scholarly journals Should A Good Organic Solar Cell Be A Good Organic LED?

Author(s):  
Gregory Kozyreff ◽  
Blaise Godefroid

We revisit the argument that link the efficiency of a solar cell to its reverse operation as a LED, in the case where the material is organic. In organic cells, exciton transport is an intermediate process between sunlight absorption and the generation of electric current. We show that quenching exciton radiation can be beneficial to cell efficiency, without contradicting the general rule prevailing for semiconductor cells. Our treatment allows us to discuss both bulk heterojunction and planar junctions.

2017 ◽  
Vol 2017 ◽  
pp. 1-10 ◽  
Author(s):  
A. J. Trindade ◽  
L. Pereira

Organic solar cell efficiency is known to be active area dependent and is usually a problem in the upscale factor for market applications. In this work, a detailed study of organic photovoltaic devices with active layer based on poly(3-hexylthiophene) (P3HT) and 1-(3-methoxycarbonyl)-propyl-1-phenyl-(6,6)C61 (PCBM) is made, evaluating the effect of the change on the active area from 10−2 to 4 cm4. The device structure was kept simple in order to allow the understanding of the physical effects involved. Device figures of merit were extracted from the equivalent circuit using a genetic-based algorithm, and their relationship with the active area was compared. It is observed that the efficiency drops significantly with the active area increase (as the fill factor) while the parallel and series resistance, adjusted to the active area, seems to be relatively constant and increases linearly, respectively. The short circuit current and the generated photocurrent also drop significantly with the active area increase. The open circuit voltage does not show major changes. These results are discussed considering the main influences for the observed efficiency data. Particularly, as the basic circuit model seems to fail to explain the macroscopic results, the behavior can be related with the enlargement of defect interaction.


2021 ◽  
Vol 543 ◽  
pp. 148863
Author(s):  
Dhanasekaran Vikraman ◽  
Hailiang Liu ◽  
Sajjad Hussain ◽  
K. Karuppasamy ◽  
Hae-Kyung Youi ◽  
...  

2013 ◽  
Vol 5 (16) ◽  
pp. 8225-8230 ◽  
Author(s):  
John R. Tumbleston ◽  
Abay Gadisa ◽  
Yingchi Liu ◽  
Brian A. Collins ◽  
Edward T. Samulski ◽  
...  

2011 ◽  
Vol 209 (2) ◽  
pp. 369-372 ◽  
Author(s):  
Fu-Ching Tang ◽  
Jay Chang ◽  
Wei-Yang Chou ◽  
Horng-Long Cheng ◽  
Steve Lien-Chung Hsu ◽  
...  

Author(s):  
Zahra Samavati ◽  
Alireza Samavati ◽  
Ahmad Fauzi Ismail ◽  
Tohid N. Borhani ◽  
Mohammad Velashjerdi ◽  
...  

2013 ◽  
Vol 1500 ◽  
Author(s):  
Rebecca Isseroff ◽  
Andrew Chen ◽  
Sneha Chittabathini ◽  
Alexandra Tse ◽  
Cheng Pan ◽  
...  

ABSTRACTRelatively low efficiency is one of the main obstacles to overcome in the engineering of organic bulk heterojunction (BHJ) solar cells. Reduced graphene oxide (RGO), which has high conductivity, has been proposed to enhance the function of PCBM in the interfacial dissociation of excitons, but incorporating it into the hydrophobic photoactive polymers has proved challenging. Here we describe a novel technique for incorporating Au nanoparticles (AuNp) into the structure of the RGO. The AuNps then interact with the sulfur groups on the photoactive polymer component, while the RGO interacts via π – π stacking with the chemically similar PCBM, thereby anchoring the complex to the polymer interface. Graphene oxide was synthesized and then reduced in the presence of a gold salt. The resulting gold-functionalized RGO (AuRGO) sheets were characterized using TGA, FTIR, and TEM. The AuRGO was not soluble in chlorobenzene; however, in the presence of P3HT, the AuRGO dissolved, suggesting a reaction between the gold and the sulfur of the P3HT via a metal-thiolate bond. At 2 mg/ml, AuRGO increased the solar cell efficiency approximately 50% over the control, but higher concentrations produced large, columnar structures which blocked the electrode from having a uniform contact with the active layer.


2017 ◽  
Vol 161 ◽  
pp. 102-148 ◽  
Author(s):  
Ramasamy Ganesamoorthy ◽  
Govindasamy Sathiyan ◽  
Pachagounder Sakthivel

Nano Energy ◽  
2020 ◽  
Vol 68 ◽  
pp. 104327 ◽  
Author(s):  
Tanya Kumari ◽  
Sungwoo Jung ◽  
Yongjoon Cho ◽  
Hwang-Pill Kim ◽  
Jae Won Lee ◽  
...  

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