Next Generation Oilfield on-Site Trace Chemicals Analysis by SERS

2021 ◽  
Author(s):  
Zhengwei Liu ◽  
Sankaran Murugesan ◽  
Sunder Ramachandran ◽  
Peng Jin
Keyword(s):  
Oil And Gas ◽  
Production Systems ◽  
Analytical Techniques ◽  
Chemical Additives ◽  
Factors Affecting ◽  
Oil And Gas Operations ◽  
Active Nature ◽  
Laboratory Procedures ◽  
Trace Chemicals ◽  
And Performance

Abstract Accurate and precise monitoring of chemical additives in oilfield brine is an important aspect of oil and gas operations towards corrosion control and flow assurance. Many operators are required to monitor the residual concentrations of chemical additives in production systems at specific locations to monitor and troubleshoot factors affecting chemical deliverability and performance. However, residual measurements are extremely problematic due to many factors, including the surface active nature of the chemicals and high ionic strength of the brine. The error on residual measurements can often be over 100%. Residual measurement typically requires the collection of a water sample, which often needs to be transported to a centralized analytical laboratory. Analytical techniques used to measure residuals are based on several combinations of separation (e.g. chromatography, liquid-liquid extraction, etc.) and detection (e.g. various forms of spectroscopy). However, most of these methods lack portability and require tedious laboratory procedures located off-site. The current paper describes a nanotechnology-enabled Raman spectroscopy method developed and tested for monitoring chemical inhibitor residuals. Development of this technology with handheld instrumentation provides better detection and quantification of chemical additives in the field and reduces time and cost compared to sending samples to off-site laboratories for data collection.

Prevent Failures and Extend Asset Life: A Reliable Onsite Corrosion Inhibitor Residuals Method Using SERS

2021 ◽  
Author(s):  
Peng Jin ◽  
Sankaran Murugesan ◽  
Zhengwei Liu ◽  
Haitao Fang ◽  
Shujun Gao ◽  
...  
Keyword(s):  
Corrosion Inhibitor ◽  
Asset Management ◽  
Oil And Gas ◽  
Solution Concentration ◽  
Chemical Information ◽  
Dye Transfer ◽  
Sample Container ◽  
Factors Affecting ◽  
Oilfield Brines ◽  
And Performance

Abstract Asset integrity for oil and gas operations requires reliable chemical information to troubleshoot factors affecting chemical deliverability and performance. Accurate and precise measurement of corrosion inhibitor (CI) concentration in oilfield brine is significant to asset management. However, historically CI residual measurements are extremely problematic due to the surface-active nature of the chemicals which interact with a host of factors that parasitically deplete the CI solution concentration. It is typical to see >100% error on traditional residual measurements especially where dye transfer techniques are concerned. Current methods and sample handling for measuring residuals involves sending samples to a local laboratory for analysis. This time delay can add to the measurement error due to loss of inhibitor species to the sample container or solids that may form in transport. This paper describes the use of a simple, portable, handheld, onsite, nanotechnology-based, residual method to measure CI concentrations in oilfield brines. With more frequent and highly accurate CI residual feedback operators can react to system conditions that threaten to impact asset integrity. Using the CI residual data provided by a rapid, accurate analytical method, operators could extend asset life and prevent failures long before they become critical.

scholarly journals A Critical Review of Analytical Methods for Comprehensive Characterization of Produced Water

Water ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 183
Author(s):  
Wenbin Jiang ◽  
Lu Lin ◽  
Xuesong Xu ◽  
Xiaoxiao Cheng ◽  
Yanyan Zhang ◽  
...  
Keyword(s):  
Analytical Methods ◽  
Management Practices ◽  
Oil And Gas ◽  
Produced Water ◽  
Treatment Effectiveness ◽  
Analytical Techniques ◽  
Gas Production ◽  
Chemical Additives ◽  
Water Composition

Produced water is the largest waste stream associated with oil and gas production. It has a complex matrix composed of native constituents from geologic formation, chemical additives from fracturing fluids, and ubiquitous bacteria. Characterization of produced water is critical to monitor field operation, control processes, evaluate appropriate management practices and treatment effectiveness, and assess potential risks to public health and environment during the use of treated water. There is a limited understanding of produced water composition due to the inherent complexity and lack of reliable and standardized analytical methods. A comprehensive description of current analytical techniques for produced water characterization, including both standard and research methods, is discussed in this review. Multi-tiered analytical procedures are proposed, including field sampling; sample preservation; pretreatment techniques; basic water quality measurements; organic, inorganic, and radioactive materials analysis; and biological characterization. The challenges, knowledge gaps, and research needs for developing advanced analytical methods for produced water characterization, including target and nontarget analyses of unknown chemicals, are discussed.

Application of a Novel Analytical Technique to Monitor Corrosion Inhibitor Residual in Oilfield Samples

2021 ◽  
Author(s):  
Peng Jin ◽  
Zhengwei Liu ◽  
Jagrut Jani ◽  
Sankaran Murugesan ◽  
Tracey Jackson ◽  
...  
Keyword(s):  
Corrosion Inhibitor ◽  
Oil And Gas ◽  
Analytical Techniques ◽  
Accurate Analysis ◽  
Residual Concentration ◽  
Analytical Technique ◽  
Field Samples ◽  
Key Factor ◽  
Oil And Gas Operations ◽  
Integrity Management

Abstract Accurate and in-time monitoring of corrosion inhibitor (CI) residual concentration is a key factor in asset integrity management for oil and gas operations. However, the natural variability of CI residual due to field conditions is usually convoluted with the error introduced by sampling and analytical techniques. In traditional analytical techniques, it is typical to encounter error of over 100%. Recently, a novel nanoscale technique (TrueDetect™, TD) was developed to accurately measure CI in the field. This technique is based on a proprietary spectrometry technique and allows quick and accurate analysis of CI residual at the ppm level. The portable instrument allows field samples to be analyzed on-site without the need for shipping them to a centralized laboratory. In the current study, the TD technique was applied to analyze field samples from various fields. Moreover, the TD technique was capable of analyzing CIs at low dosages and could be used as a method to qualify CI products in the lab and in the field.

Overcoming Lost Circulation Risks in Low Fracture Gradient Formations with a New Tailored Spacer System

2021 ◽  
Author(s):  
Kory Hugentobler ◽  
Joseph M. Shine ◽  
Alejandro De La Cruz Sasso ◽  
Abdulmalek Shamsan ◽  
Sandip Patil ◽  
...  
Keyword(s):  
Oil And Gas ◽  
Performance Testing ◽  
Lost Circulation ◽  
Oil And Gas Operations ◽  
Primary Cementing ◽  
Isolation Requirements ◽  
And Performance ◽  
Wellbore Strengthening ◽  
Placement Success ◽  
Fracture Gradient

Abstract In certain regions of oil and gas operations, lost circulation is a common occurrence, especially when a majority of the openhole exposed during primary cementing is carbonate-based formations. This can lead to lost circulation risks in most applications. To overcome lost circulation risks during primary cementing, a new tailored spacer system shows to improve the cement placement success. The manuscript discusses the quality assurance and performance testing with field cases demonstrating the value contributions of the spacer for achieving zonal isolation requirements as well as the top of cement objectives. The work efforts presented shows a spacer meeting and sometimes showing incremental wellbore strengthening in comparison to the published literature for existing available spacers used to overcome similar lost circulation risks.

Hygienic assessment of learning environment conditions (by the example of higher educational institutions of the city of Ufa)

2020 ◽  
Vol 99 (4) ◽  
pp. 405-411
Author(s):  
Elena Ju. Gorbatkova
Keyword(s):  
Ionizing Radiation ◽  
Educational Institutions ◽  
Higher Educational Institutions ◽  
Factors Affecting ◽  
Republic Of Bashkortostan ◽  
Average Relative Humidity ◽  
Higher Educational ◽  
The Republic ◽  
And Performance ◽  
The City

Introduction. The important factors affecting health and performance of young people are the conditions of education, in particular, a comfortable microclimate in the classrooms of higher educational institutions. Materials and methods. In view of the urgency of this problem, an analysis was made of the microclimate parameters of educational organizations of different profiles (Ufa city, the Republic of Bashkortostan). 294 classrooms were studied in 22 buildings of 4 leading universities in Ufa. A total of 3,822 measurements were taken to determine the parameters of the microclimate. The analysis of ionizing radiation in the aerial environment of classrooms. There was performed determination of radon and its affiliated products content. In order to assess the conditions and lifestyle of students of 4 higher educational institutions of the city of Ufa, we conducted an anonymous survey of 1,820 students of I and IV years of education. Results. The average temperature in the classrooms of all universities studied was 23.9±0.09 C. The average relative humidity in all classrooms was 34.2 ± 0.42%. Analysis of ionizing radiation (radon and its daughter products decay) in the aerial environment of the classrooms and sports halls located in the basement determined that the average annual equivalent equilibrium volumetric activity of the radon daughter products (EROA ± Δ222Rn) ranged from 28 ± 14 to 69 ± 34.5 meter, which meets the requirements established by SanPiN. Conclusion. The hygienic assessment of the microclimate parameters of educational institutions of various profile revealed a number of deviations from the regulated norms. The results indicate the need to control the parameters of the microclimate, both from the administration of universities, and from the professors. According to the results of the study, recommendations were prepared for the management of higher educational institutions in Ufa.

Drilling and Service Contracts in Offshore Oil and Gas Operations

1973 ◽  
Vol 11 (3) ◽  
pp. 480
Author(s):  
J. M. Killey
Keyword(s):  
Oil And Gas ◽  
Oil Industry ◽  
Offshore Drilling ◽  
Oil Companies ◽  
Drilling Rig ◽  
Service Contracts ◽  
Oil And Gas Operations ◽  
Offshore Oil And Gas ◽  
Offshore Oil ◽  
Offshore Operations

As onshore oil and gas deposits are becoming more difficult to locate, and as the world demands for energy continue to increase at an alarming rate, oil companies are channeling much of their exploration activities towards offshore operations, and in particular, towards operations centered off Canada's coast lines. Because of the environment, offshore drilling presents problems which are novel to the onshore-geared oil industry. J. M. Killey discusses in detail many of the considerations involved in drafting the offshore drilling contract, concentrating on problems such as the liability of the various parties; costs; scheduling; pollution; conflict of laws; etc. Similarly, he discusses service contracts (such as supply boat charters; towing services; helicopter services; etc.^ which are necessity to the operation of an offshore drilling rig. To complement his paper, the author has included number of appendices which list the various considerations lawyer must keep in mind when drafting contracts for offshore operations.

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