scholarly journals Effect of Y on the Oxidation Behavior of a Directionally Solidified Ni-based Single Crystal Superalloy

2020 ◽  
Author(s):  
Zihan Zhao ◽  
Kai Guan ◽  
Renjie Cui ◽  
Jianchao Qin ◽  
Zhaohui Huang
Keyword(s):  
Weight Gain ◽  
Single Crystal ◽  
Oxide Scale ◽  
Oxidation Rate ◽  
Oxidation Behavior ◽  
Isothermal Oxidation ◽  
Oxidation Products ◽  
Single Crystal Superalloy ◽  
Directionally Solidified ◽  
Oxidation Weight Gain

Abstract The effect of Y addition on the oxidation behavior of a Ni-based directionally solidified single crystal superalloy was investigated. Isothermal oxidation test for the samples with different-level Y addition was conducted at 1100℃ in air. The Y content of the samples was demarcated by the actual pickup amount resulted from ICP-AES test. It was found that the addition of Y increased the oxide resistance by an adhesive double-layer oxide scale which was composed of Al2O3 and spinel Ni(Cr,Al)2O4. With 70ppm Y addition, the oxidation weight gain was decreased from 12.6g/m2 for the alloy without Y addition to 5.3g/m2, and the oxidation rate was significantly decreased. Besides, the internal nitride also disappeared after Y doping because of the increasing oxidation scale adherence and the decreasing of oxidation products. In this study, 660ppm Y addition alloy showed the best oxidation resistance.

Effect of Hf Content on Oxidation Resistance of Single Crystal Superalloy at 1000°C

2014 ◽  
Vol 915-916 ◽  
pp. 562-566 ◽  
Author(s):  
Z.X. Shi ◽  
Shi Zhong Liu ◽  
M. Han ◽  
J.R. Li
Keyword(s):  
Grain Size ◽  
Single Crystal ◽  
Oxide Scale ◽  
Oxide Layer ◽  
Oxidation Resistance ◽  
Isothermal Oxidation ◽  
Single Crystal Superalloy ◽  
Ambient Atmosphere ◽  
Directionally Solidified ◽  
Better Than

The specimens of single crystal superalloy DD6 with 0.10% Hf and 0.47% Hf were prepared in the directionally solidified furnace. The effect of Hf content on the isothermal oxidation resistance of the second generation single crystal superalloy DD6 was studied at 1000°Cin ambient atmosphere. Morphology of oxides was examined by SEM, and their composition was analyzed by XRD and EDS. The experimental results show that the oxidation resistance of DD6 alloy with 0.47% Hf is better than that of the alloy with 0.10% Hf. The alloy with different Hf content all obeys parabolic rate law during oxidation for 100h at 1000°C. The increase of Hf content can promote the Al2O3 formation and decreases the proportion of NiO. The oxide grain size and the thickness of the oxide layer all reduce with increasing of Hf content. The oxide scale of the alloy with different Hf content is made up of an outer NiO layer with a small amount of Co3O4, inner Al2O3 and Cr2O3 layer with a small amount of TaO2.

Isothermal Oxidation Behavior of Ni Base Superalloy DM02 for High Temperature Dies

2007 ◽  
Vol 546-549 ◽  
pp. 1253-1256
Author(s):  
Qing Li ◽  
Jin Xia Song ◽  
Cheng Bo Xiao ◽  
Shi Yu Qu ◽  
Ding Gang Wang ◽  
...  
Keyword(s):  
Weight Gain ◽  
High Temperature ◽  
Oxide Scale ◽  
Oxidation Resistance ◽  
Growth Mechanism ◽  
Oxidation Kinetics ◽  
Oxidation Behavior ◽  
Isothermal Oxidation ◽  
Good Oxidation Resistance ◽  
Base Superalloy

The isothermal oxidation behavior of a new developed Ni base superalloy named DM02 for high temperature dies was studied in this paper. The dynamic curve was achieved by monitoring weight gain of the alloy as a function of time. The results showed that the alloy had fairly good oxidation resistance at 1050°C and 1100°C. The oxidation kinetics at both 1050°C and 1100°C followed parabolic rules in segment. It has been found that the oxidation of the alloy was controlled by multi-oxides of (Ni, Co)O, (Ni, Co)Al2O4, and NiWO4, growth mechanism in the primary stage, and by Al2O3, NiAl2O4 growth mechanism in the following stage. After oxidation at 1050°C for 100h, the oxide scale of the alloy was mainly composed of two areas. Some were thin uniform (Ni， Co)Al2O4(outer)/Al2O3 (inner) composites scale and others were multi-layer oxide scale of ( Ni,Co)O / multi-oxides (mainly NiWO4、NiO and NiAl2O4.) /Al2O3.

scholarly journals Isothermal oxidation behavior of electrospark deposited NiCrAlY coatings on a Ni-based single-crystal superalloy

2019 ◽  
Vol 53 (3) ◽  
pp. 389-394
Author(s):  
C. Guo ◽  
T. Liang ◽  
F. Lu ◽  
Z. Liang ◽  
S. Zhao ◽  
...  
Keyword(s):  
Single Crystal ◽  
Oxidation Behavior ◽  
Isothermal Oxidation ◽  
Single Crystal Superalloy

scholarly journals Investigation on Optimal Ta/Cr Ratio of a Single Crystal Ni-Base Superalloy in View of the Isothermal Oxidation Behavior

Crystals ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1421
Author(s):  
Jianxiu Chang ◽  
Wenhao Feng ◽  
Wenwen Zhao ◽  
Hongmin Jia ◽  
Yanming Liu ◽  
...  
Keyword(s):  
Single Crystal ◽  
Oxidation Resistance ◽  
Oxidation Behavior ◽  
Isothermal Oxidation ◽  
Nitride Layer ◽  
Oxidation Products ◽  
Competitive Growth ◽  
X Ray Diffraction ◽  
Al2o3 Layer ◽  
Oxidation Performance

The relative content of strengthening element tantalum (Ta) and oxidation-resistant element chromium (Cr) is an essential value for superalloys to obtain an excellent combination of oxidation resistance and mechanical properties. In the present paper, the isothermal oxidation behavior of several single crystal Ni-base superalloys with different Ta/Cr (wt. %, similarly hereinafter) ratios at 1000 °C in static air has been systematically investigated to explore the optimal Ta/Cr for excellent oxidation resistance. A detailed microstructure study using X-ray diffraction (XRD), scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS) and an electro-probe microanalyzer (EPMA) was performed to reveal the oxidation products and mechanisms. For all alloys, a three-layer structured scale consisting of an outer (Cr, Al, Ti, Ni, Ta)-O layer, an inner Al2O3 layer and an inner nitride layer was formed. As Ta/Cr increased, the amounts of Ta-containing products, cracks, holes and inner nitride increased. Meanwhile, the completeness of the Al2O3 layer got worse. It was shown that if Ta/Cr ≤ 0.5, Ta increased the growth rate of Cr2O3 via the doping effect induced by Ta cations. If Ta/Cr > 0.5, Ta reduced the completeness of Cr2O3 through competitive growth of Ta2O5 and Cr2O3. A good oxidation performance can be expected with the value Ta/Cr ≤ 0.5.

Isothermal oxidation behavior of a new Re-free nickel-based single-crystal superalloy at 950 °C

Rare Metals ◽  
2016 ◽  
Vol 36 (8) ◽  
pp. 617-621 ◽  
Author(s):  
Xue-Feng Zhou ◽  
Guang Chen ◽  
Ya-Ya Feng ◽  
Zhi-Xiang Qi ◽  
Min-Zhi Wang ◽  
...  
Keyword(s):  
Single Crystal ◽  
Oxidation Behavior ◽  
Isothermal Oxidation ◽  
Single Crystal Superalloy

The Effect of Tensile Stress on Oxidation Behavior of Nickel-Base Single Crystal Superalloy

2021 ◽  
pp. 109737
Author(s):  
Hai-Qing Pei ◽  
Meng Li ◽  
Ping Wang ◽  
Xiao-Hu Yao ◽  
Zhi-Xun Wen ◽  
...  
Keyword(s):  
Tensile Stress ◽  
Single Crystal ◽  
Oxidation Behavior ◽  
Single Crystal Superalloy ◽  
Nickel Base

Isothermal Oxidation of René N5 at 1150°C

2018 ◽  
Author(s):  
Megan Walker ◽  
Xiao Huang
Keyword(s):  
Single Crystal ◽  
Exposure Time ◽  
Bond Coat ◽  
Isothermal Oxidation ◽  
Oxidation Behaviour ◽  
Single Crystal Superalloy ◽  
Short Term ◽  
Alumina Layer ◽  
Spinel Layer ◽  
Oxide Spallation

In this study, single crystal superalloy René N5 was exposed in air at 1150 °C for up to 16 hours to evaluate the alloy’s short-term oxidation behaviour and the potential for developing a no-bond coat TBC system. The results showed that after 1 hour of exposure, a three layered oxide developed on the surface, consisting of spinel, Ta-containing oxide and alumina just above the substrate. After 4 hours of exposure, oxide spallation occurred; this became more pronounced after 16 hours. The oxide spallation took place between the top spinel layer and alumina layer, where Ta-rich oxide was more abundant. All samples tested for 0.5, 1, 2, 4 and 16 hours developed alumina near the substrate while the occurrence of NiO, spinel and Ta-oxides varied, depending upon the exposure time.

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