The Behavior of H2 in Aqueous Fluids under High Temperature and Pressure

Elements ◽  
2020 ◽  
Vol 16 (1) ◽  
pp. 33-38 ◽  
Author(s):  
Elena F. Bazarkina ◽  
I-Ming Chou ◽  
Alexander F. Goncharov ◽  
Nikolay N. Akinfiev

The presence of H2 and H2O in planetary interiors prompts the need for fundamental studies on these compounds under corresponding conditions. Here, we summarize data on H2 properties in aqueous systems under conditions of high temperature and pressure. We explain how to measure important H2 fugacities in hydrothermal systems. We present available experimental data and thermodynamic models for H2 solubility and vapor–liquid partitioning under hydrothermal conditions. In addition, we introduce the fascinating world of H2–H2O clathrate hydrates under extreme temperatures and pressures. The properties of the H2–H2O system are well established below the critical point of water (374 °C and 22.06 MPa), but far less is known under higher temperatures and pressures, or the effect of salt.

2020 ◽  
Vol 2020 ◽  
pp. 1-6
Author(s):  
Liwu Jiang ◽  
Meiling Wu ◽  
Peng Shi ◽  
Chuanhui Zhang

Arsenic trisulfide (As2S3) has been found to be an excellent glass former at high temperature and pressure. However, there is still some scarcity for the elastic and phonon behavior of the orpiment phase. By using the Dreiding force field of the geometry optimization computations, we investigated the elastic constants, mechanical moduli, and the phonon dispersion of orpiment As2S3 under the pressure from 0 to 5 GPa. Some results of the elastic parameters of orpiment-As2S3 at 0 GPa are consistent with the experimental data. The phonon dispersions for orpiment As2S3 under pressure are also reasonable with previous calculations.


Author(s):  
You Qi ◽  
Shi Zhengang ◽  
Liu Xingnan ◽  
Yan Xunshi ◽  
Yang Guojun

Helium now commonly serves as the coolant in high temperature gas-cooled reactor (HTGR). Some electrical facilities work in helium gas at certain temperature and pressure, such as the helium blower, magnetic bearings and the electrical penetration assemblies. Because the insulation property of helium is much poorer than that of air, especially at high pressure, the insulation design of these electrical facilities is rather important and challenging. So far, national standards of insulation design is only for the air while there exists almost no industrial standard for helium gas. In addition, not many scientific researches on insulation property of helium have been conducted yet and most efforts were made to deal with liquid helium. In this paper, uniform field breakdown strength in millimeter-scale gaps of helium was studied with a streamer model analysis, at from 15°C to 180°C and 0.01MPa to 7MPa. Coefficients of Paschen law are modified to better fit the experimental data under specific conditions and some analysis or explanation was given. The experimental data and rules obtained will be useful for the design of insulation structure in helium gas and promote the study of HTGR.


2018 ◽  
Vol 213 ◽  
pp. 207-214 ◽  
Author(s):  
Michael Hack ◽  
Wolfgang Korte ◽  
Stefan Sträßer ◽  
Matthias Teschner

1999 ◽  
Vol 122 (1) ◽  
pp. 22-26 ◽  
Author(s):  
M. Law ◽  
W. Payten ◽  
K. Snowden

Modeling of welded joints under creep conditions with finite element analysis was undertaken using the theta projection method. The results were compared to modeling based on a simple Norton law. Theta projection data extends the accuracy and predictive capability of finite element modeling of critical structures operating at high temperature and pressure. In some cases analyzed, it was found that the results diverged from those gained using a Norton law creep model. [S0094-9930(00)00601-6]


2020 ◽  
Author(s):  
Dapeng Wen ◽  
Yongfeng Wang ◽  
Junfeng Zhang ◽  
Pengxiao Li ◽  
Zhen-Min Jin

Open Physics ◽  
2015 ◽  
Vol 13 (1) ◽  
Author(s):  
Lili Liu ◽  
Xiaozhi Wu ◽  
Weiguo Li ◽  
Rui Wang ◽  
Qing Liu

AbstractThe high temperature and pressure effects on the elastic properties of the AgRE (RE=Sc, Tm, Er, Dy, Tb) intermetallic compounds with B2 structure have been performed from first principle calculations. For the temperature range 0-1000 K, the second order elastic constants for all the AgRE intermetallic compounds follow a normal behavior: they decrease with increasing temperature. The pressure dependence of the second order elastic constants has been investigated on the basis of the third order elastic constants. Temperature and pressure dependent elastic anisotropic parameters A have been calculated based on the temperature and pressure dependent elastic constants.


ChemPhysChem ◽  
2014 ◽  
Vol 16 (1) ◽  
pp. 138-146 ◽  
Author(s):  
Caroline Schuabb ◽  
Melanie Berghaus ◽  
Christopher Rosin ◽  
Roland Winter

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