation of the particular one-dimensional CA model. The proposed system also provides the simulation input vectors and their corresponding outputs, in order to simplify the simulation process. No prior knowledge of QCA circuit designing is required by the user. DATICAQ has been tested for a large number of QCA circuits. Paradigms of QCA circuits implementing CA models for zero and periodic boundary conditions are presented in the thesis. Simulations of CA models and the corresponding QCA circuits showed that the CA rules and models have been successfully implemented. At the present Ph.D. thesis, the design of large scale QCA circuits is analyzed and a study of the problems arising on complex algorithm implementation using QCAs is presented. One of the most important problems of the large scale QCA circuits is the synchronization of the internal signals of the circuit between the subsystems of the large QCA circuit. This problem becomes more difficult when the circuit includes signal loops. In the present thesis a methodology and a QCA circuit is presented for the first time, which solves the above mentioned synchronization problem. The QCA circuit implements the Firing Squad Synchronization Algorithm proposed by Mazoyer in order to solve the synchronization problem. The implementation was obtained using a one-dimensional 3-bit digital CA model. The QCA circuit is simulated and its operation is analyzed.


2021 ◽  
Vol 24 (24) ◽  
pp. 37-53
Author(s):  
Lysychka Oleksandr

Statement of the problem. The relevance of the article lies in revealing the peculiarities of the composer’s way of appeal to the national cultural heritage. The aim of the study is to determine the principles of embodiment of “the nationally English” in the symphonic etude “Falstaff” by Edward Elgar. The main method of the research is drawing parallels, on the one hand, and between the embodiment of the English national character through the image of Falstaff in musical and dramatic works, on the other. Research results. A conclusion is made that the main factor creating strong ties between the “symphonic etude” and the national tradition is spectacular national characterisation. Moreover, for the sake of applying the “English” the composer consciously and significantly changes his musical language. The author turns to very detailed programme (unlike general type of programness in most of his works), and that allows him to scrupulously depict the plot of Shakespeare’s chronicle on which he focuses on. Elgar also portrays overtly humoristic situations, for the first time in his symphonic works, because it would be impossible to disregard this side of Falstaff’s character, as it is the contrast of comical in the beginning and solemn in the denouement that create the tragic effect. The structural side of the composition is also unprecedented as it is formally has one movement, but the composer himself divides it in four parts (ignoring the arrangement of events in “Henry IV” in two parts) while all the parts are connected in various ways. As a result of this, “Falstaff” becomes the longest single-movement symphonic composition of Elgar. The composer favours linear type of musical thinking, integrating it with sudden “flashes” of thematically significant elements in different strata of the texture, and this all combined provides completely lush, unpredictable sonority of the orchestra. On the top of this, the author extensively uses themes with obvious genre genesis, especially in order to depict Shallow’s Gardens, although it is possible to find more traditional for Elgar passages with generalised type of intonation. Such characteristic for Elgar principles, as multi-thematism and elusion of the tonal centralisation (while using quite traditional chords in every given moment) find their new meaning regarding illustrative role of the music. A conclusion is made that the “Britishness” of the symphonic etude lies not in the use of folk intonations or allusions to the past of professional music, but in meticulous attention to W. Shakespeare’s text: both on levels of portraying or interaction between the “characters” and form-creating according to the scenes. Despite the fact that E. Elgar’s musical language seems to be quite distant from Falstaff’s comical essence, the composer was able to find means adequate to the character’s image, such as “wandering” tonal structure; superficial, but rather important analogy between quite large scale of a single-movement work and Falstaff’s body image; narrative orchestration.


Author(s):  
M. V. C. Alves ◽  
J. R. Barbosa ◽  
P. J. Waltrich ◽  
G. Falcone

A mathematical model is presented to describe the behavior of transient gas-liquid flows involving the churn and annular flow patterns in a long vertical tube. The HyTAF (Hyperbolic Transient Annular Flow) code, developed specifically for this study, is based on the one-dimensional multi-fluid formulation and takes account of hydrodynamic non-equilibrium flow conditions by means of relationships for the rates of droplet entrainment and deposition. A finite difference algorithm is employed to solve the hyperbolic system of mass, momentum and energy equations via the Split Coefficient Matrix Method. The modeling results are compared with experimental data for steady-state annular and churn flows obtained from the literature and with pressure and flow rate induced transient churn-annular flow data generated in a large scale facility (48-mm ID, 42-m long test section).


2018 ◽  
Vol 20 ◽  
pp. 02003
Author(s):  
Chu Duc Khanh ◽  
Nguyen Hoang Luc ◽  
Van Phan ◽  
Nguyen Huy Tuan

In this paper, we study for the first time the inverse initial problem for the one-dimensional strongly damped wave with Gaussian white noise data. Under some a priori assumptions on the true solution, we propose the Fourier truncation method for stabilizing the ill-posed problem. Error estimates are given in both the L2– and Hp–norms.


2019 ◽  
Vol 19 (3) ◽  
pp. 437-473 ◽  
Author(s):  
Julian López-Gómez ◽  
Pierpaolo Omari

Abstract This paper investigates the topological structure of the set of the positive solutions of the one-dimensional quasilinear indefinite Neumann problem \begin{dcases}-\Bigg{(}\frac{u^{\prime}}{\sqrt{1+{u^{\prime}}^{2}}}\Bigg{)}^{% \prime}=\lambda a(x)f(u)\quad\text{in }(0,1),\\ u^{\prime}(0)=0,\quad u^{\prime}(1)=0,\end{dcases} where {\lambda\in\mathbb{R}} is a parameter, {a\in L^{\infty}(0,1)} changes sign, and {f\in C^{1}(\mathbb{R})} is positive in {(0,+\infty)} . The attention is focused on the case {f(0)=0} and {f^{\prime}(0)=1} , where we can prove, likely for the first time in the literature, a bifurcation result for this problem in the space of bounded variation functions. Namely, the existence of global connected components of the set of the positive solutions, emanating from the line of the trivial solutions at the two principal eigenvalues of the linearized problem around 0, is established. The solutions in these components are regular, as long as they are small, while they may develop jump singularities at the nodes of the weight function a, as they become larger, thus showing the possible coexistence along the same component of regular and singular solutions.


1998 ◽  
Vol 12 (18) ◽  
pp. 1847-1870 ◽  
Author(s):  
C. Micu ◽  
E. Papp

Proofs are given for the first time that the energy-spectrum of the Harper-equation can be derived in a closed implicit form by using the one-dimensional limit of the 1/N-description. Explicitly solvable cases are discussed in some more detail for Δ=1. Here Δ expresses the Harper-parameter discriminating between metallic (Δ<1) and insulator (Δ>1) phases. Related magnetizations have been established by applying both Dingle- and quantum-gas approaches, now for a fixed value of the Fermi-level. The first description leads to large paramagnetic-like magnetizations oscillating with nearly field-independent amplitudes increasing with the temperature. In the second case one deals with magnetization-oscillations centered around the zero-value, such that the amplitudes decrease both with the field and the temperature.


1970 ◽  
Vol 43 (4) ◽  
pp. 737-751 ◽  
Author(s):  
H. Ardavan-Rhad

An analytic solution of the non-isentropic equations of gas-dynamics, for the one-dimensional motion of a non-viscous and non-conductive medium, is derived in this paper for the first time. This is a particular solution which contains only one arbitrary function. On the basis of this solution, the interaction of a centred simple wave with a shock of moderate strength is analyzed; and it is shown that, for a weak shock, this analysis is compatible with Friedrichs's theory. Furthermore, in the light of this analysis, it is explained why the empirical methods employed by the shock-expansion theory, including Whitham's rule for determining the shock path, work.


2008 ◽  
Vol 18 (08) ◽  
pp. 1259-1282 ◽  
Author(s):  
MEIRAV AMRAM ◽  
MINA TEICHER ◽  
UZI VISHNE

This is the final paper in a series of four, concerning the surface 𝕋 × 𝕋 embedded in ℂℙ8, where 𝕋 is the one-dimensional torus. In this paper we compute the fundamental group of the Galois cover of the surface with respect to a generic projection onto ℂℙ2, and show that it is nilpotent of class 3. This is the first time such a group is presented as the fundamental group of a Galois cover of a surface.


2018 ◽  
Vol 46 (2018) ◽  
pp. 69-82
Author(s):  
Gregory H. Nail ◽  
Raymond J. Kopsky

Abstract The one-dimensional HEC-RAS multi-purpose open channel flow modeling software was successfully used, with ArcMap and HEC-GeoRAS, to simulate flow over the Wappapello Dam limited-use Ogee spillway (Wappapello, Missouri). Initial computational hydraulic modeling results predicted a lake elevation of 132.9 m (405.0 ft) [NAVD 1988] would be required for the resulting floodwaters overtopping the spillway to reach the nearby Wappapello Lake Management Office. An intense rainfall event during 2011 led to the spillway being overtopped for the first time since 1945. Spillway performance during the 2011 event was analyzed afterwards. Results indicated that the spillway crest was not submerged by backwater. A technique was employed which successfully estimated the design energy head of 7.160 m (23.49 ft) for the spillway. Hydraulic modeling developed after the 2011 event incorporated this estimated design energy head, allowing the spillway discharge coefficient to vary with discharge in the course of an unsteady modeling run. Results indicated that, while the spillway did perform as designed, the performance is limited by the shallow approach depth.


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