An Investigation of the Distribution of Trihalomethanes Within GAC Contactors

1987 ◽  
Vol 22 (3) ◽  
pp. 412-426
Author(s):  
R.C. Andrews ◽  
P.M. Huck ◽  
L. Gammie

Abstract This study examined the loading distribution of trihalomethanes and total organic carbon within pilot scale granular activated carbon (GAC) contactors receiving finished drinking water and operating in the downflow mode. Three carbons originating from different sources were used for this comparison. Observed column loadings were compared to isotherms. As well, loadings were evaluated as a function of carbon particle size. Significantly higher loadings of trihalomethanes were found in the upper 10 cm (7%) of the GAC beds. Enhanced adsorption in this region was correlated with finer size carbon particles. Isotherms successfully predicted full bed depth trihalomethane loadings for two of the carbons but underestimated loadings in the top 10 cm. A replacement of the top 30 cm of the carbon in one of the beds resulted in a noticeable capacity increase for trihalomethanes.

Ciencia Unemi ◽  
2019 ◽  
Vol 12 (29) ◽  
pp. 51-62
Author(s):  
Richard Iván Ramírez-Palma ◽  
Alejandro Crisóstomo Véliz-Aguayo ◽  
Juan Francisco Garcés-Vargas ◽  
Lucrecia Cristina Moreno-Alcívar ◽  
Gerardo Antonio Herrera-Brunett ◽  
...  

El objetivo de esta investigación fue la reducción de las trazas de materia orgánica en el agua potable por medio del uso de zeolita natural, zeolita activada y la comparación con la eficiencia de la adsorción del carbón activado. Se utilizó agua suministrada por la compañía AGUAPEN  E.P. y materiales adsorbentes zeolita natural, zeolita activada y carbón activado. La zeolita se activó térmicamente a 600ªC. Se realizaron pruebas en columnas de adsorción a escala (RSSCT – Rapid Small-Scale Column Test) para carbón activado granular (GAC) de acuerdo a la norma ASTM 6586 para determinar la eficiencia de la adsorción de las trazas de materia orgánica en el agua potable. Se determinó la eficiencia en base al parámetro de carbono orgánico total en muestras simple del afluente y efluente del agua tratada cada 3 horas durante 24 horas. El incremento de la presión de trabajo evidencia el punto de ruptura o colmatación del adsorbente. La concentración del Carbón Orgánico Total (COT) se determinó mediante el análisis de la combustión de la muestra con el detector infrarrojo no dispersivo de dióxido de carbono (CO2). Los resultados mostraron reducción de materia orgánica con el uso de zeolita natural y zeolita activada, con respecto al carbón activado.AbstractThe objective of this research was the reduction of organic matter traces in drinking water through the use of natural and activated zeolite, and the comparison with the efficiency of activated carbon adsorption. Water supplied by the company AGUAPEN E.P. was used, and adsorbent materials as natural zeolite, activated zeolite and activated carbon were utilized. The zeolite was thermally activated at 600 ° C. Tests were performed on scale adsorption columns (RSSCT - Rapid Small Scale Column Test) for Granular Activated Carbon (GAC) according to ASTM 6586 to determine the efficiency of the adsorption of traces of organic matter in drinking water. Efficiency was determined based on the total organic carbon parameter in simple affluent and effluent samples of treated water every 3 hours during 24 hours. The increase in working pressure shows the point of rupture or clogging of the adsorbent. The concentration of Total Organic Carbon (TOC) was determined by analyzing the sample combustion with a non-dispersive infrared carbon dioxide (CO2) detector. The results showed the reduction of organic matter in natural zeolite and activated zeolite compared to activated carbon. 


2021 ◽  
pp. 1-15
Author(s):  
Hamed Abedini ◽  
Nesrin Ozalp

Abstract Carbon particles can be used as catalyst in solar reactors where they serve as radiant absorbent and nucleation sites for the heterogeneous decomposition reaction. Unlike commonly used metal catalysts, carbon catalyst does not have durability problem and high cost. However, in order to achieve sustainable catalytic decomposition of feedstock over carbon catalysts at elevated temperatures, the surface area of the carbon particles must be maintained. A subsequent treatment of deactivated carbon samples with CO2 at about 1000 °C would increase the surface and would recover the original activity as catalyst. In a windowed solar reactor, carbon particles are directly exposed to the high flux irradiation providing efficient radiation heat transfer directly to the reaction site. Therefore, one of the key parameters to achieve higher conversion efficiencies in a solar reactor is the presence and transport of carbon particles. In this paper, a transient one-dimensional model is presented to describe effect of carbon particle feeding on energy transport and temperature profile of a cavity-type solar receiver. The model was developed by dividing the receiver into several control volumes and formulating energy balance equations for gas phase, particles, and cavity walls within each control volume. Monte Carlo ray tracing (MCRT) method was used to determine the solar heat absorbed by particles and cavity walls, as well as the radiative exchange between particles and cavity walls. Model accuracy was verified by experimental work using a solar receiver where carbon particles were injected uniformly. Comparison of simulation results with the experimentally measured temperatures at three different locations on cavity receiver wall showed an average deviation of 3.81%. The model was then used to study the effect of carbon particle size and feeding rate on the heat transfer, temperature profile, and energy absorption of the solar receiver. Based on the simulation results, it was found that injection of carbon particles with a size bigger than 500 µm has no significant influence on heat transfer of the system. However, by reducing the particle size lower than 500 µm, temperature uniformity and energy absorption were enhanced.


2020 ◽  
Vol 382 ◽  
pp. 123044 ◽  
Author(s):  
Zhenqi Du ◽  
Ruibao Jia ◽  
Congcong Li ◽  
Pengwei Cui ◽  
Wuchang Song ◽  
...  

Proceedings ◽  
2020 ◽  
Vol 51 (1) ◽  
pp. 35
Author(s):  
Patrycja Sobczak ◽  
Agata Rosińska

Total organic carbon (TOC) present in surface water consists of different fractions like dissolved organic carbon (DOC) or biodegradable dissolved organic carbon (BDOC). BDOC may have an impact on the bacteriological quality of water as it can be a source of carbon and energy for microorganisms. It is important to consider this parameter in case of the distribution of drinking water. The aim of this research was to compare the qualities of chosen surface water in Poland and Germany in terms of concentration of total organic carbon and its fractions. The samples were taken from the reservoir in Poland and Rhine River in Germany. The first one is a source of drinking water for humans. The research showed that, considering the analyzed compounds, the water from the river has better quality.


2011 ◽  
Vol 354-355 ◽  
pp. 380-384
Author(s):  
Chun Bo Wang ◽  
Jin Gui Sheng ◽  
Ming Lei ◽  
Jian Guo Wei ◽  
Xiao Fei Ma

The combustion rates of carbon particle in pressurized oxygen-enriched environment were studied. The combustion rates of different diameter carbon particles were calculated in atmospheric as well as pressurized oxygen-enriched conditions. The effects of pressure and particle size on combustion rate of carbon particle were investigated. It shows that the combustion rate of carbon particle rise with the increase of the pressures in pressurized oxygen-enriched and pressurized air conditions. But, the combustion rate of carbon particle change little at higher pressure. When particle size increased from 50μm to 100μm,the combustion rate of carbon particle rising. When the particle size increased to 150μm, the combustion rate of carbon particle changed little.


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