Evaluation of Pore Size Distribution Effects on Phase Behavior of Hydrocarbons Produced in Shale Gas Condensate Reservoirs

Author(s):  
Baoyan Li ◽  
Alberto Mezzatesta
Energies ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1315
Author(s):  
Jingwei Huang ◽  
Hongsheng Wang

Confined phase behavior plays a critical role in predicting production from shale reservoirs. In this work, a pseudo-potential lattice Boltzmann method is applied to directly model the phase equilibrium of fluids in nanopores. First, vapor-liquid equilibrium is simulated by capturing the sudden jump on simulated adsorption isotherms in a capillary tube. In addition, effect of pore size distribution on phase equilibrium is evaluated by using a bundle of capillary tubes of various sizes. Simulated coexistence curves indicate that an effective pore size can be used to account for the effects of pore size distribution on confined phase behavior. With simulated coexistence curves from pore-scale simulation, a modified equation of state is built and applied to model the thermodynamic phase diagram of shale oil. Shifted critical properties and suppressed bubble points are observed when effects of confinement is considered. The compositional simulation shows that both predicted oil and gas production will be higher if the modified equation of state is implemented. Results are compared with those using methods of capillary pressure and critical shift.


Energies ◽  
2020 ◽  
Vol 13 (20) ◽  
pp. 5427
Author(s):  
Boning Zhang ◽  
Baochao Shan ◽  
Yulong Zhao ◽  
Liehui Zhang

An accurate understanding of formation and gas properties is crucial to the efficient development of shale gas resources. As one kind of unconventional energy, shale gas shows significant differences from conventional energy ones in terms of gas accumulation processes, pore structure characteristics, gas storage forms, physical parameters, and reservoir production modes. Traditional experimental techniques could not satisfy the need to capture the microscopic characteristics of pores and throats in shale plays. In this review, the uniqueness of shale gas reservoirs is elaborated from the perspective of: (1) geological and pore structural characteristics, (2) adsorption/desorption laws, and (3) differences in properties between the adsorbed gas and free gas. As to the first aspect, the mineral composition and organic geochemical characteristics of shale samples from the Longmaxi Formation, Sichuan Basin, China were measured and analyzed based on the experimental results. Principles of different methods to test pore size distribution in shale formations are introduced, after which the results of pore size distribution of samples from the Longmaxi shale are given. Based on the geological understanding of shale formations, three different types of shale gas and respective modeling methods are reviewed. Afterwards, the conventional adsorption models, Gibbs excess adsorption behaviors, and supercritical adsorption characteristics, as well as their applicability to engineering problems, are introduced. Finally, six methods of calculating virtual saturated vapor pressure, seven methods of giving adsorbed gas density, and 12 methods of calculating gas viscosity in different pressure and temperature conditions are collected and compared, with the recommended methods given after a comparison.


SPE Journal ◽  
2021 ◽  
pp. 1-13
Author(s):  
Sheng Luo ◽  
Fangxuan Chen ◽  
Dengen Zhou ◽  
Hadi Nasrabadi

Summary In shale gas-condensate reservoirs, when the initial reservoir pressure is greater than the dewpoint pressure, the condensate/gas ratio (CGR) has been observed to decrease continuously as the pressure drops to less than the initial reservoir pressure. This abnormal behavior cannot be explained with conventional pressure/volume/temperature (PVT) models that ignore the presence of nanopores in shale rock. Herein, for the first time, we present a study that provides a physical explanation for the observed CGR trends by including the effect of nanopores on the fluid phase behavior and depletion of shale gas-condensate reservoirs. Our model uses multiscale PVT simulation by means of a pore-size-dependent equation of state (EOS). Two lean gas-condensate cases (shallow and deep reservoirs) are investigated. The simulation results show that hydrocarbons distribute heterogeneously with respect to pore size on the nanoscale. There are more intermediate to heavy hydrocarbons (C3–11+) but fewer light ends (C1–2) distributed in the nanopores than in the bulk region. At the end of depletion, because of confinement effects, large amounts of intermediate hydrocarbons are trapped in the nanopores, causing condensate recovery loss. Multiscale depletion simulations suggest that a decreasing CGR can occur at the beginning of production when the reservoir pressure is higher than the dewpoint pressure. Such behavior is caused by the nanopore depletion in the shale matrix, which is a process of selectively releasing light hydrocarbon components. We also present a novel approach to model the nonequilibrium fluid distribution between the fracture and nanopores using a simple local-equilibrium concept. Our results indicate that the nonequilibrium fluid distribution increases the CGR drop because of the compositional selectivity of the nanopore in favor of intermediate and heavy hydrocarbons.


2015 ◽  
Vol 26 ◽  
pp. 883-894 ◽  
Author(s):  
Botao Lin ◽  
Mian Chen ◽  
Yan Jin ◽  
Huiwen Pang

2019 ◽  
Vol 33 (2) ◽  
pp. 700-707
Author(s):  
Wei Tian ◽  
Xingru Wu ◽  
Dehua Liu ◽  
Amanda Knaup ◽  
Changlong Chen ◽  
...  

2016 ◽  
Vol 1 (3) ◽  
pp. 213-220 ◽  
Author(s):  
Yu Zhang ◽  
Deyong Shao ◽  
Jianping Yan ◽  
Xiangjuan Jia ◽  
Yanfang Li ◽  
...  

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