Hysteretic and Time Dependent Deformation of Plasma Sprayed Zirconia Ceramics

Time dependent deformation at room and elevated temperature is a significant property of zirconia ceramics and has a direct influence on their use. An understanding of this time dependent behaviour is therefore important in predicting the service life of a component. In this work, the indentation creep behaviour of two typical zirconia ceramics ¾ ceria stabilised polycrystalline tetragonal (Ce-TZP) and yttria (6%) stabilized polycrystalline cubic zirconia, YCPZ, have been investigated from room temperature to 600 °C. Indentation creep tests with various loads yielded identical creep rate, which indicates that indentation size effect has no significant effect on the indentation creep of zirconia ceramics. Tests with variable loads, using a spring loaded apparatus, exhibited comparable indentation creep rates to that under constant loading.

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Electron microscopy studies of plasma-sprayed materials

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100074276 ◽

1983 ◽

Vol 41 ◽

pp. 70-71

Author(s):

K.R. Subramanian ◽

A.H. King ◽

H. Herman

Keyword(s):

Plasma Spraying ◽

Substrate Surface ◽

Flame Temperature ◽

Ceramic Coatings ◽

Metallic Substrates ◽

Hot Plasma ◽

Almost All ◽

Plasma Sprayed ◽

Hostile Environments ◽

Plasma Spraying Process

Plasma spraying is a technique which is used to apply coatings to metallic substrates for a variety of purposes, including hardfacing, corrosion resistance and thermal barrier applications. Almost all of the applications of this somewhat esoteric fabrication technique involve materials in hostile environments and the integrity of the coatings is of paramount importance: the effects of process variables on such properties as adhesive strength, cohesive strength and hardness of the substrate/coating system, however, are poorly understood.Briefly, the plasma spraying process involves forming a hot plasma jet with a maximum flame temperature of approximately 20,000K and a gas velocity of about 40m/s. Into this jet the coating material is injected, in powder form, so it is heated and projected at the substrate surface. Relatively thick metallic or ceramic coatings may be speedily built up using this technique.

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Novel methods for demonstrating osseointegration of hydroxylapatite-coated titanium hip prostheses

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100084478 ◽

1991 ◽

Vol 49 ◽

pp. 34-35 ◽

Cited By ~ 1

Author(s):

P. Frayssinet ◽

J. Hanker ◽

D. Hardy ◽

B. Giammara

Keyword(s):

Hip Prosthesis ◽

Ethanol Concentration ◽

Bone Matrix ◽

Electron Microscopic Examination ◽

Electron Microscopic ◽

Hip Prostheses ◽

Cellular Inclusions ◽

Microscopic Studies ◽

Diamond Saw ◽

Plasma Sprayed

Prostheses implanted in hard tissues cannot be processed for electron microscopic examination or microanalysis in the same way as those in other tissues. For these reasons, we have developed methods allowing light and electron microscopic studies as well as microanalysis of the interface between bone and a metal biomaterial coated by plasma-sprayed hydroxylapatite(HA) ceramic.An HA-coated titanium hip prosthesis (Corail, Landos, France), which had been implanted for two years, was removed after death (unrelated to the orthopaedic problem). After fixation it was dehydrated in solutions of increasing ethanol concentration prior to embedment in polymethylmethacrylate(PMMA). Transverse femur sections were obtained with a diamond saw and the sections then carefully ground to a thickness of 200 microns. Plastic-embedded sections were stained for calcium with a silver methenamine modification of the von Kossa method for calcium staining and coated by carbon. They have been examined by back-scatter SEM on an ISI-SS60 operated at 25 KV. EDAX has been done on cellular inclusions and extracellular bone matrix.

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Strain analysis in composite ceramics

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100144012 ◽

1986 ◽

Vol 44 ◽

pp. 494-497

Author(s):

W. M. Kriven

Keyword(s):

Strain Field ◽

Strain Analysis ◽

Processing Temperature ◽

Transformation Toughening ◽

Zirconia Ceramics ◽

Volume Increase ◽

Analysis Technique ◽

Fundamental Understanding ◽

Contrast Analysis ◽

Elastic Strain Field

Significant progress towards a fundamental understanding of transformation toughening in composite zirconia ceramics was made possible by the application of a TEM contrast analysis technique for imaging elastic strains. Spherical zirconia particles dispersed in a large-grained alumina matrix were examined by 1 MeV HVEM to simulate bulk conditions. A thermal contraction mismatch arose on cooling from the processing temperature of 1500°C to RT. Tetragonal ZrO2 contracted amisotropically with α(ct) = 16 X 10-6/°C and α(at) = 11 X 10-6/°C and faster than Al2O3 which contracted relatively isotropically at α = 8 X 10-6/°C. A volume increase of +4.9% accompanied the transformation to monoclinic symmetry at room temperature. The elastic strain field surrounding a particle before transformation was 3-dimensionally correlated with the internal crystallographic orientation of the particle and with the strain field after transformation. The aim of this paper is to theoretically and experimentally describe this technique using the ZrO2 as an example and thereby to illustrate the experimental requirements Tor such an analysis in other systems.

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