scholarly journals Electrochemical and Quantum Chemical Assessment of Some Thiosemicarbazide Derivatives as Carbon Steel Corrosion Inhibitors in HCl; Continuously Monitoring the Current Change by FFT Voltammetry

Author(s):  
Shirin Shahabi ◽  
RSC Advances ◽  
2016 ◽  
Vol 6 (19) ◽  
pp. 15639-15654 ◽  
Author(s):  
Chandrabhan Verma ◽  
L. O. Olasunkanmi ◽  
I. B. Obot ◽  
Eno E. Ebenso ◽  
M. A. Quraishi

The inhibition of mild steel corrosion in 1 M HCl by four 5-arylpyrimido-[4,5-b]-quinoline-diones has been investigated using weight loss, electrochemical, surface, and quantum chemical calculations and molecular dynamics simulation methods.


1991 ◽  
Vol 247 (2-3) ◽  
pp. 352-359 ◽  
Author(s):  
Jiann-Ruey Chen ◽  
Huei-Yun Chao ◽  
Yuh-Lin Lin ◽  
Iua-Jou Yang ◽  
Jung-Chou Oung ◽  
...  

Al-Kimia ◽  
2020 ◽  
Vol 8 (1) ◽  
Author(s):  
Yayan - Sunarya ◽  
Heli Siti H ◽  
Munawaroh Munawaroh ◽  
Gun Gun Gumilar

Corrosion control on petroleum pipe wells can only be done through the addition of corrosion inhibitors. In this study, the corrosion inhibitors studied were sourced from marine microorganisms, namely the type of microalgae Tetraselmis chuii sp. The aim to be achieved in this study was to determine the mechanism and efficiency of inhibition of the extraction of microalgae biomass in corrosion of carbon steel in an environment of petroleum conditions. To achieve this goal, a potentiodynamic polarization method (Tafel extrapolation) was used and the Electrochemistry Impedance Spectroscopy (EIS) method used the galvanostat-potentiostat device (Voltalab 40, PGZ 301). The results obtained from this study indicate that API 5L X65 carbon steel in the petroleum environment is very significantly corroded, caused by acidic media derived from acetic acid and dissolved CO2. The inhibition ability of the Tetraselmis chuii sp. Biomass extract. in line with the increasing extraction concentration reaching optimum at a concentration of 250 ppm with inhibition efficiency reaching 70%. The mechanism of inhibition takes place through the formation of a protective layer adsorbed on the surface of carbon steel. The protective membrane formed is uneven and tends to be porous.


2019 ◽  
Vol 26 (10) ◽  
pp. 1950066 ◽  
Author(s):  
VENKATESAN HEMAPRIYA ◽  
ILL-MIN CHUNG ◽  
KANDASAMY PARAMESWARI ◽  
SUBRAMANIAN CHITRA ◽  
SEUNG-HYUN KIM ◽  
...  

The inhibitive performance of 2-[(5-phenyl-1,3,4-oxdiazol-2-yl)methyl]-2H-benzo[b] [1,4] thiazin-3-one (POBT) for low carbon steel corrosion in 1 M H2SO4 has been evaluated by non-electrochrmical, and electrochemical measurements. Efficiency of the inhibitor enhanced with inhibitor concentration and declined with rise in temperature. 92.39% inhibition efficiency was attained using 0.1[Formula: see text]mM of POBT. Anticorrosive effect of the inhibitor is owing to the adsorption of POBT molecules on the metal surface. Mono layer adsorption of inhibitor was favored by observing the best fit with Langmuir isotherm. Polarization measurements reveal that the inhibitor behaves as mixed type. Surface analysis by scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDX) confirm the existence of a protective film of POBT on low carbon steel surface. Quantum chemical parameters obtained using density functional theory (DFT) method complements the above results.


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