Application of a Novel Analytical Technique to Monitor Corrosion Inhibitor Residual in Oilfield Samples

2021 ◽  
Author(s):  
Peng Jin ◽  
Zhengwei Liu ◽  
Jagrut Jani ◽  
Sankaran Murugesan ◽  
Tracey Jackson ◽  
...  
Keyword(s):  
Corrosion Inhibitor ◽  
Oil And Gas ◽  
Analytical Techniques ◽  
Accurate Analysis ◽  
Residual Concentration ◽  
Analytical Technique ◽  
Field Samples ◽  
Key Factor ◽  
Oil And Gas Operations ◽  
Integrity Management

Abstract Accurate and in-time monitoring of corrosion inhibitor (CI) residual concentration is a key factor in asset integrity management for oil and gas operations. However, the natural variability of CI residual due to field conditions is usually convoluted with the error introduced by sampling and analytical techniques. In traditional analytical techniques, it is typical to encounter error of over 100%. Recently, a novel nanoscale technique (TrueDetect™, TD) was developed to accurately measure CI in the field. This technique is based on a proprietary spectrometry technique and allows quick and accurate analysis of CI residual at the ppm level. The portable instrument allows field samples to be analyzed on-site without the need for shipping them to a centralized laboratory. In the current study, the TD technique was applied to analyze field samples from various fields. Moreover, the TD technique was capable of analyzing CIs at low dosages and could be used as a method to qualify CI products in the lab and in the field.

Next Generation Oilfield on-Site Trace Chemicals Analysis by SERS

2021 ◽  
Author(s):  
Zhengwei Liu ◽  
Sankaran Murugesan ◽  
Sunder Ramachandran ◽  
Peng Jin
Keyword(s):  
Oil And Gas ◽  
Production Systems ◽  
Analytical Techniques ◽  
Chemical Additives ◽  
Factors Affecting ◽  
Oil And Gas Operations ◽  
Active Nature ◽  
Laboratory Procedures ◽  
Trace Chemicals ◽  
And Performance

Abstract Accurate and precise monitoring of chemical additives in oilfield brine is an important aspect of oil and gas operations towards corrosion control and flow assurance. Many operators are required to monitor the residual concentrations of chemical additives in production systems at specific locations to monitor and troubleshoot factors affecting chemical deliverability and performance. However, residual measurements are extremely problematic due to many factors, including the surface active nature of the chemicals and high ionic strength of the brine. The error on residual measurements can often be over 100%. Residual measurement typically requires the collection of a water sample, which often needs to be transported to a centralized analytical laboratory. Analytical techniques used to measure residuals are based on several combinations of separation (e.g. chromatography, liquid-liquid extraction, etc.) and detection (e.g. various forms of spectroscopy). However, most of these methods lack portability and require tedious laboratory procedures located off-site. The current paper describes a nanotechnology-enabled Raman spectroscopy method developed and tested for monitoring chemical inhibitor residuals. Development of this technology with handheld instrumentation provides better detection and quantification of chemical additives in the field and reduces time and cost compared to sending samples to off-site laboratories for data collection.

Drilling and Service Contracts in Offshore Oil and Gas Operations

1973 ◽  
Vol 11 (3) ◽  
pp. 480
Author(s):  
J. M. Killey
Keyword(s):  
Oil And Gas ◽  
Oil Industry ◽  
Offshore Drilling ◽  
Oil Companies ◽  
Drilling Rig ◽  
Service Contracts ◽  
Oil And Gas Operations ◽  
Offshore Oil And Gas ◽  
Offshore Oil ◽  
Offshore Operations

As onshore oil and gas deposits are becoming more difficult to locate, and as the world demands for energy continue to increase at an alarming rate, oil companies are channeling much of their exploration activities towards offshore operations, and in particular, towards operations centered off Canada's coast lines. Because of the environment, offshore drilling presents problems which are novel to the onshore-geared oil industry. J. M. Killey discusses in detail many of the considerations involved in drafting the offshore drilling contract, concentrating on problems such as the liability of the various parties; costs; scheduling; pollution; conflict of laws; etc. Similarly, he discusses service contracts (such as supply boat charters; towing services; helicopter services; etc.^ which are necessity to the operation of an offshore drilling rig. To complement his paper, the author has included number of appendices which list the various considerations lawyer must keep in mind when drafting contracts for offshore operations.

Recent Developments in CE-MS Based Metabolomics

2020 ◽  
Vol 16 ◽  
Author(s):  
Mustafa Çelebier ◽  
Merve Nenni
Keyword(s):  
Sample Preparation ◽  
Scientific Information ◽  
Analytical Techniques ◽  
Living Organism ◽  
Analytical Technique ◽  
Ionic Compounds ◽  
Recent Sample ◽  
Recent Developments ◽  
Endogenous Metabolites ◽  
Preparation Techniques

Background: Metabolomics has gained importance in clinical applications over the last decade. Metabolomics studies are significant because the systemic metabolome is directly affected by disease conditions. Metabolome-based biomarkers are actively being developed for early diagnosis and to indicate the stage of specific diseases. Additionally, understanding the effect of an intervention on a living organism at the molecular level is a crucial strategy for understanding novel or unexpected biological processes. Results: The simultaneous improvements in advanced analytical techniques, sample preparation techniques, computer technology, and databank contents has enabled more valuable scientific information to be gained from metabolomics than ever before. With over 15,000 known endogenous metabolites, there is no single analytical technique capable of analyzing the whole metabolome. However, capillary electrophoresis-mass spectrometry (CE-MS) is a unique technique used to analyze an important portion of metabolites not accessible by liquid chromatography or gas chromatography techniques. The analytical capability of CE, combined with recent sample preparation techniques focused on extracting polar-ionic compounds, make CE-MS a perfect technique for metabolomic studies. Conclusion: Here, previous reviews of CE-MS based metabolomics are evaluated to highlight recent improvements in this technique. Specifically, we review papers from the last two years (2018 and 2019) on CE-MS based metabolomics. The current situation and the challenges facing metabolomic studies are discussed to reveal the high potential of CE-MS for further studies, especially in biomarker development studies.

Accelerating oil and gas investment and reserves by design

2018 ◽  
Vol 58 (2) ◽  
pp. 557
Author(s):  
Barry A. Goldstein
Keyword(s):  
Natural Gas ◽  
Fossil Fuels ◽  
Oil And Gas ◽  
South Australia ◽  
Land Access ◽  
Oil And Gas Exploration ◽  
Oil And Gas Producers ◽  
Crude Oil Prices ◽  
Exploration And Production ◽  
Oil And Gas Operations

Facts are stubborn things; and whatever may be our wishes, our inclinations, or the dictates of our passion, they cannot alter the state of facts and evidence (Adams 1770). Some people unfamiliar with upstream petroleum operations, some enterprises keen to sustain uncontested land use, and some people against the use of fossil fuels have and will voice opposition to land access for oil and gas exploration and production. Social and economic concerns have also arisen with Australian domestic gas prices tending towards parity with netbacks from liquefied natural gas (LNG) exports. No doubt, natural gas, LNG and crude-oil prices will vary with local-to-international supply-side and demand-side competition. Hence, well run Australian oil and gas producers deploy stress-tested exploration, delineation and development budgets. With these challenges in mind, successive governments in South Australia have implemented leading-practice legislation, regulation, policies and programs to simultaneously gain and sustain trust with the public and investors with regard to land access for trustworthy oil and gas operations. South Australia’s most recent initiatives to foster reserve growth through welcomed investment in responsible oil and gas operations include the following: a Roundtable for Oil and Gas; evergreen answers to frequently asked questions, grouped retention licences that accelerate investment in the best of play trends; the Plan for ACcelerating Exploration (PACE) Gas Program; and the Oil and Gas Royalty Return Program. Intended and actual outcomes from these initiatives are addressed in this extended abstract.

scholarly journals Colonization of Durum Wheat (Triticum turgidum L. var. durum) Culms Exhibiting Premature Senescence (Dead Heads) Associated with Fusarium pseudograminearum Crown Rot

Plant Disease ◽  
2017 ◽  
Vol 101 (10) ◽  
pp. 1788-1794 ◽  
Author(s):  
Noel L. Knight ◽  
Bethany Macdonald ◽  
Mark W. Sutherland
Keyword(s):  
Durum Wheat ◽  
Disease Susceptibility ◽  
Triticum Turgidum ◽  
Crown Rot ◽  
Vascular Bundles ◽  
Fusarium Crown Rot ◽  
Fusarium Pseudograminearum ◽  
Field Samples ◽  
Key Factor ◽  
Significant Disease

Fusarium crown rot is a significant disease of durum wheat (Triticum turgidum L. var. durum), which exhibits high levels of disease susceptibility. The most extreme symptom of crown rot is a prematurely senescing culm that typically fails to set grain. Individual crown rot-affected durum wheat plants displaying both nonsenescent and prematurely senescent culms were harvested to compare visual discoloration, Fusarium pseudograminearum biomass, and vascular colonization in culm sections sampled at three different heights above the crown. Field samples of EGA Bellaroi were collected at Wellcamp, QLD, in 2011, 2012, 2013, and 2014, and of Hyperno at Narrabri, NSW, in 2014. Prematurely senescent culms exhibited greater visual discoloration, F. pseudograminearum biomass, and vascular colonization than nonsenescent culms in each year they were examined. The extent of these differences varied between environments and timing of collection in each year. Vascular colonization initially occurred in xylem vessels and spread into phloem tissues as disease severity increased. The increased presence of hyphae in vascular bundles of prematurely senescing culms provides strong evidence for the hypothesis that restriction of water and nutrient movement in a diseased culm is a key factor in crown rot severity.

Effective Improvements to Reliability Based Corrosion Management

2010 ◽  
Author(s):  
Shahani Kariyawasam ◽  
Warren Peterson
Keyword(s):  
Decision Making ◽  
Oil And Gas ◽  
Data Gathering ◽  
Effective Area ◽  
The Face ◽  
Integrity Management ◽  
Reliability Methods ◽  
Specific Growth Rates ◽  
Safe Condition ◽  
Effective Use

Reliability methods have being adopted by oil and gas operators for integrity management decisions. These methods explicitly account for all relevant uncertainties and are designed to provide consistent safety. Consequently, a risk or reliability based approach is a very appropriate basis for decision making in the face of uncertainties. However, as in the effective use of any powerful methodology the sensitivities of the method to assumptions and limitations of applicability need to be well understood. This paper presents how improvements were made to reliability based integrity program by understanding its limitations and sensitivities. First the inputs that have the highest impact on the results were identified. These inputs are the most appropriate areas for improvement and data gathering. It is also very important to understand how the results are to be used and for what purpose. The results of this particular inline inspection based reliability assessment are used to make better excavation and repair decisions. A defect-based and joint-based decision making process is essential for determining with sufficient confidence if each defect and joint is in a safe condition. Consequently, the improvements are focused on discriminating between the myriad of defects found during an inline inspection run. Distinct field characteristics of corrosion growth are also taken into account in these improvements. The paper presents the implementation of effective area methods for future integrity probabilistic evaluations. It also describes the benefit of applying defect-specific growth rates. Finally, case studies are presented to demonstrate the effectiveness of the changes.

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