A New Family of Ionic Liquids 1-Amino-3-Alkyl-1,2,3-Triazolium Nitrates

A new family of herbicidal ionic liquids based on d-glucose and MCPA or 2,4-D anions has been synthesized and the physicochemical, surface active and herbicidal properties of the obtained salts were characterized.

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Bishydrobis(tetrazol-1-yl)borate (BTB) based energetic ionic liquids with high density and energy capacity as hypergolic fuels

Journal of Materials Chemistry A ◽

10.1039/c7ta03241b ◽

2017 ◽

Vol 5 (30) ◽

pp. 15525-15528 ◽

Cited By ~ 21

Author(s):

Xingye Li ◽

Chenbin Wang ◽

Haibo Li ◽

Fude Nie ◽

Hongquan Yin ◽

...

Keyword(s):

Ionic Liquids ◽

High Density ◽

Energy Capacity ◽

New Family ◽

Energetic Ionic Liquids

A new family of bishydrobis(tetrazol-1-yl)borate (BTB) based energetic ionic liquids were synthesized, which are hypergolic with oxidizers and show superior energy capacity and high density.

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The influence of alkyl chain branching on the properties of pyrrolidinium-based ionic electrolytes

Physical Chemistry Chemical Physics ◽

10.1039/d0cp03046e ◽

2020 ◽

Vol 22 (32) ◽

pp. 18102-18113 ◽

Cited By ~ 1

Author(s):

Danah Al-Masri ◽

Ruhamah Yunis ◽

Anthony F. Hollenkamp ◽

Cara M. Doherty ◽

Jennifer M. Pringle

Keyword(s):

Ionic Liquids ◽

Electrochemical Properties ◽

Alkyl Chain ◽

Chain Branching ◽

Plastic Crystals ◽

New Family

Introduction of a branched alkyl chain onto the widely used pyrrolidinium cation has produced a new family of ionic liquids and plastic crystals with advantageous physical, thermal and electrochemical properties.

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Novel and versatile room temperature ionic liquids for energy storage

Energy & Environmental Science ◽

10.1039/c8ee02437e ◽

2019 ◽

Vol 12 (2) ◽

pp. 566-571 ◽

Cited By ~ 32

Author(s):

Mega Kar ◽

Oscar Tutusaus ◽

Douglas R. MacFarlane ◽

Rana Mohtadi

Keyword(s):

Ionic Liquids ◽

Energy Storage ◽

Electrochemical Properties ◽

Melting Temperature ◽

Room Temperature ◽

Storage Systems ◽

Room Temperature Ionic Liquids ◽

Cluster Anions ◽

Boron Cluster ◽

New Family

The first example of a family of low melting temperature ionic liquids based on the highly stable and inert closo-boron cluster anions is demonstrated. This, combined with excellent physiochemical and electrochemical properties makes this new family of ionic liquids a serious contender towards overcoming key challenges of electrolytes in energy storage systems.

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New family of highly conductive and low viscous ionic liquids with asymmetric 2,2,2-trifluoromethylsulfonyl-N-cyanoamide anion

Electrochimica Acta ◽

10.1016/j.electacta.2015.02.228 ◽

2015 ◽

Vol 175 ◽

pp. 254-260 ◽

Cited By ~ 16

Author(s):

Alexander S. Shaplov ◽

Elena I. Lozinskaya ◽

Petr S. Vlasov ◽

Sofia M. Morozova ◽

Dmitrii Y. Antonov ◽

...

Keyword(s):

Ionic Liquids ◽

New Family

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Soft materials with graphitic nanostructures

Philosophical Transactions of The Royal Society A Mathematical Physical and Engineering Sciences ◽

10.1098/rsta.2007.2030 ◽

2007 ◽

Vol 365 (1855) ◽

pp. 1539-1552 ◽

Cited By ~ 25

Author(s):

Takuzo Aida ◽

Takanori Fukushima

Keyword(s):

Carbon Nanotubes ◽

Ionic Liquids ◽

Self Assembly ◽

Soft Materials ◽

Review Article ◽

New Family ◽

Nanotube Composites ◽

Long Time ◽

Walled Carbon Nanotubes ◽

Imidazolium Ion

This review article focuses on our recent studies on novel soft materials consisting of carbon nanotubes. Single-walled carbon nanotubes, when suspended in imidazolium ion-based ionic liquids and ground in an agate mortar, form physical gels (bucky gels), where heavily entangled bundles of carbon nanotubes are exfoliated to give highly dispersed, much finer bundles. By using bucky gels, the first printable actuators that operate in air for a long time without any external electrolyte are developed. Furthermore, the use of polymerizable ionic liquids as the gelling media results in the formation of electroconductive polymer/nanotube composites with enhanced mechanical properties. The article also highlights a new family of nanotubular graphite, via self-assembly of amphiphilic hexabenzocoronene (HBC) derivatives. The nanotubes consist of a graphitic wall composed of a great number of π-stacked HBC units and are electroconductive upon oxidation. The use of amphiphilic HBCs with functional groups results in the formation of nanotubes with various interesting properties.

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Design and synthesis of new family of ionic liquids based on 2-iminium-1,3-dithiolanes: A combined theoretical and experimental effort

Journal of Molecular Structure ◽

10.1016/j.molstruc.2013.10.017 ◽

2014 ◽

Vol 1056-1057 ◽

pp. 56-62 ◽

Cited By ~ 1

Author(s):

Azim Ziyaei Halimehjani ◽

Mehdi Shakourian-Fard ◽

Marziye Vahdati Farvardin ◽

Mozhgan Raeesi ◽

Mohammed Mahmoodi Hashemi ◽

...

Keyword(s):

Ionic Liquids ◽

Design And Synthesis ◽

New Family ◽

Experimental Effort

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Computational Screening of the Physical Properties of Water-in-Salt Electrolytes

10.26434/chemrxiv.13012646.v2 ◽

2020 ◽

Author(s):

Trinidad Mendez-Morales ◽

Zhujie Li ◽

Mathieu Salanne

Keyword(s):

Ionic Liquids ◽

Diffusion Coefficients ◽

Free Water ◽

Li Ion Batteries ◽

Energy Storage Devices ◽

Storage Devices ◽

New Family ◽

Computational Screening ◽

Potential Applications ◽

Li Ion

Water-in-salts form a new family of electrolytes with properties distinct from the ones of conventional aqueous systems and ionic liquids. They are currently investigated for Li-ion batteries and supercapacitors applications, but to date most of the focus was put on the system based on the LiTFSI salt. Here we study the structure and the dynamics of a series of water-in-salts with different anions. They have a similar parent structure but they vary systematically through their symmetric/asymmetric feature and the length of the fluorocarbonated chains. The simulations allow to determine their tendency to nanosegregate, as well as their transport properties (viscosity, ionic conductivity, diffusion coefficients) and the amount of free water, providing useful data for potential applications in energy storage devices.

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