Characteristics and Sources of Environmentally Persistent Free Radicals in PM2.5 in Dalian: Important Role of Polycyclic Aromatic Hydrocarbons
Abstract Environmentally persistent free radicals (EPFRs) are an emerging class of environmental hazardous contaminants that extensively, stably exist in airborne particulate matter and pose harmful effects on human health. However, there was little research about the sources of EPFRs in actual atmospheric conditions. This study reported the occurrence, characteristics and sources of EPFRs and polycyclic aromatic hydrocarbons (PAHs) in PM2.5 collected in Dalian, China. The concentrations of PM2.5-bound EPFRs ranged from 1.13×1013 to 8.97×1015 spins/m3 (mean value: 1.14×1015 spins/m3). Carbon-centered radicals and carbon-centered radicals with adjacent oxygen atoms were detected. The concentration of ∑PAHs ranged from 1.09 to 76.24 ng/m3 and PAHs with high molecular weight (HMW) were predominant species in PM2.5. The correlation analysis and PMF result showed that coal and biomass combustion are the top contributors to EPFR, followed by vehicle emission. The secondary sources to EFPRs was negligible. The finding of present study provides an important evidence for further study on the formation mechanism of EPFRs in actual atmospheric to control the air pollution.